2.
1)
1-butanol and 2-butanol
1-butanol is primary alcohol and 2-butanol is secondary alcohol
We need to distinguish primary alcohol from secondary alcohol.
Lucas test (anhydrous zinc chloride and conc HCl)
On reaction, 1-butanol will have no effect. 2-butanol solution turns cloudy after 3-5 minutes.
2)
Butanal and 2-butanone
Butanal is an aldehdye and 2-butanone is a ketone
We need to distinguish an aldehyde from a ketone
Tollens reagent (ammoniacal silver nitrate solution) forms a silver mirror with butanal. This test is not given by 2-butanone.
3)
Propanal and ethyl acetate
Propanal is an aldehyde and ethyl acetate is an ester
Tollens reagent (ammoniacal silver nitrate solution) forms a silver mirror with propanal. This test is not given by ethyl acetate.
4)
Ethyl acetate is an ester and methyl ethyl ketone is a methyl ketone.
We need to distinguish an ester from a methyl ketone
Iodoform test (Iodine and NaOH) is given by methyl ketones. It is not given by esters.
Methyl ethyl ketone forms pale yellow precipitate of iodoform when treated with iodine and NaOH. However no precipitate is formed with ethyl acetate.
rated C-H Single bonds O-HV b) Name the two major chemical tests you would perform on...
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