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![@ Slow step is ridis. Rate = k[NO][N] Applying 38A on N, + K, [NO][Hz] – K2 [N] No] = 0 w7 K, [NO] [he] - K [Hz] [N] = Ko [](http://img.homeworklib.com/questions/dffe6b30-966b-11ea-a23a-31b65219ef9a.png?x-oss-process=image/resize,w_560)
R.D.S means rate
determining step.
S.S.A means steady state approximation.
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Reaction Mechanism Review CHM 1120 NO + H₂ + N + NON +H2O + N2O step...
Please answer each part with work shown. Thank you. 6. The following three mechanisms have been proposed for a particular reaction. Mechanism II Mechanism III Mechanisml H2 +NO-H2O+N (slow) N +...
Please answer each part with work shown. Thank you.
6. The following three mechanisms have been proposed for a particular reaction. Mechanism II Mechanism III Mechanisml H2 +NO-H2O+N (slow) N +NON2+0 (fast) O+H2-> H2O (fast) 2 NO-N202 (fast equilibrium) H2-N202-H20+ N3O (slow) H2+N20-H2O+N2 (fast) H2 + 2 NO- H2O+N2O (slow) N20+ H2N2+ H2O (fast) a) What is the overall reaction that each proposed mechanism supports? b) Calculate the ΔΗ'm for the overall reaction. c) For each mechanism, draw an energy...
QUESTION 19 A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1:...
QUESTION 19 A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1: 2NO(g) + N2O2(g) (very fast, reversible) Step 2: N2O2(g) + H2(g) → N2O(g) + H2O(g) (slow) Step 3: N2O(g) + H2(g) →N2(g) + H2O(g) (fast) What is the rate law for the overall reaction? Ok[NO]1/2[H2] k[NO]2[H2] k[NO] [H2)2 k[N20][H2] k[NO]2
A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1: 2NO(g) →...
A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1: 2NO(g) → N2O2(g) (very fast, reversible) Step 2: N2O2(g) + H2(g) → N2O(g) + H2O(g) (slow) Step 3: N2O(g) + H2(g) →N2(g) + H2O(g) (fast) What is the rate law for the overall reaction? O k[no]/2[Hz] O k[N20][H2] O k[NO]2 O k[NO]2[Hz] O k[NO]2[H212
What is the molecularity of the rate determining step in this mechanism? CH3COOC2H5 + H2O →...
What is the molecularity of the rate determining step in this mechanism? CH3COOC2H5 + H2O → CH3COOC2H6+ + OH- (Slow) CH3COOC2H6+ → CH3COOH + C2H5+ (Fast) C2H5+ + OH- → C2H5OH (Fast) A. unimolecular B. tetramolecular C. bimolecular D. termolecular E. need additional information
1. a) Overall reaction: Rate = k[NO]^2 2NO(g)+H2(g)-> N2O(g)+H2O(g) propose a likely two step reaction mechanism...
1. a) Overall reaction: Rate = k[NO]^2 2NO(g)+H2(g)-> N2O(g)+H2O(g) propose a likely two step reaction mechanism for this reaction.
QUESTION 9 A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1:...
QUESTION 9 A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1: 2NO(g) → N2O2(g) (very fast, reversible) Step 2: N2O2(g) + H2(g) → N2O(g) + H2O(g) (slow) Step 3: N2O(g) + H2(g) →N2(g) + H2O(g) (fast) What is the rate law for the overall reaction? k[N2O][H2] k[NO]2[H2] k[NO]2[H2]2 k[NO]1/2[H2] k[NO]2
The nitrogen-monoxide-catalyzed decomposition of dinitrogen monoxide is thought to proceed by a two-step mechanism: NO(g) +...
The nitrogen-monoxide-catalyzed decomposition of dinitrogen monoxide is thought to proceed by a two-step mechanism: NO(g) + N2O(g) --> N2(g) + NO2(g) (slow) 2 NO2(g) --> 2 NO(g) + O2(g) (a) If the first step of this mechanism is rate-determining (slow), choose the correct rate law for the overall process. Rate = k [N2O]2 Rate = k [NO] [NO2] Rate = k [N2O]2 [N2O] Rate = k [NO2] [N2O] Rate = k [N2O] [N2O] Rate = k [NO] [N2O] (b) Choose...
1) 2) 3) A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step...
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2)
3)
A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1: 2NO(g) + N2O2(g) (very fast, reversible) Step 2: N2O2(g) + H2(g) N20(g) + H20(g) (slow) Step 3: N2O(g) + H2(g) →N2(g) +H2O(g) (fast) What is the rate law for the overall reaction? Ok[NO2 Ok[NO]2[H212 O k[NO]2[H2] Ok[N20][H2] k[NO]1/2[H2] 2NO(g) +Cl2 (g) → NOCI (8) Experiment concentration of NO (M) 0.09 0.045 0.045 concentration of Cl2(M) Rate (M/s) 0.01 3.40 x 10-4 8.50 x...
A three-step mechanism has been suggested for the formation of carbonyl chloride: Step 1: Cl2 ===> 2 Cl (fast equlibrium) Step 2: Cl + CO ===> COCl (fast equilibrium) Step 3: COCl + Cl2 ===> COCl2 + Cl (slow) What is the molecularit
1. A three-step mechanism has been suggested for the formation of carbonyl chloride: Step 1: Cl2 ===> 2 Cl (fast equlibrium) Step 2: Cl + CO ===> COCl (fast equilibrium) Step 3: COCl + Cl2 ===> COCl2 + Cl (slow) What is the molecularity of the rate-determining step? unimolecular bimolecular termolelcular none of these 2. The elementary reaction representing the formation of ozone, O2(g) + O(g) + M(g) ===> O3(g) + M*(g) is an example of a _________ reaction. unimolecular...
사oposedmechanism for the decomposition ofozone in the stratosphere is Step 2: ClO(8)+0,)Cl(g)+2 0(8 What is the...
사oposedmechanism for the decomposition ofozone in the stratosphere is Step 2: ClO(8)+0,)Cl(g)+2 0(8 What is the molecularity of step 11? a. zeromolecular b. unimolecular c. bimolecular e. More information is needed. 4. A proposed mechanism for the reduction of nitrogen as NO by hydrogen is: Step 1: H2(2)+2 NOG)-N+H) Step 2: NO(g)+H2(g) → N2(g) + HO(g) What is the rate law for step 1? (slow) (fast) e. More information is needed. c. 서Halz[NO] 5. The mechanism forthe first-order reaction 2HOfag)→2HOO-gin...
Please answer each part with work shown. Thank you.
6. The following three mechanisms have been proposed for a particular reaction. Mechanism II Mechanism III Mechanisml H2 +NO-H2O+N (slow) N +NON2+0 (fast) O+H2-> H2O (fast) 2 NO-N202 (fast equilibrium) H2-N202-H20+ N3O (slow) H2+N20-H2O+N2 (fast) H2 + 2 NO- H2O+N2O (slow) N20+ H2N2+ H2O (fast) a) What is the overall reaction that each proposed mechanism supports? b) Calculate the ΔΗ'm for the overall reaction. c) For each mechanism, draw an energy...
QUESTION 19 A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1: 2NO(g) + N2O2(g) (very fast, reversible) Step 2: N2O2(g) + H2(g) → N2O(g) + H2O(g) (slow) Step 3: N2O(g) + H2(g) →N2(g) + H2O(g) (fast) What is the rate law for the overall reaction? Ok[NO]1/2[H2] k[NO]2[H2] k[NO] [H2)2 k[N20][H2] k[NO]2
A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1: 2NO(g) → N2O2(g) (very fast, reversible) Step 2: N2O2(g) + H2(g) → N2O(g) + H2O(g) (slow) Step 3: N2O(g) + H2(g) →N2(g) + H2O(g) (fast) What is the rate law for the overall reaction? O k[no]/2[Hz] O k[N20][H2] O k[NO]2 O k[NO]2[Hz] O k[NO]2[H212
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A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1: 2NO(g) + N2O2(g) (very fast, reversible) Step 2: N2O2(g) + H2(g) N20(g) + H20(g) (slow) Step 3: N2O(g) + H2(g) →N2(g) +H2O(g) (fast) What is the rate law for the overall reaction? Ok[NO2 Ok[NO]2[H212 O k[NO]2[H2] Ok[N20][H2] k[NO]1/2[H2] 2NO(g) +Cl2 (g) → NOCI (8) Experiment concentration of NO (M) 0.09 0.045 0.045 concentration of Cl2(M) Rate (M/s) 0.01 3.40 x 10-4 8.50 x...
사oposedmechanism for the decomposition ofozone in the stratosphere is Step 2: ClO(8)+0,)Cl(g)+2 0(8 What is the molecularity of step 11? a. zeromolecular b. unimolecular c. bimolecular e. More information is needed. 4. A proposed mechanism for the reduction of nitrogen as NO by hydrogen is: Step 1: H2(2)+2 NOG)-N+H) Step 2: NO(g)+H2(g) → N2(g) + HO(g) What is the rate law for step 1? (slow) (fast) e. More information is needed. c. 서Halz[NO] 5. The mechanism forthe first-order reaction 2HOfag)→2HOO-gin...
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