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O KINETICS AND EQUILIBRIUM Interconverting Kp and Kc Consider the following chemical equilibrium: CaCO,G) = CaO (G)+CO,g) Now
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Answer:

Step 1: Explanation:

Kc is defined as the amounts of products and reactants present at equilibrium in a reversible chemical reaction at a given temperature.

Kp is the equilibrium constant calculated from the partial pressures of a reaction equation. It is used to express the relationship between product pressures and reactant pressures

Relationship between Kp and Kc is

Kp = Kc (RT)Δn where, Δ n = ( moles of gaseous products - moles of gaseous reactants

Step 2: Solution

Given, CaCO3(s)⇌CaO(s)+CO2(g)

Δ n = ( moles of gaseous products - moles of gaseous reactants )

  Δ n = (0+1) -(0) = 1 [ because moles of solid is not considered ]

Since we know

Kp = Kc (RT)Δn

then, Kc = Kp / (RT)Δn

if  Δ n = 1 then   Kc = Kp / (RT) [ where R = gas constant = 8.314 J / mol.K ]

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