a) A 4.951 g sample of a metal reacted with sulfuric acid to produce a gas and a sulfate solid. What is the expected mass (in grams) of the dried sulfate if the metal was Al?
b) A 7.77 g sample of a metal reacted with sulfuric acid to produce a gas and a sulfate solid. What is the expected mass (in grams) of the dried sulfate if the metal was Zn?
Explanation:
A mole ratio is the ratio between the amounts in moles of any two compounds involved in a chemical reaction. The mole ratio can be determined by examining the coefficients in front of formulas in a balanced chemical equation.
Step 1: write the balanced chemical equation.
(a) 2Al + 3H2SO4 ---> Al2(SO4)3 + 3H2
(b) Zn + H2SO4 ---> ZnSO4 + H2
Step 2: calculate the moles of Al and Zn
we know, moles = mass given / molar mass
(a) moles of Al = ( 4.951 g / 26.981538 g/mol ) = 0.1835 mol
(a) moles of Zn = ( 7.77 g / 65.38 g/mol ) = 0.119 mol
Step 3: Calculate the moles of sulfate solid
(a) 2Al + 3H2SO4 ---> Al2(SO4)3 + 3H2
According to the reaction:
2 mol of Al produce 1 mol
of Al2(SO4)3
so, 0.1835 mol of Al will produce=( 1 mol of
Al2(SO4)3 / 2 mol of Al
) × 0.1835 mol of Al = 0.09175 mol of
Al2(SO4)3
(b) Zn + H2SO4 ---> ZnSO4 + H2
According to the reaction:
1 mol of Zn produce 1 mol of ZnSO4
so, 0.119 mol of Al will produce=( 1 mol of
ZnSO4 / 1 mol of Zn ) × 0.119 mol of Zn =
0.119 mol of ZnSO4
Step 4: Calculation of dried sulfate produced
(a) we get moles of Al2(SO4)3 that can be produced = 0.09175 mol
(b) we get moles of ZnSO4 that can be produced = 0.119 mol
(a) Mass of Al2(SO4)3 produced =( moles×molar mass ) = ( 0.09175 mol × 342.15 g/mol ) = 31.4 g
(a) Mass of ZnSO4 produced =( moles×molar mass ) = ( 0.119 mol × 161.47 g/mol ) = 19.2 g
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