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Water at STP is raised to a final temperature of 125 degrees Celsius. Write an expression for the change in entropy for this
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Answer #1

STP refers to standard temperature & pressure.

At STP

Temperature = 25 degree celsius

Pressure = 1 atm

Cp = 4.2 J /g degree celsius

Entropy can be calculated by using the formula

S = n Cp ln T

For initial entropy,

T1 = 25 degree celsius

S1 = 1 * 4.2 * 2.303 log 25 = 13.522 J/degree celsisus

For final entropy

T2 = 125 degree celsisus

S2 = 1 * 4.2 * 2.303 log 125 = 20.283J/degree celsius

Change in entropy = S2 - S1 = 20.283 - 13.522 = 6.761 J/degree celsisus

or change in entropy can be calculated by using the direct formula

= n Cp 2.303 log (T2/T1)

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