Question

please answer following question and expain why.

1. It is important to remember that the same grouping of orbitals will have different symmetry labels when you solve for their irreducible representations in different point groups. For each point group listed, (i) solve for the reducible representation (Tred) of two 1s orbitals that are symmetric about the z axis. (ii) List the Mulliken symbols of the two irreducible representations (Tirrep) that you can determine from your Fred. (ii) If there was a metal atom at (0,0,0), which of its orbitals (s, p, and/or d) could interact with each of your F'irrep? 1sA 1s,x Е С C2 (a) Example: Point Group (Cz) (i) 0 (ii) A and B (iii) A (s, pz, dz, dxy, dsz-y2); B (py, p, dyz, dsz) (b) Сav (c) Dzh (d) Czh

Answer 1

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