Homework Answers
Allylic and benzylic alkyl halides undergoes SN1 because these are form resonance stabilized carbocation intermediate.
The rate of SN1 reaction is only depends on the concentration of alkyl halide but not on the concentration of nucleophile. So double the concentration of KI doesn't change the rate of reaction.
Add Answer to:
need 35 and 38
(a) OH (b) 8.35 (SYN) For each of these compounds, draw an...
(a) OH 8.35 (SYN) For each of these compounds, draw an alkyl halide that can be used to produce it in an S1 reactio...
(a) OH 8.35 (SYN) For each of these compounds, draw an alkyl halide that can be used to produce it in an S1 reaction. Then, determine whether the alkyl halide would need to be treated with water or methanol and draw the corresponding mechanism. Toon OCH3
i need help with these but alkene is the major product formed from each alkyl halide...
i need help with these
but alkene is the major product formed from each alkyl halide in an El reaction? CH Br CHE Considering the requirement of an anti-periplanar geometry, what E2 product(s) is/are formed from each starting material? Note: Deuterium (Atomic Symbol: D) is one of the two stable isotopes of hydrogen."It nucleus contains one proton and one neutron, whereas the nucles of the more common isotope, protium, contains only one profon. The heavier version of hydrogen can undergo...
CIC-CH.CH $$ 0,09 ( -CCHCH, K CANON D) IV 2, whicen er falowing the A) B)...
CIC-CH.CH $$ 0,09 ( -CCHCH, K CANON D) IV 2, whicen er falowing the A) B) II CITI 21) Which of the following alkenes is the most stable? or more com B) II D) IV 22) For the following reaction, use the identity of the alkyl halide and nucleophile to determine which substitution mechanism occurs. Then determine which solvent affords the faster reaction. OH + BO • ное но A) SN 2, H20 B DMF ) SN1, H20 SN1, DMF...
E2 Reaction 2. Draw all constitutional isomers formed in each E2 reaction and predict the major...
E2 Reaction 2. Draw all constitutional isomers formed in each E2 reaction and predict the major product using the Zaitsev rule. Be OH El Reaction 3. What alkene is the major product formed from each alkyl halide in an El reaction? 4. Label the mechanism as SN2, SN1, E2 or El. You do not have to draw the product(s). CHO CH3-C-CH2-CH CH
3. Determine the mechanism of nucleophilic substitution (SNI or SN2) for each reaction and draw the products. Be aw...
3. Determine the mechanism of nucleophilic substitution (SNI or SN2) for each reaction and draw the products. Be aware of stereochemistry. 8 + CN - dletone m et och cun, DE Br + OCH₂ CH₂ DME 4. Draw all constitutional isomers formed during each elimination reaction after determining whether it is E1 or E2. habel it as El or E2. госна. a y "ocha, B b. Tă CH₃OH Br -OH
was given the wrong solutions What alkene is the major product formed from each alkyl halide...
was given the wrong solutions
What alkene is the major product formed from each alkyl halide in an El reaction? сну Considering the requirement of an anti-periplanar geometry, what E2 product(s) is/are formed from each starting material? Note: Deuterium (Atomie Symbol: D) is one of the two stable isotopes of hydrogen." It nucleus contains one profon and one neutron, whereas the nucleus of the more common isotope, protium, contains only one proton. The heavier version of hydrogen can undergo the...
I need help with 1-4 please Question 1: Find a table that compares the relative reaction...
I need help with 1-4 please
Question 1: Find a table that compares the relative reaction rates (Su2) for alkyi fluorides, chlorides, bromides and iodides (Section 9.2 in the textbook). Which halide is the best leaving group? How much faster is it than the slowest halide leaving group? Question 2: The nature of the solvent plays a big role in determining the type of substitution or elimination mechanism that takes place (SH1, SN2, E1 or E2). Draw structures for 2...
1. Draw all of the constitutional isomers that are formed in each elimination reaction and label...
1. Draw all of the constitutional isomers that are formed in each elimination reaction and label the mechanism as E2 or E1. a. 2-bromo butane reacts with methoxide b. 1-chloro-1-ethyl 2 methyl cyclopentane reacts with water 2. For which reaction mechanism are each of the following statements true? Mechanism S1, S2, E1 or E2. A statement may be true for one or more mechanisms a. The mechanism involves carbocation intermediates b. The mechanism has two steps C. The reaction rate...
answer all 1. In each of the following, indicate which S2 reaction will occur faster. Explain...
answer all
1. In each of the following, indicate which S2 reaction will occur faster. Explain your reasoning. a. 1-bromo-2,2-dimethylpropane or 1-bromo-3-methylbutane with Nal in DMSO. b. 1-iodopentane with NaN, in ethanol or NaSCH, in ethanol, c. Reaction of isobutyl iodide with NaBr in acetone or in ethanol. 2. In each of the following, indicate which S, 1 reaction will occur faster. Explain your reasoning. a. Reaction of I-chloro-1-methylcyclohexane or 1-chloro-2-methylcyclohexane in aqueous ethanol. b. Reaction of 2-chloropentane or 3-bromohexane...
Consider the SN2 reaction of butyl bromide with hydroxide ion , Assuming no other changes, what...
Consider the SN2 reaction of butyl bromide with hydroxide ion , Assuming no other changes, what effect on the reaction rate would result from simultaneously doubling the concentrations of both butyl bromide and hydroxyl ion No effect (B)It would double the rate (C)it would increase the rate six times (D) It would increase the rate four times. 2. Which alky halide would you expect to undergo SN1 hydrolysis most rapidly? (A) (CH3)3C-I (B) (CH3)3C-Br (C) (CH3)3C-Cl (D) (CH3)3C-F 3....
(a) OH 8.35 (SYN) For each of these compounds, draw an alkyl halide that can be used to produce it in an S1 reaction. Then, determine whether the alkyl halide would need to be treated with water or methanol and draw the corresponding mechanism. Toon OCH3
i need help with these
but alkene is the major product formed from each alkyl halide in an El reaction? CH Br CHE Considering the requirement of an anti-periplanar geometry, what E2 product(s) is/are formed from each starting material? Note: Deuterium (Atomic Symbol: D) is one of the two stable isotopes of hydrogen."It nucleus contains one proton and one neutron, whereas the nucles of the more common isotope, protium, contains only one profon. The heavier version of hydrogen can undergo...
CIC-CH.CH $$ 0,09 ( -CCHCH, K CANON D) IV 2, whicen er falowing the A) B) II CITI 21) Which of the following alkenes is the most stable? or more com B) II D) IV 22) For the following reaction, use the identity of the alkyl halide and nucleophile to determine which substitution mechanism occurs. Then determine which solvent affords the faster reaction. OH + BO • ное но A) SN 2, H20 B DMF ) SN1, H20 SN1, DMF...
E2 Reaction 2. Draw all constitutional isomers formed in each E2 reaction and predict the major product using the Zaitsev rule. Be OH El Reaction 3. What alkene is the major product formed from each alkyl halide in an El reaction? 4. Label the mechanism as SN2, SN1, E2 or El. You do not have to draw the product(s). CHO CH3-C-CH2-CH CH
3. Determine the mechanism of nucleophilic substitution (SNI or SN2) for each reaction and draw the products. Be aware of stereochemistry. 8 + CN - dletone m et och cun, DE Br + OCH₂ CH₂ DME 4. Draw all constitutional isomers formed during each elimination reaction after determining whether it is E1 or E2. habel it as El or E2. госна. a y "ocha, B b. Tă CH₃OH Br -OH
was given the wrong solutions
What alkene is the major product formed from each alkyl halide in an El reaction? сну Considering the requirement of an anti-periplanar geometry, what E2 product(s) is/are formed from each starting material? Note: Deuterium (Atomie Symbol: D) is one of the two stable isotopes of hydrogen." It nucleus contains one profon and one neutron, whereas the nucleus of the more common isotope, protium, contains only one proton. The heavier version of hydrogen can undergo the...
I need help with 1-4 please
Question 1: Find a table that compares the relative reaction rates (Su2) for alkyi fluorides, chlorides, bromides and iodides (Section 9.2 in the textbook). Which halide is the best leaving group? How much faster is it than the slowest halide leaving group? Question 2: The nature of the solvent plays a big role in determining the type of substitution or elimination mechanism that takes place (SH1, SN2, E1 or E2). Draw structures for 2...
1. Draw all of the constitutional isomers that are formed in each elimination reaction and label the mechanism as E2 or E1. a. 2-bromo butane reacts with methoxide b. 1-chloro-1-ethyl 2 methyl cyclopentane reacts with water 2. For which reaction mechanism are each of the following statements true? Mechanism S1, S2, E1 or E2. A statement may be true for one or more mechanisms a. The mechanism involves carbocation intermediates b. The mechanism has two steps C. The reaction rate...
answer all
1. In each of the following, indicate which S2 reaction will occur faster. Explain your reasoning. a. 1-bromo-2,2-dimethylpropane or 1-bromo-3-methylbutane with Nal in DMSO. b. 1-iodopentane with NaN, in ethanol or NaSCH, in ethanol, c. Reaction of isobutyl iodide with NaBr in acetone or in ethanol. 2. In each of the following, indicate which S, 1 reaction will occur faster. Explain your reasoning. a. Reaction of I-chloro-1-methylcyclohexane or 1-chloro-2-methylcyclohexane in aqueous ethanol. b. Reaction of 2-chloropentane or 3-bromohexane...
Most questions answered within 3 hours.
-
An infinite sheet of charge that has a surface charge density of
39 nC/m2 lies in...
asked 1 hour ago -
After watching the lectures I am still having a hard time
understanding these equations.
1. The...
asked 2 hours ago -
Testing:
H0:μ=56.9
H1:μ<56.9
Your sample consists of 23 subjects, with a mean of 56.3 and
standard...
asked 2 hours ago -
straight wire, labeled as Wire A, lies horizontally on a
tabletop and is oriented to run...
asked 2 hours ago -
For a Chi-Squared Goodness of Fit Test about a uniform
distribution, complete the table.
Round to...
asked 2 hours ago -
Milk of magnesia is only slightly soluble in water. Kc for the
reaction Mg(OHs)(s)>Mg2+(a) + 2OH-1(aq)...
asked 2 hours ago -
Excel's HYPGEOM.DIST function can be used to compute _____.
a. both hypergeometric probabilities and cumulative
hypergeometric...
asked 3 hours ago -
The rocket used for the human lunar missions was the Saturn V
rocket. At liftoff the...
asked 2 hours ago -
1. The East Street Bagel Shop has a weekly demand for 3,500
bagels, which they make...
asked 2 hours ago -
paraphrasing each paragraph
“Where two or more persons knowingly act together unlawfully,
the act of each...
asked 2 hours ago -
The lateral line system in fish is contained which of the
following?
chemoreceptors
photoreceptors
mechanoreceptors
odor...
asked 2 hours ago -
Find the y-intercept of y =-5 x. The y-intercept of y equals
negative 5 x is______...
asked 3 hours ago