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Limestone stalactites and Stalagmites are formed in caves through the following reaction: Ca2+ (aq) + 2...

Limestone stalactites and Stalagmites are formed in caves through the following reaction:

Ca2+ (aq) + 2 HCO3- (aq) ⟶ CaCO3 (s) + H2O (l) + CO2 (g)

When 1 mol of CaCO3 (s) forms under standard conditions, it performs 2.48 kJ of work to the surroundings, pushing back the atmosphere as CO2 forms. At the same time, 36.47 kJ of heat is absorbed from the environment. How much did the internal energy of the reaction change during this process? Consider the reaction as the system. Include proper sign.

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Answer #1

Work done by system – ve. Heat absorbed by system tve. Given. W=-2.48KJ Q = 36.47 KJ from 1st law of thermodynamics. AU= QtW

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