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МСРВА Alkenes are oxidized to give epoxides on treatment with a peroxyacid, RCo,H, such as metachloroperoxybenzoic...
Peroxyacids (RCO3H) can convert alkenes into epoxides. Draw the two products and the mechanism arrows for...
Peroxyacids (RCO3H) can convert alkenes into epoxides. Draw the two products and the mechanism arrows for the following reaction. Be sure to include lone pairs of electrons and nonzero formal charges on all species. 1st attempt See Periodic Table See Hint Draw curved arrow notation to show the reaction between the peroxy acid and the alkene.
1. LiAIHA 2. H2O H3C NH2 H3C NH2 Amides are reduced to amines by treatment with...
1. LiAIHA 2. H2O H3C NH2 H3C NH2 Amides are reduced to amines by treatment with LiAlH4. Two additions of hydride are required. The carbonyl oxygen atom is lost in complex with the aluminum. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions no XT ... AH, NH2 H3C7NH, 30-AIHz H3C 7 H20+ Ho, H. NH, NH3 HAC NHA H3C OH Amides can be hydrolyzed to yield carboxylic acids. The conditions are...
CECH HO, H,SO4 HgSO4 Alkynes do not react directly with aqueous acid as do alkenes, but...
CECH HO, H,SO4 HgSO4 Alkynes do not react directly with aqueous acid as do alkenes, but will do so in the presence of mercury(II) sulfate as a Lewis acid catalyst. The reaction occurs with Markovnikov regiochemistry, so the OH group adds to the more highly substituted carbon and the H adds to the less highly substituted carbon. The initial product of the reaction is a vinyl alcohol, also called an enol. The cnol immediately rearranges to a more stable ketone...
draw curved arrows to show the movement of electrons in this step of the reaction mechanism...
draw curved arrows to show the movement of electrons in this step
of the reaction mechanism
HCI H2O NH,CI -CEN ОН Acid catalyzed hydrolysis of a nitrile to give a carboxylic acid occurs by initial protonation of the nitrogen atom, fo Draw curved arrows to show the movement of electrons in this step of the reaction mechanism Arrow-pushing Instructions O: x H -CI: -NH₂ SLIDE ty Another Mansion 1 terrattuttomat
Electrophilic addition of HBr to alkenes yields a bromoalkane.
Electrophilic addition of HBr to alkenes yields a bromoalkane. The reaction begins with an attack on the hydrogen of the electrophilic HBr by the n electrons of the double bond to give a carbocation. This step follows Markovnikov's rule with the electrophilic H atom adding to the sp2 carbon containing the most hydrogens, leading to the formation of the most stable carbocation (1°<2°<3°). If possible, a 1,2-shift of either a neighboring hydride or methyl group can occur prior to the...
Tulung ate n illud aludke place in a single step. In the Sn2 reaction, the nucleophile...
Tulung ate n illud aludke place in a single step. In the Sn2 reaction, the nucleophile attacks the a-carbon from the backside and displaces the leaving group with an inversion of configuration occurring at the carbon. In the E2 elimination reaction, strong base removes an acidic hydrogen from the B-carbon and an alkene is formed as the leaving group is expelled from the a-carbon. This elimination follows Zaitsey's rule whereby the more substituted alkene is generally formed. In E2 elimination,...
2 problems (Review Topical (References Br н,слен . CH2Cl2 Electrophilic addition of bromine, Bry, to alkenes...
2 problems
(Review Topical (References Br н,слен . CH2Cl2 Electrophilic addition of bromine, Bry, to alkenes yields a 1,2 dibromoalkane. The reaction proceeds through a cyclic intermediate known as a bromonium ion. The reaction occurs in an anhydrous solvent such as CH CI In the second step of the reaction, bromide is the nucleophile and attacks at one of the carbons of the bromonium ion to yield the product Due to stenc clashes, the bromide ion always attacks the carbon...
This nucleophilic substitution occurs with rearrangement. Draw curved arrows to show the movement of electrons in...
This nucleophilic substitution occurs with
rearrangement. Draw curved arrows to show the movement of electrons
in the following step of the reaction mechanism.
NaOH HON Om This nucleophilic substitution occurs with rearrangement. Draw curved arrows to show the movement of electrons in the following step of the reaction mechanism. Arrow-pushing Instructions Nex mm 34 Submit Answer Try Another Version 1 item attempt remaining
Alkenes can be hydrated via the addition of borane to yield alcohols with non-Markovnikov regiochemistry
Alkenes can be hydrated via the addition of borane to yield alcohols with non-Markovnikov regiochemistry. The boron atom is an electrophile and thus follows Markovnikov's rule in adding to the carbon containing the most hydrogens. Oxidation of the alkylborane with basic peroxide yields the product alcohol. Draw curved arrows to show the movement of electrons in this step of the mechanism. Alkenes can be hydrated via the addition of borane to yield alcohols with non-Markovnikov regiochemistry. The boron atom is an electrophile...
Electrophilic addition of HBr to alkenes yields a bromoalkane
Electrophilic addition of HBr to alkenes yields a bromoalkane. The reaction begins with an attack on the hydrogen of the electrophilic HBr by the electrons of the double bond to give a carbocation. This step follows Markovnikov's rule with the electrophilic H atom adding to the sp2 carbon containing the most hydrogens, leading to the formation of the most stable carbocation (1° < 2° < 3°). If possible, a 1,2-shift of either a neighboring hydride or methyl group can occur...
Peroxyacids (RCO3H) can convert alkenes into epoxides. Draw the two products and the mechanism arrows for the following reaction. Be sure to include lone pairs of electrons and nonzero formal charges on all species. 1st attempt See Periodic Table See Hint Draw curved arrow notation to show the reaction between the peroxy acid and the alkene.
1. LiAIHA 2. H2O H3C NH2 H3C NH2 Amides are reduced to amines by treatment with LiAlH4. Two additions of hydride are required. The carbonyl oxygen atom is lost in complex with the aluminum. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions no XT ... AH, NH2 H3C7NH, 30-AIHz H3C 7 H20+ Ho, H. NH, NH3 HAC NHA H3C OH Amides can be hydrolyzed to yield carboxylic acids. The conditions are...
CECH HO, H,SO4 HgSO4 Alkynes do not react directly with aqueous acid as do alkenes, but will do so in the presence of mercury(II) sulfate as a Lewis acid catalyst. The reaction occurs with Markovnikov regiochemistry, so the OH group adds to the more highly substituted carbon and the H adds to the less highly substituted carbon. The initial product of the reaction is a vinyl alcohol, also called an enol. The cnol immediately rearranges to a more stable ketone...
draw curved arrows to show the movement of electrons in this step
of the reaction mechanism
HCI H2O NH,CI -CEN ОН Acid catalyzed hydrolysis of a nitrile to give a carboxylic acid occurs by initial protonation of the nitrogen atom, fo Draw curved arrows to show the movement of electrons in this step of the reaction mechanism Arrow-pushing Instructions O: x H -CI: -NH₂ SLIDE ty Another Mansion 1 terrattuttomat
Tulung ate n illud aludke place in a single step. In the Sn2 reaction, the nucleophile attacks the a-carbon from the backside and displaces the leaving group with an inversion of configuration occurring at the carbon. In the E2 elimination reaction, strong base removes an acidic hydrogen from the B-carbon and an alkene is formed as the leaving group is expelled from the a-carbon. This elimination follows Zaitsey's rule whereby the more substituted alkene is generally formed. In E2 elimination,...
2 problems
(Review Topical (References Br н,слен . CH2Cl2 Electrophilic addition of bromine, Bry, to alkenes yields a 1,2 dibromoalkane. The reaction proceeds through a cyclic intermediate known as a bromonium ion. The reaction occurs in an anhydrous solvent such as CH CI In the second step of the reaction, bromide is the nucleophile and attacks at one of the carbons of the bromonium ion to yield the product Due to stenc clashes, the bromide ion always attacks the carbon...
This nucleophilic substitution occurs with
rearrangement. Draw curved arrows to show the movement of electrons
in the following step of the reaction mechanism.
NaOH HON Om This nucleophilic substitution occurs with rearrangement. Draw curved arrows to show the movement of electrons in the following step of the reaction mechanism. Arrow-pushing Instructions Nex mm 34 Submit Answer Try Another Version 1 item attempt remaining
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