With explanation please -- thanks!
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With explanation please -- thanks!
1.(12 pts) Review the energy profile diagram below for an E1...
Question 4 Which is NOT true of a free energy diagram for an E1 reaction? o...
Question 4 Which is NOT true of a free energy diagram for an E1 reaction? o It proceed through a carbocation intermediate. O The first step is electrophilic elimination. O It includes two transition states. O It begins with a rate determining step.
2. Given the reaction coordinate diagram below, answer the following questions: Free energy Progress of the...
2. Given the reaction coordinate diagram below, answer the following questions: Free energy Progress of the reaction a) How many intermediates are formed in the reaction? b) Which letter(s) represent(s) a transition state? c) What is the fastest step in the reaction? d) Which is more stable: A or G? e) Does A or E form faster from C? f) Which is the most stable intermediate? g) What is the reactant of the rate-determining step? h) is the first step...
Give the complete mechanism for the radical chlorination the reaction potential energy diagram below for the...
Give the complete mechanism for the radical chlorination the reaction potential energy diagram below for the reaction from A to X, Answer the following questions: 7 points Reaction 3) Wichstponis a) Indicate the intermediate(s) on the diagram with letters. b) How many transition states are there? c) Clearly show the free energy of activation for each step. d) What is the slowest step of the reaction? e) Which reaction is fastest and exergonic? 1) Which step is fastest and endergonic?...
points cach) 7. (ll points Given the reaction coordinate diagram for the reaction of A to...
points cach) 7. (ll points Given the reaction coordinate diagram for the reaction of A to form G, answer the follow Cand E B,D,F questions a How many intermediates are formed in the reaction? b. Which letters represent transition states? c. What is the fastest step in the reaction? d. Which is more stable: A or G? e Does A or E form faster from C? f. Which is the more stable intermediate? g. What is the reactant of the...
3. For the Sul reaction given the reaction coordinate diagram is as shown Stop 1 to...
3. For the Sul reaction given the reaction coordinate diagram is as shown Stop 1 to siune L.OM- L .Br 7*. Br + OH2 -O-H HBO O-1 + OH2 (a) Which step is the rate determining step for the reaction? Draw the activation energy for that step into the above diagram. (b) Draw the structure of the highest energy intermediate in the reaction. (c) Given the following bond dissociation energies (in kcal/mol), calculate the AH for the overall reaction. Tertiary...
5. For the Sul reaction given, the reaction coordinate diagram is as shown. step to t.....
5. For the Sul reaction given, the reaction coordinate diagram is as shown. step to t.. supstintos + Br + OH2 -O-H + HBO -Br 79-H + OH2 Br (a) Which step is the rate determining step for the reaction? Draw the activation energy for that step into the above diagram. (b) Draw the structure of the highest energy intermediate in the reaction. (e) Given the following bond dissociation energies (in kcal/mol), calculate the AH for the overall reaction. Tertiary...
please snswer all thanks 5. For the following reaction step, indicate which pattern of arrow pushing...
please snswer all thanks
5. For the following reaction step, indicate which pattern of arrow pushing it represents. Circle one. A. proton transfer C. nucleophilic attack B. loss of leaving group D. rearrangement 6. The following reaction has three mechanistic steps (down, across, and up), Draw all of the curved arrows necessary to complete the mechanism. (Hint: there should be 4 arrows total) HBO OH Br H-Br OH2 + Hö 7. Draw the most likely structure of the following cation...
5) The diagram below represents the energy diagram for the reaction of 1-butyl chloride with water....
5) The diagram below represents the energy diagram for the reaction of 1-butyl chloride with water. On the diagram, draw and indicate the position of each of the following: (0.9 points) a) structures of reactants, products, and intermediates (indicate the position of each on the diagram) b) indicate the positions of all transition states (label as "TS") c) indicate the activation energy of the rate-determining step (label as Ea) Energy Reaction Coordinate 6) Below is an energy diagram that represents...
Can you please answer the following questions? The rate constant, k for the reaction below A...
Can you please answer the following questions?
The rate constant, k for the reaction below A - Products is 2.8 x 10 sat 80°C. If the initial concentration of A is 0.25M, what is the concentration after 50 s? The oxidation reaction of thallium (I) by cerium (IV) is believed to occur via three steps. The rate low for the reaction is: rate = k[Ce [Mn2") ce". Mne - Cen ! ce". Mn. Cell. Mn TI". Mn* - TI. Mn?...
With explanation please -- thanks! 9. (30 pts) Predict whether the following conditions would mainly proceed...
With explanation please --
thanks!
9. (30 pts) Predict whether the following conditions would mainly proceed via an SN2, SN1, E2, or E1 mechanism (write your answer into box on left). Draw the major product (including enatiomer wher appropriate) in each reaction and show stereochemistry (where appropriate). SN2, SN1 E1, or E2 conc.H2SO4 heat SN2, S1 E1, or E2 H2O SN2, SN1 E1, or E2 NaOEt EtOH, heat SN2, SN1 E1, or E2 v O-CF3 H. KOtBu D. H tBuOH...
Question 4 Which is NOT true of a free energy diagram for an E1 reaction? o It proceed through a carbocation intermediate. O The first step is electrophilic elimination. O It includes two transition states. O It begins with a rate determining step.
2. Given the reaction coordinate diagram below, answer the following questions: Free energy Progress of the reaction a) How many intermediates are formed in the reaction? b) Which letter(s) represent(s) a transition state? c) What is the fastest step in the reaction? d) Which is more stable: A or G? e) Does A or E form faster from C? f) Which is the most stable intermediate? g) What is the reactant of the rate-determining step? h) is the first step...
Give the complete mechanism for the radical chlorination the reaction potential energy diagram below for the reaction from A to X, Answer the following questions: 7 points Reaction 3) Wichstponis a) Indicate the intermediate(s) on the diagram with letters. b) How many transition states are there? c) Clearly show the free energy of activation for each step. d) What is the slowest step of the reaction? e) Which reaction is fastest and exergonic? 1) Which step is fastest and endergonic?...
points cach) 7. (ll points Given the reaction coordinate diagram for the reaction of A to form G, answer the follow Cand E B,D,F questions a How many intermediates are formed in the reaction? b. Which letters represent transition states? c. What is the fastest step in the reaction? d. Which is more stable: A or G? e Does A or E form faster from C? f. Which is the more stable intermediate? g. What is the reactant of the...
3. For the Sul reaction given the reaction coordinate diagram is as shown Stop 1 to siune L.OM- L .Br 7*. Br + OH2 -O-H HBO O-1 + OH2 (a) Which step is the rate determining step for the reaction? Draw the activation energy for that step into the above diagram. (b) Draw the structure of the highest energy intermediate in the reaction. (c) Given the following bond dissociation energies (in kcal/mol), calculate the AH for the overall reaction. Tertiary...
5. For the Sul reaction given, the reaction coordinate diagram is as shown. step to t.. supstintos + Br + OH2 -O-H + HBO -Br 79-H + OH2 Br (a) Which step is the rate determining step for the reaction? Draw the activation energy for that step into the above diagram. (b) Draw the structure of the highest energy intermediate in the reaction. (e) Given the following bond dissociation energies (in kcal/mol), calculate the AH for the overall reaction. Tertiary...
please snswer all thanks
5. For the following reaction step, indicate which pattern of arrow pushing it represents. Circle one. A. proton transfer C. nucleophilic attack B. loss of leaving group D. rearrangement 6. The following reaction has three mechanistic steps (down, across, and up), Draw all of the curved arrows necessary to complete the mechanism. (Hint: there should be 4 arrows total) HBO OH Br H-Br OH2 + Hö 7. Draw the most likely structure of the following cation...
5) The diagram below represents the energy diagram for the reaction of 1-butyl chloride with water. On the diagram, draw and indicate the position of each of the following: (0.9 points) a) structures of reactants, products, and intermediates (indicate the position of each on the diagram) b) indicate the positions of all transition states (label as "TS") c) indicate the activation energy of the rate-determining step (label as Ea) Energy Reaction Coordinate 6) Below is an energy diagram that represents...
Can you please answer the following questions?
The rate constant, k for the reaction below A - Products is 2.8 x 10 sat 80°C. If the initial concentration of A is 0.25M, what is the concentration after 50 s? The oxidation reaction of thallium (I) by cerium (IV) is believed to occur via three steps. The rate low for the reaction is: rate = k[Ce [Mn2") ce". Mne - Cen ! ce". Mn. Cell. Mn TI". Mn* - TI. Mn?...
With explanation please --
thanks!
9. (30 pts) Predict whether the following conditions would mainly proceed via an SN2, SN1, E2, or E1 mechanism (write your answer into box on left). Draw the major product (including enatiomer wher appropriate) in each reaction and show stereochemistry (where appropriate). SN2, SN1 E1, or E2 conc.H2SO4 heat SN2, S1 E1, or E2 H2O SN2, SN1 E1, or E2 NaOEt EtOH, heat SN2, SN1 E1, or E2 v O-CF3 H. KOtBu D. H tBuOH...
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