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10. Consider the three reactions shown below. For each reaction t o...
3. Please answer the following questions concerning the two energy diagrams depicted below. (10 pts) Energy...
3. Please answer the following questions concerning the two energy diagrams depicted below. (10 pts) Energy Diagram A 30 25 20 15 10 0 10 15 20 25 Energy Diagram B 30 25 20 15 10 15 20 25 10 (a) Do the energy diagrams represent concerted or stepwise reactions? Concerted (b) Label the axes, the reactants (R), products (P), any intermediates (), activation energy (E), enthalpy of reaction (AH), and transition state(s) (TS) on the above diagrams. (c) Do...
3. Please answer the following questions concerning the two energy diagrams depicted below. (10 pts) Energy...
3. Please answer the following questions concerning the two energy diagrams depicted below. (10 pts) Energy Diagram A 20 Energy Diagram B (a) Do the energy diagrams represent concerted or stepwise reactions? (b) Label the axes, the reactants (R), products (P), any intermediates (1), activation energy (E.), enthalpy of reaction (AH"), and transition state(s) (TS) on the above diagrams. (c) Do the energy diagrams represent endothermic or exothermic reactions? (d) Which energy diagram represents the faster reaction? (e) Which energy...
3. Please answer the following questions concerning the two energy diagrams depicted below. (10 pts) Energy...
3. Please answer the following questions concerning the two energy diagrams depicted below. (10 pts) Energy Diagram A Energy Diagram B (a) Do the energy diagrams represent concerted or stepwise reactions? (b) Label the axes, the reactants (R), products (P), any intermediates (1), activation energy (E.), enthalpy of reaction (AH'), and transition state(s) (TS) on the above diagrams. (C) Do the energy diagrams represent endothermic or exothermic reactions? (d) Which energy diagram represents the faster reaction? (e) Which energy diagram...
2. Draw a labeled reaction-energy diagram (graph of potential energy versus reaction coordinate) for a three-step...
2. Draw a labeled reaction-energy diagram (graph of potential energy versus reaction coordinate) for a three-step overall exothermic reaction with the A. first step being the rate-determining step B. third step being the rate-determining step Label each graph with the following: reactants (r), transition states (ts.), intermediates (int.), products (p). activation energies (Ea), and overall standard heat of reaction (AH). (Note: Each subscript, x, needs to be a number that refers to the appropriate primary mechanistic step. For example, Ea,...
a) Consider sider this two-step reaction. Draw the structure for the transition state in each step...
a) Consider sider this two-step reaction. Draw the structure for the transition state in each step of the mechanism. arly show any partially broken or partially formed bonds. Include only the hydrogens shown. (0.6 pts) Step 1 Step 2 (b) How many partially formed or partially broken bonds are found in the transition state structure for step 1? # of partially formed bonds (step 1) = ; # of partially broken bonds (step 1) = Will AH® for this reaction...
1. Draw all of the constitutional isomers that are formed in each elimination reaction and label...
1. Draw all of the constitutional isomers that are formed in each elimination reaction and label the mechanism as E2 or E1. a. 2-bromo butane reacts with methoxide b. 1-chloro-1-ethyl 2 methyl cyclopentane reacts with water 2. For which reaction mechanism are each of the following statements true? Mechanism S1, S2, E1 or E2. A statement may be true for one or more mechanisms a. The mechanism involves carbocation intermediates b. The mechanism has two steps C. The reaction rate...
(10 points) Draw the correct product for the reaction below. For step 2, draw the reaction...
(10 points) Draw the correct product for the reaction below. For step 2, draw the reaction mechanism. Be sure to include important intermediate compounds, electron flow arrows, and formal charges for full credit. ОН 1. SOCl2, pyridine 2. CH3NH2 (10 points) Fill in the boxes with the missing starting material, intermediate products, reagents, and/or products. Then for each reaction draw the reaction mechanism with Correct electron flow arrows if appropriate or intermediates and correct formal charges. -OH -NH2 NH (10...
1. In each of the following addition reactions (1) using arrows provide a mechanistic explanation of...
1. In each of the following addition reactions (1) using arrows provide a mechanistic explanation of the course of the reaction (show transition state for concerted mechanism and intermediate for two-step mechanism); (ii) write the product/s of the reaction; (iii) name the reaction product/s. (4 x 5= 20 points) a. Sulfuric acid catalyzed hydration (addition of H:0) of 2-methyl-but-2-ene b. Addition of molecular bromine to l-methyl-cyclohex-l-ene c. Addition of hydrogen bromide to (3R)-2,3-dimethyl-pent-1-ene, present product/s through Fischer projection. d. Hydroboration...
Consider the initial rate data collected at 298 K for the reaction shown below. CH3CH2CH2Br(aq) +...
Consider the initial rate data collected at 298 K for the reaction shown below. CH3CH2CH2Br(aq) + OH(aq) + CH3CH2CH2OH(aq) + Br (aq) Experiment [CH3Br] (M) 0.024 [OH-] (M) 0.024 2 0.048 0.024 Rate (M/s) 3.5 x 10-10 7.1 x 10-10 1.8 x 10-9 1.8 x 10-10 8.6 x 10-9 0.048 0.060 0.024 0.012 4 5 0.036 0.036 a. Determine the rate law and rate constant for the above reaction. b. Draw and label any intermediates and the transition state(s) that...
Addition Reaction (Ch. 8. primarily) Learning Outcomes: By successfully completing this assignment, the student will demonstrate...
Addition Reaction (Ch. 8. primarily) Learning Outcomes: By successfully completing this assignment, the student will demonstrate the ability to: (A) Provide proper curved-arrow mechanisms for addition reactions involving alkene reactants. (B) Predict the correct structure of the products of addition reactions, including correct regiochemistry and stereochemistry. (C) Provide reasonable explanations for mechanistic steps in addition reactions based on energy considerations and the structures of reactants, intermediates, and transition states. 1. The following molecule will be the reactant for all reactions...
3. Please answer the following questions concerning the two energy diagrams depicted below. (10 pts) Energy Diagram A 30 25 20 15 10 0 10 15 20 25 Energy Diagram B 30 25 20 15 10 15 20 25 10 (a) Do the energy diagrams represent concerted or stepwise reactions? Concerted (b) Label the axes, the reactants (R), products (P), any intermediates (), activation energy (E), enthalpy of reaction (AH), and transition state(s) (TS) on the above diagrams. (c) Do...
3. Please answer the following questions concerning the two energy diagrams depicted below. (10 pts) Energy Diagram A 20 Energy Diagram B (a) Do the energy diagrams represent concerted or stepwise reactions? (b) Label the axes, the reactants (R), products (P), any intermediates (1), activation energy (E.), enthalpy of reaction (AH"), and transition state(s) (TS) on the above diagrams. (c) Do the energy diagrams represent endothermic or exothermic reactions? (d) Which energy diagram represents the faster reaction? (e) Which energy...
3. Please answer the following questions concerning the two energy diagrams depicted below. (10 pts) Energy Diagram A Energy Diagram B (a) Do the energy diagrams represent concerted or stepwise reactions? (b) Label the axes, the reactants (R), products (P), any intermediates (1), activation energy (E.), enthalpy of reaction (AH'), and transition state(s) (TS) on the above diagrams. (C) Do the energy diagrams represent endothermic or exothermic reactions? (d) Which energy diagram represents the faster reaction? (e) Which energy diagram...
2. Draw a labeled reaction-energy diagram (graph of potential energy versus reaction coordinate) for a three-step overall exothermic reaction with the A. first step being the rate-determining step B. third step being the rate-determining step Label each graph with the following: reactants (r), transition states (ts.), intermediates (int.), products (p). activation energies (Ea), and overall standard heat of reaction (AH). (Note: Each subscript, x, needs to be a number that refers to the appropriate primary mechanistic step. For example, Ea,...
a) Consider sider this two-step reaction. Draw the structure for the transition state in each step of the mechanism. arly show any partially broken or partially formed bonds. Include only the hydrogens shown. (0.6 pts) Step 1 Step 2 (b) How many partially formed or partially broken bonds are found in the transition state structure for step 1? # of partially formed bonds (step 1) = ; # of partially broken bonds (step 1) = Will AH® for this reaction...
1. Draw all of the constitutional isomers that are formed in each elimination reaction and label the mechanism as E2 or E1. a. 2-bromo butane reacts with methoxide b. 1-chloro-1-ethyl 2 methyl cyclopentane reacts with water 2. For which reaction mechanism are each of the following statements true? Mechanism S1, S2, E1 or E2. A statement may be true for one or more mechanisms a. The mechanism involves carbocation intermediates b. The mechanism has two steps C. The reaction rate...
(10 points) Draw the correct product for the reaction below. For step 2, draw the reaction mechanism. Be sure to include important intermediate compounds, electron flow arrows, and formal charges for full credit. ОН 1. SOCl2, pyridine 2. CH3NH2 (10 points) Fill in the boxes with the missing starting material, intermediate products, reagents, and/or products. Then for each reaction draw the reaction mechanism with Correct electron flow arrows if appropriate or intermediates and correct formal charges. -OH -NH2 NH (10...
1. In each of the following addition reactions (1) using arrows provide a mechanistic explanation of the course of the reaction (show transition state for concerted mechanism and intermediate for two-step mechanism); (ii) write the product/s of the reaction; (iii) name the reaction product/s. (4 x 5= 20 points) a. Sulfuric acid catalyzed hydration (addition of H:0) of 2-methyl-but-2-ene b. Addition of molecular bromine to l-methyl-cyclohex-l-ene c. Addition of hydrogen bromide to (3R)-2,3-dimethyl-pent-1-ene, present product/s through Fischer projection. d. Hydroboration...
Consider the initial rate data collected at 298 K for the reaction shown below. CH3CH2CH2Br(aq) + OH(aq) + CH3CH2CH2OH(aq) + Br (aq) Experiment [CH3Br] (M) 0.024 [OH-] (M) 0.024 2 0.048 0.024 Rate (M/s) 3.5 x 10-10 7.1 x 10-10 1.8 x 10-9 1.8 x 10-10 8.6 x 10-9 0.048 0.060 0.024 0.012 4 5 0.036 0.036 a. Determine the rate law and rate constant for the above reaction. b. Draw and label any intermediates and the transition state(s) that...
Addition Reaction (Ch. 8. primarily) Learning Outcomes: By successfully completing this assignment, the student will demonstrate the ability to: (A) Provide proper curved-arrow mechanisms for addition reactions involving alkene reactants. (B) Predict the correct structure of the products of addition reactions, including correct regiochemistry and stereochemistry. (C) Provide reasonable explanations for mechanistic steps in addition reactions based on energy considerations and the structures of reactants, intermediates, and transition states. 1. The following molecule will be the reactant for all reactions...
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