Br Br excess NaNH, HBr, 2-equiv. Bry, 2-equiv. CH3Br NaBH4 PBr3 Hz. Lindlar cat. BH/THF NaOH. HBr, 1-equiv. Brz, 1-equiv. H30*
15. H.Pd 16. 17. 17. H3C 1) NaNH, 2) CH CH,Br 3) Lindlar's H2 18. 1) KMnO4(aq) warm, OH 2) H30+ 19. -CH3 excess Br? 20. 1) 1 equiv. HBr. peoxides 2) HCI
How would you synthesize the following reactions? a. H3C CH3 b. Br H3C CH3 Br
What is the major product of this reaction? 1 equiv. HBr -80 °C Br O A. Br OB. Br OC. OD. Br
H3C Br-Br > Br H3C-CH2 CH3 (large excess) Br CHa он H3 он
The following compound is an intermediate of what reaction? Br 1-butyne with 2 equiv HBr 1 butene with Br2 and hy © 1-butyne with 1 equiv Br2 1- butene with NBS and hy 1-buytne with 2 equl Herand ROOR
For each separate reaction fill in what goes in the
blank box
CH3 CH3 H3C H3C Br © P(CH3)3 bideo ed jer Br Me Br
61Sum2020FinalMU.pdf Download Print Save to OneDrive HBr peroxide Br2 (1 equiv.) CH_C2 Br NaOH THE heat Br, H20 1) KMnO4 NаОН НЬО NBS heat hv 2) H0 H30 11. Predict the major organic product(s) for the following reactions. If there is no reaction write N.R. (6 points each, 72 points total) Show the correct stereochemistry when needed!!
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CH3 CH3 CH's to H3C-CH-CH-CH3 is best Br OH 10. The conversion of achieved through use of which of these reagents in a low temperature reaction? a) Concd. HBr b) Brze c) NaBr, H2SO4 d) PBr3 e) HBr, peroxide 11. Which is the best way to prepare 3-methoxypentane via the Williamson method? a) CH3OH CH3CH2CHOHCH2CH3 H2SO4, 140 C b) CH3OH (CH3)2CHCH2CH2OH H2SO4, 140°C e) CH3I (CH3)2CHCH2CH2ONa 12. When nucleophilic addition to a carbonyl group occurs, the...
What is the AH° for the reaction in kcal/mole? CH3 H2C- C-OH + HBr – - H3C—¢-Br + H2O CH3 BDE in kcal/mole H-Br = 87.6 3° C-Br = 63 3° C-OH = 92 H-OH = 119