Dots represent the lone pair of electrons. So, the complete reaction with the step wise arrow pushing mechanism is given as below:-
Draw ALL possible unimolecular elimination (E1) products formed under the reaction conditions below; don't worry about...
"Complete the reactions showing all Major Products, both substitution and elimination, that can form based on the reaction conditions. Be sure to show stereochemistry where appropriate. Fill in each table with reaction conditions." w upiete the following reactions showing all products, both substitution and elimination, that can form, then circle the MAJOR Foduct(s). Under each reaction, draw the step by step mechanism showing how each porduct is formed. Show or indicate stereochemistry where appropriate. Fill in each table with reaction...
8. Draw the catalytic cycle (all key steps) for the proline-catalyzed reaction below. Don't worry about the absolute stereochemistry of the product 10 pts COOH H H + NO2 8. Draw the catalytic cycle (all key steps) for the proline-catalyzed reaction below. Don't worry about the absolute stereochemistry of the product 10 pts COOH H H + NO2
Alkyl Halides: Elimination reaction with (2R,3R)-2-chloro-3-methylpentane Draw the product formed when (2R,3R)-2-chloro-3-methylpentane under-goes an elimination reaction with NaOCH3. Alkyl Halides: Elimination reaction with 3-chloro-3-ethyl-2,2-dimethylpentane. Draw the structure of the product that is formed when 3-chloro-3-ethyl-2,2-dimethylpentane undergoes an elimination reaction with NaOCH3. Indicate the stereochemistry of the product. Identify the three products formed when 2-bromo-2-methylpropane is dissolved in a mixture of 80% ethanol and 20% water.
7. Under the following conditions, three products are formed in this reaction. OH H2O a. Draw the mechanism that leads to the product that is the least likely to form in the space below. (7pts) b. In the space below, explain why that product is the most likely to form. You should be able to justify your answer. (4pts)
Draw all possible products formed when the compound shown below undergoes reaction with 1 equivalent of Br2. Interactive 3D display mode
2. Draw two possible products for the reaction shown below. Are your products formed as a racemic mixture? Which of your two products do you expect to be the major one? Why? 1 equiv. Br2 THF possible product 1 possible product 2 Possible product 1 a racemic mixture? Yes No Possible product 2 a racemic mixture? Yes No Which would be major? Why?
2. Draw two possible products for the reaction shown below. Are your products formed as a racemic mixture? Which of your two products do you expect to be the major one? Why? 1 equiv. VON Br2 THE possible product 1 possible product 2 Possible product la racemic mixture? Yes No Possible product 2 a racemic mixture? Yes No Which would be major? Why?
HW 5 1. Draw all possible products for the base catalyzed reaction of ethanal and propanal. Indicate the new bond formed. (Full: all possible products and correct ID of new bond, partial: 75% of possible products) 2. Draw and label the kinetic and thermodynamic products for reacting the following ketone with LDA. (Full: correct products and labeling, partial: correct products but no labels) 1. LDA 2 CH31 3. Show the mechanism for the following intramolecular reaction. You do NOT need...
3. As we will soon lean, under certain reaction conditions it is possible to react hydrocarbons to give all possible monochloro derivatives as products, i.e. where one C-H bond is replaced by a C-Cl bond. The following isomers with the formula CsH12 were reacted under these conditions to produce products with the formula CsH11C CsH1Cl. Using various physical experimental methods it is possible to separate all of the possible CsH11CI isomers derived from each CSH12 isomer. Draw Kekulé or bond-...
help Thank you 4. (10 pts) Draw all possible products for the following reaction including stereoisomers. Note that the addition occurs through a "syn" mechanism. Is the product solution optically active (yes or no)? 1. BAHATHF 2. NaOH, HO (8 pts) Provide a complete mechanism for the reaction below and include lone-pairs of electrons and formal charges. Show all products formed including stereoisomers. Is the product solution optically active (yes or no)? Bras 11. (8 pts) Draw all four regiochemical...