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4. The decomposition of N2Os in the gas phase is first order in N Os. If...
The first-order rate constant for the gas-phase decomposition of N2O5 to NO2 and O2 at 65oC is 4.87 x 10-3/sec. (a) If a chemist starts with 0.550 moles of N2O5 in a 500.0 ml container, how many moles of N2O5 will remain after 18.0 minutes? (b) How long will it take for the quantity of N2O5 to drop to 0.0550 moles? 14. The first-order rate constant for the gas-phase decomposition of N205 to NO2 and O2 at 65℃ is 4.87...
The rate constant for the decomposition of N,Os(8) at a certain temperature is 1.70x10sl. (a) If the initial concentration of N;O(8) is 0.200 mol/L, How long will it take for the concentration to fall to 0.100 mol/L? (b) What will the concentration of N:Os(8) be after 16 hours of reaction?
The decomposition of N2Os in CCl is a first-order reaction. If 3.98 mg of N20s is present initially and 3.91 mg is present after 3.13 minutes at 53 °C, what is the value of the rate constant? Rate constant- min-1
14.44 The first-order rate constant for the decomposition of N205, 2N205(g)-→ 4 NO2(g) + O2(g), at 70°C is 6.82 × 10-3 s-1. Suppose we start with 0.250 mol of N205(g) 1S in a volume of 2.0 L. (a) How many moles of N2O5 will re- main after 10.0 min? (b) How many minutes will it take for the quantity of N205 to drop to 0.100 mol? (c) What is the half-life, in minutes, of N2Os at 70 °C?
6 (a) N2Os decomposes in the gas phase by the reaction: 2 N2Os (g)4 NO2 (g)+02 (g) At 25°C, a sample of gaseous N2Os showed the following dependence of concentration on time: IN:Os(mmol dm Time/h C0 8.0 5 4.3 10 2.3 15 1.20 0.64 20 ( Determine the order of reaction by plotting an appropriate graph. [5 marks] [2 marks] (ii) Determine the rate constant for this reaction. (ii) Find the concentration of NO2 after 25 h. [2 marks] 6...
6. (a) The rate constant for the first-order decomposition of N2Os in the reaction, 2 N2Os(g)-4 NO(g)+0.(g), k-3x10-s at 25°C. What is the half-life of N20s? What will be the pressure, initially 500 bar, at 10 min after initiation of the reaction? (b) Knowing the activation energy of the above reaction is 100 kJ mor', calculate the required reaction temperature at which the reaction rate is doubled. (c) What is the conversion efficiency of N20s at 1 bar and 25...
Be sure to answer all parts. The gas-phase decomposition of peroxyacetyl nitrate (PAN) obeys first-order kinetics: CH3COOONO2 + CH3C000 + NO2 with a rate constant of 4.9 x 10-45-1. Calculate the rate of decomposition (in M/s) if the concentration of PAN is 0.35 ppm by volume. Assume STP conditions. rate= x 100 M/s (Enter your answer in scientific notation.)
NO (g) + 10, is studied at 383°C, giving 7. The gas-phase decomposition of NO, (g) the following data: (8 pts) Submit graph Time (s) [NO,](M) 0 0.100 5 0.017 10 0.009 15 0.0062 20 0.0047 (A) Is the reaction first order or second order with respect to the concentration of NO, by graphical method? (B) What is the value of the rate constant?
1. a. The gas phase decomposition of sulfuryl chloride at 600 K SO2Cl2(g) -------> SO2(g) + Cl2(g) is first order in SO2Cl2 with a rate constant of 2.80×10-3 min-1. If the initial concentration of SO2Cl2 is 5.84×10-3 M, the concentration of SO2Cl2 will be _____M after 618 min have passed. b. The gas phase decomposition of dimethyl ether at 500 °C CH3OCH3(g)-------->CH4(g) + H2(g) + CO(g) is first order in CH3OCH3 with a rate constant of 4.00×10-4 s-1. If the...
* 100%- 6 (a) NOs decomposes in the gas phase by the reaction: 2 N2Os (g) 4 NO2 (9)+ 02 (9) At 25'C, a sample of gaseous N,O, showed the following dependence of concentration on time: IN2Os/(mmol dm-3) 8.0 4.3 2.3 1.20 0.64 Time/h 10 15 20 (0 Determine the order of reaction by plotting an appropriate graph. (i) Determine the rate constant for this reaction. () Find the concentration of NO2 after 25 h [5 marks] [2 marks] 12...