Homework Answers
It is a beta-1,4' glycosidic linkage.
Alfa or beta type is given by the position of the linkage respect to the anomeric carbon (the carbonyl carbon in the linear molecule), an axial position is called alfa and the equatorial one is called beta. The numbers indicate the position of the linkage, each monomer is numerated beginning with the anomeric carbon and finishing with the nearest carbon to the oxygen atom; the first number indicates the position of the bonded anomeric carbon and the second one the carbon atom which the linkage is bonded to in the second molecule.
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y/node/845/take/3 Question 3 Classify the glycosidic linkage #3 in the structure shown below. Your answer must...
4. For each sugar below, characterize the anomer if a monosaccharide or the glycosidic bond(s) if...
4. For each sugar below, characterize the anomer if a monosaccharide or the glycosidic bond(s) if a di- or polysaccharide (e.g., B,B-2,3; if there is more than one glycosidic bond, draw an arrow from each label to its corresponding bond). CH,OH CH2OH CH OН но н H Н H Он Н OH н OH Он Н ОН O H Но он b. a. OH H OH CH-OH O H Но ОН Н CH2OH CH2 CH2OH он OCH CH3 Но н...
8. Use the image to answer the questions that follow HO-CH HO-CH2 HO-CH2 CHO H₂o OH CHO CHO OCH CHOICH CH-OH CHCc C...
8. Use the image to answer the questions that follow HO-CH HO-CH2 HO-CH2 CHO H₂o OH CHO CHO OCH CHOICH CH-OH CHCc CHOICH CH 10 | | CH-CH HỒ CH-CH CH-CH CH-CH CH-CH но он но HO он но OH OH HO A B C D Do not e How many carbons does each of the above sugars contain? Name to E n ipo Which sugars are aldoses and which are ketoses? Identify each sugar. Name the linkage for each...
Carbohydrates 1. Label each of the monosaccharides shown below as a triose, tetrose, pentoso, or hexose....
Carbohydrates 1. Label each of the monosaccharides shown below as a triose, tetrose, pentoso, or hexose. но CH OH HT -он - он Н - ОН но -н но -Н но -н нон сньон он но -н НОН CH OH нон нон нон снон CH OH сон сон H- OH H- -он OH cң, он н-с-он Сн,он снон 2. Label each of the monosaccharides shown above as a ketose or aldose. 3. Identify all of the chiral carbons in the...
1) SHOW WORK STEP By STEP below is Figure 7-3 Recognizing Epimers Using Figure 7-3, identify the epimers of (a) D-...
1) SHOW WORK STEP By STEP
below is Figure 7-3
Recognizing Epimers Using Figure 7-3, identify the epimers of (a) D-allose, (b) D-gulose, and (c) D-ribose at C-2, C-3, and C-4. Answer Epimers differ by the configuration about only one carbon. (a) D-altrose (C-2), D-glucose (C-3), D-gulose (C-4) (b) D-idose (C-2), D-galactose (C-3), D-allose (C-4) (c) D-arabinose (C-2), D-xylose (C-3) (a) D-Aldoses Three carbons Four carbons Five carbons но не HO -OH н-с-он CH, OH D-Glyceraldehyde но-с-н H-C-OH снион D-Threose...
Culhydrates 1. Complete th Complete the table by classifying each sugar sugar (A, B, C, D)...
Culhydrates 1. Complete th Complete the table by classifying each sugar sugar (A, B, C, D) below based on carbonyl group and number of carbons (c.8. aldohexose, ketotriose, etc.). Classify them as an antiomer. Indicate the number of chiral carbons for each sugar. Sugar Classification based on carbonyl group and number of carbons Lor D enantiomer Number of chiral carbons н-с-он HO-6-H. н-с-он ін,он CH,OH C=0 HO-C-H н-с-он HO-C-H. ён,он снон c=0 | HO-C-H ін,он H-C-OH CH, OH CD 2....
C=O 2. Which of the following is an example of an aldopentose? Circle your answer. СН,ОН...
C=O 2. Which of the following is an example of an aldopentose? Circle your answer. СН,ОН CH,он CH н-с-он H-6-H H-C-OH HO-C-H. H-C-H H-C-OH H-C-OH H-6-H H-C-OH CH,OH CH,OH CH OH 3. In the L- isomer of a Fischer projection of a monosaccharide, the -OH group furthest from the carbonyl is written. Circle your answer. on the left of the top chiral carbon. on the left of the middle chiral carbon. on the left of the bottom chiral carbon. on...
Page Chemistry 107 Midterm II Review Problems Draw a Lewis structure for CaHN (think over the...
Page Chemistry 107 Midterm II Review Problems Draw a Lewis structure for CaHN (think over the bonding preferences of each atom when you lay out the skeleton of this molecule!) 1. CC Determine the geometry at each "central atom" (a) Does this molecule have any polar bonds? Is the entire molecule polar? (b) What will be the dominant intermolecular force in a sample of this compound? (c) (c) If you had 100.0 g of this compound, how many moles would...
18. Which of the following compound(s) would undergo mutarotation in aqueous solution? 19. Draw the chair...
18.
Which of the following compound(s) would undergo mutarotation in
aqueous solution?
19. Draw the chair conformation of a-D-galactopyranose.
20. Which of the following compound(s) is a glycoside?
21. Provide the reagents neccesary to carry out the following
conversion.
22. Predict the product(s) for the following reaction.
23. D-glucose & D-galactose are ______epimers of each
other.
24. Predict the product(s) for the following reaction.
25. Which of the following compound(s) would produce D-glucose
and D-mannose when treated with HCN followed...
Please complete for Tuesday, we will go through the questions and mark them in class. pg 156 - 4.23,...
Please complete for Tuesday, we will go through the questions and mark them in class. pg 156 - 4.23, 4.24, 4.26 pg 170 - 4.29, 4.31, pg 171-4.36 pg 175 - 4.59 pg 176- 4.74, 4.75, 4.80 pg 177-4.81, 4.82 pg 188- 5.1, 5.4, 5.5, 5.6, 5.11 - Using Table 5.1 pg 198-5.22, 5.25 pg 203 - 5.29 pg 206 - 5.37 pg 209 - 5.39 pg 2.14 5.61 pg 235-6.11, 6.14, 6.16 156 CHAPTER 4 Introduction to Organic Compounds...
Name the following aldoses. (Include in the names the stereochemical designation D or L and, where...
Name the following aldoses. (Include in the names the stereochemical designation D or L and, where appropriate, the configuration of the anomeric carbon, alpha or beta. This question is case-sensitive, so capitalize only the D or L.) ball & stick + labels b all & stick + labels The following model is that of an aldopentose: ball & stick - + labels Draw the alpha anomer of the sugar in its furanose form. Classify each of the following sugars. (For...
4. For each sugar below, characterize the anomer if a monosaccharide or the glycosidic bond(s) if a di- or polysaccharide (e.g., B,B-2,3; if there is more than one glycosidic bond, draw an arrow from each label to its corresponding bond). CH,OH CH2OH CH OН но н H Н H Он Н OH н OH Он Н ОН O H Но он b. a. OH H OH CH-OH O H Но ОН Н CH2OH CH2 CH2OH он OCH CH3 Но н...
8. Use the image to answer the questions that follow HO-CH HO-CH2 HO-CH2 CHO H₂o OH CHO CHO OCH CHOICH CH-OH CHCc CHOICH CH 10 | | CH-CH HỒ CH-CH CH-CH CH-CH CH-CH но он но HO он но OH OH HO A B C D Do not e How many carbons does each of the above sugars contain? Name to E n ipo Which sugars are aldoses and which are ketoses? Identify each sugar. Name the linkage for each...
Carbohydrates 1. Label each of the monosaccharides shown below as a triose, tetrose, pentoso, or hexose. но CH OH HT -он - он Н - ОН но -н но -Н но -н нон сньон он но -н НОН CH OH нон нон нон снон CH OH сон сон H- OH H- -он OH cң, он н-с-он Сн,он снон 2. Label each of the monosaccharides shown above as a ketose or aldose. 3. Identify all of the chiral carbons in the...
1) SHOW WORK STEP By STEP
below is Figure 7-3
Recognizing Epimers Using Figure 7-3, identify the epimers of (a) D-allose, (b) D-gulose, and (c) D-ribose at C-2, C-3, and C-4. Answer Epimers differ by the configuration about only one carbon. (a) D-altrose (C-2), D-glucose (C-3), D-gulose (C-4) (b) D-idose (C-2), D-galactose (C-3), D-allose (C-4) (c) D-arabinose (C-2), D-xylose (C-3) (a) D-Aldoses Three carbons Four carbons Five carbons но не HO -OH н-с-он CH, OH D-Glyceraldehyde но-с-н H-C-OH снион D-Threose...
Culhydrates 1. Complete th Complete the table by classifying each sugar sugar (A, B, C, D) below based on carbonyl group and number of carbons (c.8. aldohexose, ketotriose, etc.). Classify them as an antiomer. Indicate the number of chiral carbons for each sugar. Sugar Classification based on carbonyl group and number of carbons Lor D enantiomer Number of chiral carbons н-с-он HO-6-H. н-с-он ін,он CH,OH C=0 HO-C-H н-с-он HO-C-H. ён,он снон c=0 | HO-C-H ін,он H-C-OH CH, OH CD 2....
C=O 2. Which of the following is an example of an aldopentose? Circle your answer. СН,ОН CH,он CH н-с-он H-6-H H-C-OH HO-C-H. H-C-H H-C-OH H-C-OH H-6-H H-C-OH CH,OH CH,OH CH OH 3. In the L- isomer of a Fischer projection of a monosaccharide, the -OH group furthest from the carbonyl is written. Circle your answer. on the left of the top chiral carbon. on the left of the middle chiral carbon. on the left of the bottom chiral carbon. on...
Page Chemistry 107 Midterm II Review Problems Draw a Lewis structure for CaHN (think over the bonding preferences of each atom when you lay out the skeleton of this molecule!) 1. CC Determine the geometry at each "central atom" (a) Does this molecule have any polar bonds? Is the entire molecule polar? (b) What will be the dominant intermolecular force in a sample of this compound? (c) (c) If you had 100.0 g of this compound, how many moles would...
18.
Which of the following compound(s) would undergo mutarotation in
aqueous solution?
19. Draw the chair conformation of a-D-galactopyranose.
20. Which of the following compound(s) is a glycoside?
21. Provide the reagents neccesary to carry out the following
conversion.
22. Predict the product(s) for the following reaction.
23. D-glucose & D-galactose are ______epimers of each
other.
24. Predict the product(s) for the following reaction.
25. Which of the following compound(s) would produce D-glucose
and D-mannose when treated with HCN followed...
Please complete for Tuesday, we will go through the questions and mark them in class. pg 156 - 4.23, 4.24, 4.26 pg 170 - 4.29, 4.31, pg 171-4.36 pg 175 - 4.59 pg 176- 4.74, 4.75, 4.80 pg 177-4.81, 4.82 pg 188- 5.1, 5.4, 5.5, 5.6, 5.11 - Using Table 5.1 pg 198-5.22, 5.25 pg 203 - 5.29 pg 206 - 5.37 pg 209 - 5.39 pg 2.14 5.61 pg 235-6.11, 6.14, 6.16 156 CHAPTER 4 Introduction to Organic Compounds...
Name the following aldoses. (Include in the names the stereochemical designation D or L and, where appropriate, the configuration of the anomeric carbon, alpha or beta. This question is case-sensitive, so capitalize only the D or L.) ball & stick + labels b all & stick + labels The following model is that of an aldopentose: ball & stick - + labels Draw the alpha anomer of the sugar in its furanose form. Classify each of the following sugars. (For...
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