Question

6. (a) The rate constant for the first-order decomposition of N2Os in the reaction, 2 N2Os(g)-4 NO(g)+0.(g), k-3x10-s at 25°C. What is the half-life of N20s? What will be the pressure, initially 500 bar, at 10 min after initiation of the reaction? (b) Knowing the activation energy of the above reaction is 100 kJ mor, calculate the required reaction temperature at which the reaction rate is doubled. (c) What is the conversion efficiency of N20s at 1 bar and 25 °C when the reaction reaches the chemical equilibrium? When the total pressure increases to 100 bar, what is the new conversion efficiency? The standard Gibbs energies of formation for N2Os(g) and NO2(g) are 115.1 kJ mol and 51.31 kJ mor-1, respectively.

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0.693 6) a)Half-life of N,Os,t,- 0.693 3x10-3s-1 - 2.31x101s For first order reaction s00bar10min 1min 60s 3x10 S In 00bar0.0

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