I have a question in regards to bond strength. So the more stable an alkyl radical...
I have a question in regards to bond strength. So the more stable an alkyl radical is the weaker its c-h bond is correct? If this is true then must the c-h bond of a tertiary hydrogen be weaker than the c-h bond of a primary hydrogen?
Homework Answers
Yes... you are right.
The dissociation energies for C--H bond :-
101 kcal/mol for primary
99 kcal/mol for secondary and
97 kcal/mol for tertiary
In general , the greater the amount of electron donation to the antibonding MO of the bond ,the bond is weaker.
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