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A molecule which has absorbed a photon of energy in the visible range could move from the excited electronic state (S1) to a
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Option A is correct. The process is called fluorescence, in which the molecule has absorbed a photon of energy in the visible range and could move from the excited electronic state S1 to a highly excited vibrational level of the ground state.

Option D is wrong, Intersystem crossing takes place when molecule moved from S1 to an excited triplet state T1.

Option C is wrong, in vibrational relaxation during electronic excitation molecule promote to any of the vibrational states and then return to lower vibrational states.

Option B is wrong , internal conversion is the process in which molecule return to a lower ebergy states without emission of radiation.

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