Rate Law
Rate of reaction = k[NH4+]^1[NO2-]^1
From the above table it is clear that rate of reaction is directly proportional to concentration of NH4+ and NO2-.
Rate of disappeareance of NH4+ --->
d[NH4+]/dt =rate of reaction
d[NH4+] = rate of reaction× dt
= 4.3 × 10^-4 M/sec × 155 sec
=666.5 × 10^-4 M
= 0.067 M
Timer Notes Eva mitial rate data are listed in the table for the reaction: (aq) +...
Initial rate data are listed in the table for the reaction: NH4+ (aq) + NO2 (aq) → N2 (g) + H20 (1) AWNA Experiment (NH4+1: [NO2). Initial rate (M/s) 0.24 0.10 17.2 x 10-4 0.12 0.10 13.6 x 10-4 0.15 15.4 x 10-4 0.12 0.12 4.3 x 10-4 0.12 First determine the rate law and rate constant. Under the same initial conditions as in Experiment 4, calculate (NH4+] at 103 seconds after the start of the reaction. In this experiment,...
Initial rate data are listed in the table for the reaction: NH4+ (aq) + NO2- (aq) → N2 (g) + H2O (l) First determine the rate law and rate constant. Under the same initial conditions as in Experiment 4, calculate [NH4+] at 184 seconds after the start of the reaction. In this experiment, both reactants are present at the same initial concentration. The units should be M, and should be calculated to three significant figures. 1:26 Bb Bb # ....
Initial rate data are listed in the table for the reaction NH4t (aq)NO2 (aq)N2 (g)H20 () Experiment [NH4+[NO2Initial rate (M/s) 0.10 0.24 7.2 x 104 1 0.10 0.12 3.6 x 104 0.12 0.15 5.4 x 104 0.12 0.12 4.3 x 104 4 First determine the rate law and rate constant Under the same initial conditions as in Experiment 4, calculate [NH4 ] at 368 seconds after the start of the reaction. In this experiment, both reactants are present at the...
Initial rate data are listed in the table for the reaction: Initial rate data are listed in the table for the reaction: NH4+ (aq) + NO2 (aq) + N2 (g) + H20 (1) Experiment (NH4+]: [NO 2-1. Initial rate (M/s) 0.24 0.10 7.2 x 10-4 0.10 3.6 x 10-4 10.12 0.15 5.4 x 10-4 0.12 0.12 4.3 x 10-4 0.12 First determine the rate law and rate constant. Under the same initial conditions as in Experiment 4, calculate [NH4+] at...
Initial rate data are listed in the table for the reaction: NH4+ (aq) + NO2 (aq) + N2(g) + H20 (1) Experiment (NH4+) (NO2). Initial rate (m/s) AWN + 0.24 0.10 0.12 0.10 0.120.15 0.12 0.12 7.2 x 10-4 3.6 x 104 5.4 x 10-4 4.3 x 10-4 First determine the rate law and rate constant. Under the same initial conditions as in Experiment 4, calculate [NH4+) at 114 seconds after the start of the reaction. In this experiment, both...
1. Initial rate data at 25.0 °C are listed below for the reaction: 2 HgCl2 (aq) + C,042 (aq) → 2 (aq) + 2 CO2(g) + HgCl(s) Expt. [HgCl2]0 [C:02) Initial rate/Ms? 0.100 0.20 0.100 0.40 3.1 x 105 1.2 x 104 6.2 x 10-5 0.050 0.40 Use the data to determine the rate law for the reaction. 2. At 500 °C, cyclopropane (C3H.) rearranges to propene (CH:CH-CH2): CH. (g) → CH,CH=CH2 (8) The reaction is first order and the...
1. Initial rate data at 25.0 °C are listed below for the reaction: 2 HgCl2 (aq) C2O (aq)2 C (aq)+ 2 CO:(g)+ Hg Cl(s) (COP)0 Expt. HgClalo Initial rate/ 3.1 x 10 1 0.100 0.20 1.2x 10 0.100 0.40 6.2x 10S 0.050 0.40 Use the data to determine the rate law for the reaction. 2. At 500 °C, cyclopropane (CsH6) rearranges to propene (CH3CH-CH2): CH CH=CH2 (g) CaHs (g) The reaction is first order and the rate constant is 6.7...
5. The reaction of peroxydisulfate ion (S2O82−) with iodide ion (I−) is S2O82−(aq) + 3I−(aq) → 2SO42−(aq) + I3−(aq) From the following data collected at a certain temperature, determine the rate law and calculate the rate constant. Experiment [S2O82−](M) . [I−](M) . Initial Rate [M/s] 1 0.0300 0.0840 8.80 × 10−4 2 0.0300 0.0420 4.40 × 10−4 3 0.0600 0.0420 8.80 × 10−4 (a) Which of the following equations represents the rate law for this reaction? What is the...
1 7. The initial rate of the reaction: BrOz (aq) + 5 Br(aq) + 8 H+(aq) + 3 Brz(1) + H2O(1) Has been measured at the reactant concentrations shown (in mol/L) Experiment [Br03-] [Br] [H] Initial rate (mol/(L:s)) 0.10 0.10 0.10 8.0 x 10-4 2 0.20 0.10 0.10 1.6 x 10-3 3 0.10 0.20 0.10 1.6 x 10-3 4 0.10 0.10 0.20 3.2 x 10-3 a) what is the rate law expression and the rate constant k? [3] b) what...
Four experiments were conducted to discover how the initial rate of consumption of BrO3- ions in the reaction BrO3-(aq) + 5Br-(aq) + 6H+(aq) à 3Br2(aq) + 3H2O(l) varies as the concentration of the reactants are changed. Use the data given below to determine the average rate constant and write the rate law for this reaction. Experiment [BrO3-] (M) [Br-] (M) [H+] (M) Initial rate (M/s) 1 0.10 0.10 0.10 0.0012 2 0.20 0.10 0.10 0.0024 3 0.10 0.30 0.10 0.0035...