Solution :
The major products of the given reactions are provided below in the attached sheet.
A) Reaction is an example of reduction of acetone to secondary alcohol.
B) Reaction is an example of ketal formation.
C) Reaction is an example of reductive animation of ketone.
2. Predict the major product(s) of the following reactions: (6 points) . - NaBH4 MeOH excess...
Predict the product(s), both major and minor, of the following reactions. Indicate stereochemistry where appropriate. MeOH/heat а тюх меонтоа, а. NaOEt EtOH HCI
11. Predict the major organic product(s) for the following reactions. If there is no reaction write N.R. (6 points each, 72 points total) Show the correct stereochemistry when needed!! -OH HSO heat 1) 0, (2 equiv.) 2) Meys (2 equiv.) HC104 excess CHO NaBH4 (excess) HO CHOH Br ON HỌ, PHÚC
:. Predict the major product of the following reactions and identify if it is SN2, SNI/EI or E2. A. CNaOMe MeOH Major Products) B. NaCI DMSO Major Product(s) Mechanism C. MeOH Major Product(s) Mechanism D. Br NaShH Major Producs) Mechanism E. EtOH Major Product(s Mechanism
19.54 predict the major product(s) from the treatment of acetone with the following: 19.54 Predict the major product(s) from the treatment of acetone with the following: (a) [H*1, NH3, (-H2O) (b) [H*], CH3NH2, (-H2O) (d) [H*], (CH3)2NH, (-H2O) (c) [H*], excess ETOH, (-H2O) (e) [H*], NH2NH2, (-H2O) (f) [H*1, NH2OH, (-H2O) (g) NaBH4, MeOH (h) RCO3H (i) HCN, KCN () EtMgBr followed by H2O (k) (C&Hs)3P=CHCH2CH3 (I) LIAIH4 followed by H2O
3. Predict the major product(s) for the following reactions. (12 points) 1. BH3 THE 2. H2O2 NaOH Br2 H20 1. Hg(OAc)2 CH3OH 2. NaBH4 HBr
organic III. Predict the major product(s) or fill in the reagent(s) for the following reactions. If there is no reaction write NR. (6 points each, 36 points total) Show the correct stereochemistry when needed!! 16 HO H,Cro (excess) -CHO 17 1)0, (2 equiv.) 2) Mezs (2 equiv.) 18 Ph Ph он om Ph Ph 19 1) mCPBA 2) EtONa, EtOH 20 1) LIAIH (excess) 2) H20*, ,0+ 21 1) NaNH, 2) CH,Br 3) HBr (2 equiv.)
Question- 21. Predict the product of following reaction: (draw inside the box) NaBH4 EtOH, MeOH, or H2O Question 23. What is the IUPAC name for the following compound? OH Answer: Question 24. What is the IUPAC name for the following compound? 11111 OH Answer: Question 25: Identify the following compounds (Write their names below the structure ОН ОН
Provide the major product(s) for the following Provide the major product(s) for the following reactions. Be sure to note stereochemistry and racemic mixtures. NaOH, H29 2 100 °Ç ? NaOH, H2O H 0°C H W H CCl3 OC (provide product of both steps) H a. Hn b. CHEM 370 W13 Homework Page 1 of 2 giorel Noot Hoi solu NOEL IN DER NaOH, H2O 100 °C Hv NaOET, H OEt EtOH 8. Eto- i. LDA, -78°C NaO Me MeOH Оме...
Predict the major product(s) from the following reactions Predict the major product(s) from the following reactions: 1. O3 CH3 ? 2. DMS CH3 b) 1. CH3COH HаС. 2. H30 CH3 cat. OsO4 CH3 r-BuOOH d) .CHa ? cold CH3 0. e) CH3 CH3 На Hас ? Pt CH3 CH3 Hас 1. BH3-THF CHз 2. H2O2, NaOH g) Bг2 ? CH3OH "CHз
III. Predict the major product(s) or fill in the reagent(s) for the following reactions. If there is no reaction write NR. (6 points each, 36 points total) Show the correct stereochemistry when needed!! 16 H,Cro (excess) -CHO HO 17 1)0, (2 equiv.) 2) Mes (2 equiv.) 18 Ph Ph Ph Ph OH