7.) Shown below are the spectra (labeled A and B) for the reactant and product in...
For the protons labeled Ha and Hb in the structure below, predict the characteristics of their signals in the H NMR spectrum: the approximate chemical shift, the splitting pattern, and the integration value of their signals. Approximate Integration Splitting chemical shift value O 1H H NMR signal O 1 ppm O singlet for H O doublet O 2H 2 ppm O 3H O 3-4 ppm O triplet Br O 4H O 5-6 ppm O quartet O 5H O 7-8 ppm...
Deduce the structures of compounds given from the spectra provided assigning all 1H and 13C signals (1H on the front and 13C on the back). All spectra were taken in CDCl3. The peaks are designated as follows: s=singlet, bs=broad singlet, d=doublet, t=triplet, q=quartet, pent=pentet(quintet), sext=sextet, sept=septet, m=multiplet, d of d=double of doublet, etc. Draw the structure of each compound below the spectra. Label and assign all signals for both the 1H and 13C spectra. 2 3 5 6 g84884 te...
Having trouble figuring out these two unknown compounds. 17) Formula: C8H10O with a strong peak at 3200 cm^-1 18) Formula: C10H13Br I just need to know the structures of each of them if you could please help me out! 17) Chemical Formulac: CHroO IR: strong broad peak at 3200 cm-1 Singlet, 3 Triplet, 1H Singlet, 2hH Doublet, 1H Singlet, 1H Singlet, 1H Doublet, 1H 0 2 6 PPM 18) Chemical Formula: C10H13Br Doublet, 3H Doublet, 2H Triplet, 3hH Quartet, 2H...
In the following chemical structure, several sets of hydrogens are labeled, along with a table of possible 1H- NMR resonance peaks. Match the peak pattern to the indicated signal. OH protons do not show spin-spin coupling in this example. Table of resonances 1 doublet (3) @ 1.3 ppm p 2. doublet (3) @ 1.7 ppm 3. singlet (1) @ 2.1 ppm 4. multiplet (1) @ 4.3 ppm 5. multiplet (1) @ 5.5 ppm 6 doublet of doublets (1)@ 5.6 ppm
For the protons labeled Ha and Ho in the structure below, predict the characteristics of their signals in the H NMR spectrum: the approximate chemical shift, the splitting pattern, and the integration value Approximate chemical shift Splitting Integration value O 1H O 2H 03H O 4H H NMR signal1 ppm for Ha O 2 ppm O 3-4 ppm O 5-6 ppm O 7-8 ppm O singlet O doublet O triplet O quartet O septet O multiplet O 6H H NMR...
Propose structures that fit the following formula and NMR data. (a) C3H100 singlet at 2.10 8 (3H) doublet at 0.958 (6H) multiplet at 2.43 8 (1H) (b) C10H14 singlet at 1.30 8 (9 H) singlet (broad) at 7.308 (5H) (c) C9H11Br quintet at 2.15 8 (2H) triplet at 2.758 (2H) triplet at 3.38 8 (2H) singlet at 7.22 8 (51) IR spectrum: strong peak near 1720 cm (d) C18H14 O2 Singlet at 2.20 8 (3H) Singlet at 5.08 8 (1H)...
Please help propose interpretations of the spectra for the two unknowns pictured below. Identification and drawing of the unknowns would be much appreciated and will get a thumbs up. Liquid T alcohol MS Relative Intensity 0- r 10 20 30 40 50 70 80 90 100 60 m/z Liquid T "H-NMR broad singlet, IH doublet, 6H quartet, 2H triplet, 2H nonet, IH PPM C-NMR PPM Sold e Carboxylic acid Mass Spec. 100 Relative Intensity optippropri protiletterturmflopperprompt 25 50 75 100...
b) Which area of the spectrum did you focus on and which key piece of information (chemical shift, integration, or splitting pattern) helped you decide which spectrum belonged to which isomer? Please explain your responses. Reaction 1: Nitration HNO3 NO2 + + H2SO4, H20 NO2 toluene NO2 ortho meta para Spectrum For Peak A on GC For Peak B on GC For Peak Con GC Isomer Ortho Nitro Toluene Para Nitro Toluene Meta Nitro Toluene Proton NMR Spectrum for Peak...
b) Which area of the spectrum did you focus on and which key piece of information (chemical shift, integration, or splitting pattern) helped you decide which spectrum belonged to which isomer? Please explain your responses. Reaction 1: Nitration HNO3 NO2 + + H2SO4, H20 NO2 toluene NO2 ortho meta para Spectrum For Peak A on GC For Peak B on GC For Peak Con GC Isomer Ortho Nitro Toluene Para Nitro Toluene Meta Nitro Toluene Proton NMR Spectrum for Peak...
10. The 1H NMR for cinnamaldehyde is given below. Sketch the spectrum, and label the H's in the structure with the letters shown. (6 pts) H a-9.7 ppm (1H, singlet) b-7.7 ppm (1H, doublet) c-7.6ppm (2H, doublet) d 7.4 ppm (2H, triplet) e-7.3 ppm (1H, triplet) f- 6.6 ppm (1H, doublet) 7 10 8