true/false
1. Energy of absorbed photon equals energy of emitted
photon.
2. Following emission, molecule returns to its lowest energy state
by a series of rapid vibrational relaxations.
3. The lifetime of the excited vibrational states is about a
femtosecond; the lifetime of the excited electronic state is
generally longer than a nanosecond.
4. Photon absorption usually occurs when a molecule is in its
ground electronic state.
true/false 1. Energy of absorbed photon equals energy of emitted photon. 2. Following emission, molecule returns...
A molecule which has absorbed a photon of energy in the visible range could move from the excited electronic state (S1) to a highly excited vibrational level of the ground state (So) with the same energy. What is this process called? O a. fluorescence O b.internal conversion O C. vibrational relaxation d. intersystem crossing
There is an uncertainty principle for energy and time ∆E∆t ≥ ¯h/2 . This relationship can be applied to the excited state energies and their lifetimes of atoms and molecules. a) Show that both sides of the expression for time-energy uncertainty relationship have the same units. b) If the lifetime of a molecule at its excited state is 1 nanosecond, what is the uncertainty of the energy (in eV) of this state? c) If a 10-femtosecond laser is used to...
1. Luminescence is because of Photons emitted while excited electrons drop down I Knocking out of electrons by photons Photons stimulated by photons O All 2. Internal conversion is where... The spin of an excited electron reverses, changing the state of the molecule (from singlet state to triplet state or vice versa) A molecule converts its excess energy to light, and emits a photon A molecule converts excess electronic energy to vibrational energy 3. Fluorescence typically occurs within 1055 10-5...
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1. A vacuum bubble forms in a liquid and subsequently collapses. The liquid has density 1g em 3 and pressure equal to 1 standard atmosphere. The initial radius of the bubble is 2 mm. Using dimensional analysis, estimate the duration of the collapse. 2. An astronaut throws a small rock whilst standing on an open plain on Mars. Their hand is moving at approximately 60 km h -...
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LI TIe (kJ/photon) for each calibrated wavelength and then esponding energy (k.J/mol) per mole by using Avogadro's number. (.5d (c) Using Figurel determines the values of quantum numbers ni and for the initial and Trattatert the transitions that give rise to each line. ectr 1 . is с я Wavelength from the calibration graph (nm) Photon energy Value of n (initial state) Value of n (final state) (kJ/mol) S4L10a 419, к) п 430.00 219Kfa 2...