1. Give the major product of the following reactions, write N.R. if no reaction happens. Indicate the stereochemistry if necessary:
1. Give the major product of the following reactions, write N.R. if no reaction happens. Indicate...
1. Give the major product of the following reactions, write N.R. if no reaction happens. Indicate the stereochemistry if necessary: i 1. NaBH, MOH 2. H, H2O 3. conc. H2SO4, heat 1. LiAlH4, THE 2. H, H2O 3. MSCI, Pyr, 0 °C 1. SOCI, EIN -D 2. LAIH, ether 1. Li, hexane 2. i . THE 3. acidic work-up Jone's reagent ОН OH 1. PBT 2. NaCN, THE PH conc. H2SO4 NaCl 0°C conc. HBO OH heat
Provide all organic products for the reactions below. Indicate the relationship between any stereoisomers (label as diastereomers or enantiomers). e. 1. Cl2, H20 2. KOtBu 1. NaOH, H20 2. PCC HO 1. cat. OsO4, H202 2. Br2, hv, CCl4 g. 1. ICH2Znl, Et20 2. MsCI, руг 3. LDA он h. CHCl3 KOtBu 1. HBr, 'BuoOH, hv 2. NaCN, DMF
1. Give the major product of the following reactions, write N.R. if no reaction happens. Indicate the stereochemistry if necessary: 1. conc. HCI 2. LDA, THE 3. O3, CH3OH 4. (CH3)2S N2 hv 1. Hg(OAC)2, THE 2. NaBH4, NaOH, H20 Y-OH (Hint: product has a bicyclic ring)
1. Give the major product of the following reactions, write N.R. if no reaction happens. Indicate the stereochemistry if necessary: 1. Give the major product of the following reactions, write N.R. if no reaction happens. Indicate the stereochemistry if necessary: CHCl3 KOC(CH3)3, (CH3)3COH 1. conc. HBr, heat 2. KOBU, HOBU ✓ 1. NaoMe, MeOH 2. BrCN 1. 1 eq. BH3, THE 2. H2O2, NaOH, H20 3. Hg(OAc)2, MeOH 4. NaBH4, NaOH, H20
1. Give the major product of the following reactions, write N.R. if no reaction happens. Indicate the stereochemistry if necessary: Jone's reagent OH OH Ph~ 1. PBr3 2. NaCN, THE conc. H2S04, n D -OH ou Naci 0 °C 0°C Ph conc. HBr Он /. heat
1. Give the major product of the following reactions, write NR. if no reaction happens. Indicate the stereochemistry if necessary CHCI KOC(CH3). (CH),COH 1. conc. HBr, heat 2. KOBU, HOBU 1. NaOM, MOH CI 2. BICN 1. 1 eq. BH3. THE 2. H2O2, NaOH, H2O 3. Hg(OAC), MeOH 4. NaBH4, NaOH, H2O 1. conc. HCI 2. LDA, THF 3. O. CH,OH 4.(CH), 1. Hg(OAC), THE 2. NaBH, NaOH, H2O > OH (Hint: product has a bicyclic ring)
1. Cl, H20 2. KOBU 1. NaOH, H20 2. PCC 1. ICH Znl, Et, 2. MsCl, pyr 3. LDA 1. HBr, 'BuOOH, hv 2. NaCN, DMF 2. Given both reactants and products, provide correct chemical reagents and solvents to complete the reaction. You might have multiple choices: a. (i) OH + enantiomer CHO CHO
help please! 1) Reactions. Provide the major product for each reaction sequence, account for stereochemistry. 1) PCC, CH2Cl2 2) Brz, acetic acid OH 3) KotBu, A 4) NaOEt, EtOH P CO 8 5) H2O+ workup 6) THF, H.CaPPha HCB , cat. PdOAC) cat. PPh3, DMF, EN | CHA 0 нс. CH32) LDA, THF, -78 °C CHICH,then H3O+ workup 4) NaBH4, EtOH, then H3O+ workup 5) cat. TSOH, benzaldehyde 1) cat. H2SO4, A 2) O3. CH2Cl2, then (CH3)2S CH; 3) NaOE,...
1. Provide the products of the following reactions. Write N.R. if there is no reaction happens. NH2 Nal Acetone CH COONa - foto 57 NaOM NaSH DBU EtOH NaCN EtONa Me- Br -Me
1. Predict the major product for the reactions shown below; pick any 5: HO xs CHal Ag20 NaOEt EtOH, Δ -H2O HO но он 0 он H2SO4 H20, A heat 1) PhMgBr 1) NaOH, Br2 2) 5% HCI 2)H3O+, Δ OEt 1) PPh3 3) KOtBu 2) O 1) NaOH on. Br 2) O o