Question
Number 6 and 7. label both spectra of pure p-acetamidophenol and phenacetin product by indicating the bonds

5. Spectra 6. Label the IR spectrum of pure p-acetamidophenol below by indicating the bonds associated with stretches in the
% Transmittance 3269.20 3189.76 3129.39 3069.02 2980.05 2926.04 1658.25 1601.06 1540.69 86 68 4000 3500 3000 2500 2000 1500 1
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Answer #1

он НаС. NH оstructure of p-acetamidophenol

peak due to  =CH sp2 carbon of arene is approx 3030 cm-1.

peak due to alcohal OH group frequency is nearly 3200 cm-1

peak due to C=O group bind to amine showing frequency nearly equal to 1650 cm-1

peak due to amide nitrogen N-H stretching is 3200-3500 cm-1 generally two peaks observed in this region.

2)- structure of phenacetin is CHз HN CH3 and peak at 3269.20 and 3189.76 cm-1 is due to amide group (N-H) stretching of ring

peak from 2900-3000 cm-1 is due to the =CH of aromatic ring

peak at 1658.25 cm-1 and 1601.06 cm-1 is due to the C=O group of amide group.

peak at 1540.69 cm-1 is due to the ether group attatched to the ring.

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