Provide the major products for the following reactions 3. Provide the major products for the following...
2. (16 pts) Reactions Provide reagents, products or starting materials for the following reactions. Show stereochemistry when relevant (or loss thereof). If a reaction produces no significant products, write "NR". If you have a question about an abbreviation, just ask. NaBr OH 1. TsCI 2. Nal, DMF CI DMSO OH 1. PBrg NaCN 2. KOC(CH3)3 Ether LDA НОН THE NaH NaH PO Acetone Heat, water
9. Provide the major products and mechanisms for the following reactions. (16 points) OH 1) NaH 2) CH,CH! CH2CH3
Draw the major products for the following reactions
Nah DMF Br NaNHCH3 Br acetone
3) What are the major products, AE to AU produced in the following reactions? Where it states stereochemistry, dashes and wedges must be used to show stereochemistry. Note: for some reaction enantiomers are formed. 17 Marks One mark for each correct product. Must show stereochemistry and all products for full mark. 1. Hg(OAc)H,0 2. NaBH4 1. BH-THF 2. NaOH/H2O2 conc. HB 1. Nah 2. Br heat AK AF AE K CrO; H2SO4 ZnCI HCI РСС, CH2Cl2 Cro 1. NaOH 2....
3. Predict the major organic products for the following reactions: 1 + H+ OH OH ОН HIO4 HO
3) What are the major products, AE to AU produced in the following reactions? Where it states stereochemistry, dashes and wedges must be used to show stereochemistry. Note: for some reaction enantiomers are formed. 17 Marks One mark for each correct product. Must show stereochemistry and all products for full mark. 1. Hg(OAc)H,0 2. NaBH4 1. BH-THF 2. NaOH/H2O2 conc. HB 1. Nah 2. Br heat AK AF AE K CrO; H2SO4 ZnCI HCI РСС, CH2Cl2 Cro 1. NaOH 2....
1. ELIMINATION CONVERGENCE REACTIONS: Provide the major products for the following elim under the unique prescribed conditions: Bulky Ba (CH3)3COK В NaOH Br A DMSO DMF NAOH Нао С
• Please provide the major organic product(s) of the reaction as described Account for all stereochemistry requirements for reaction and products. You need not include byproducts such as salts for this assignment, but you should be aware of their presence. "No reaction is NOT a possibility on this assignment Starting Material Conditions Major Product(s) ОН PBr3 Et20 NaCN DMF NaNH2 DMSO, 20'C 8 hr 1) NaH, DMF, -78°C 2) M ai NaOH
12. REACTIONS: Give the MAJOR organic products of each of the following reactions. India stereochemistry where appropriate. [3 points each] 1) NaH 2) CH-CH2 CH,CH,OH HASO. PBrg 1) BH, THE 2) H202 / OH 1) TCI. pyridine 1) NBS 2) DMSO,H2O
Provide the major organic product (including stereochemistry if appropriate) for each of the following reactions: 3. 1) NaH а) (CH)-СHCH,ОН 2) (CH),СНОСH-CH,Br b) excess HI 1) Hg(OAc),/H,O 2) NaBHĄ/HO¯ 1) NaOH 2) PҺOH d) CH,CH,Br 1) BH3/THF 2) H-0,/Но" НCIZnClz он g) MCPBA h) 1) mCPBA 2) CH3O¯ 1) mCPBA 2) CH,ОН/Н"