Provide the products and
mechanism
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Provide the products and
mechanism
a) CH CH2CH,OH (excess) Ht b) ) LDA 2) O 3)...
COLUMNA 0 NO2 19 COLUMN B O + OH OH A) HAN AICI: 1) ch 2...
COLUMNA 0 NO2 19 COLUMN B O + OH OH A) HAN AICI: 1) ch 2 BHA 3) H,09 B) YN B 1) My C) ОН 2) 2)CO2 3) H30 4) CH3OH D) 3) E) 0 OH H 1)DBAL-H 2)Ph PCH2 3) mCPBA 1) SOCI2 2CH.NH. pyridine 3) excess LAHA 4)H,0* F) 0 O 4) OH o G) excess HB H) 5) 1) 6) H30* Δ. Mglk J) 7) OH 0 2 1,0 hp question completion Status: Н. 6) Н...
2) CHs LDA 1) LDA 3 2) Ci OH, H20 -OH, H2O CHO 1 LDA 2)...
2) CHs LDA 1) LDA 3 2) Ci OH, H20 -OH, H2O CHO 1 LDA 2) CH3CH2Br Он, H2O 1) NaOEt 8 2) NaOEt OEt 10 Cl NaH 2 (excess) 12 HO Bra(excess) 13 HO LDA 14L THF, -78 C NaOEt, EtOH NaOEt, EtOH 16 NaOEt, EtOH 17 Br но 18 OOEt 1)NaOEt, EtOH 2) H3O 19 OEt 20 l HO o CHO + H20
(2) NaBH4 (2) H202 OH cold, dilute KMnO4 "ОН H,C H,C HCO,H H,O с-с CH CH2CH,...
(2) NaBH4 (2) H202 OH cold, dilute KMnO4 "ОН H,C H,C HCO,H H,O с-с CH CH2CH, CH,CH2CH Predict the major products of the following reactions, including stereochemistry where appropriate. (a) (R)-2-butanol + TsCl in pyridine c) cyclooctanol + CrO3/H2SO4 (e) cyclopentylmethanol + Na2Cr 01/H2SO4 (g) n-butanol + HBr (i) potassium t-butoxide + methyl iodide (k) cyclopentanol + H2SO4/heat (m) sodium ethoxide +1-bromobutane (b) (S)-2-butyl tosylate +NaBr (d) cyclopentylmethanol + CrOs pyridine HC cyclopentanol + HCI/ZnCl2 (h) cyclooctylmethanol + CH3CH2MgBr (G)...
Provide the major product for the following reactions: b. NaH, THF CH Br 1.1 eq LDA,...
Provide the major product for the following reactions:
b. NaH, THF CH Br 1.1 eq LDA, THF D O NaOD 1. LDA (1.1 eq) 2. CH2CH 3. LDA (1.1 eq, -78 °C) 4. CH 1 equiv. Br2 NaOH, H2O
Provide the major product or reagents OH (a-b) K-OH excess OH NaHCO, (c-d) 1. SOCI 2....
Provide the major product or reagents
OH (a-b) K-OH excess OH NaHCO, (c-d) 1. SOCI 2. NH OH e-t) NH 1. кон 2. CH CH CH.BI 3. NHANH H. Hy Pd 22 ?? (g-h) NH NO (g-k) OH 1. CH 2. Ag,0 3. heat 1. CH 2. Ag, 3. heat (l-m) NH OH ?? ?? (n-o) CI (p-1) 1. Mg, other 2.CO 3.H.,0,H CH,CHÁNH, H+ Δ ?? 1" O 1. LAIH4 CH,CH,OH, H осн. A 2. H,O, H.
Provide the product for the following reaction І. Br HOCH,CH,OH Mg/ether H2SO, Н,0° 2. H,0 но...
Provide the product for the following reaction І. Br HOCH,CH,OH Mg/ether H2SO, Н,0° 2. H,0 но он ОН он IV он у Predict the product of the following synthesis. 1. Br2, H20 2. NaOH, HO 3. CH2OH, H+ OCH, н,со OCH, A B с OCH OCH OCH, D E Predict the product for the following reaction. OH Acid Catalyst + 25 °C O А D с B
Draw the arrows for the 7-step mechanism in formation of the mixed acetal shown. Map CH,OH...
Draw the arrows for the 7-step mechanism in formation of the mixed acetal shown. Map CH,OH OH mi # + HO ht Mixed ACETAL HEMIACETAL click to edit H. 0 Step он H Step w HỘ One H Two HⓇ H H 16 Step 3. Step HÖCH3 Step + H H Five Four Step 6 Draw the arrows for the 7-step mechanism for hydrolysis of an acetal to a carbonyl. Map . H2O Hö: H,O L; E i + CH,CH,OH...
5.59 Provide the products and balance the following reac tion for the complete combustion of pentane,...
5.59 Provide the products and balance the following reac tion for the complete combustion of pentane, C;H12 Identify the reactant that is oxidized and the reactant 5.65 that is reduced. CsH12) 02() 5.60 Provide the products and balance the following reac- tion for the complete combustion of the fatty acid octanoic acid, C H1602. Identify the reactant that is oxidized and the reactant that is reduced. CgH1602(s) O2 (g) 5.62 Identify the reactant that is oxidized and the reactant that...
List in Order (a) 0 EtNH, (excess) ОН H2SO4 (cat.) OCH3 + CH,OH (excess) + H2O...
List in Order
(a) 0 EtNH, (excess) ОН H2SO4 (cat.) OCH3 + CH,OH (excess) + H2O CI NH -02 S- HÓ: OH Hd 0–CH OCH CI LOH Hac +N-H H NH A HON A HO OH H ---CH ام وی ام H 0 CH Step #1 Step #2 Step #3 D E H2O, H2SO4 (cat.) ОН Step #1 Step #2 Step #3 Step #4 Step #5 Step #6 N ОН 0 H S- HO HO NH 0 H sos-0 B...
Enol fom Kets (om Provide the structure of the major products A, B, and C formed...
Enol fom Kets (om Provide the structure of the major products A, B, and C formed in each of the synthesis routes below. 2 OH EtzNH H cat Br в 1) г 2) H,о* CrO3, H2SO Hао C A (-H2O) С- 2 2EIOH 1)Hg(OAc)2, THF A Но C H' cat (-H2O) 2) NaBH OAc O2CCHy он dk pEt &0- 1) POCI DMF Ph,P CHCO Me A Pd/C c) Me в C Hа 2) NaHCO3 (aq) Me CHa CHICO me CH...
COLUMNA 0 NO2 19 COLUMN B O + OH OH A) HAN AICI: 1) ch 2 BHA 3) H,09 B) YN B 1) My C) ОН 2) 2)CO2 3) H30 4) CH3OH D) 3) E) 0 OH H 1)DBAL-H 2)Ph PCH2 3) mCPBA 1) SOCI2 2CH.NH. pyridine 3) excess LAHA 4)H,0* F) 0 O 4) OH o G) excess HB H) 5) 1) 6) H30* Δ. Mglk J) 7) OH 0 2 1,0 hp question completion Status: Н. 6) Н...
2) CHs LDA 1) LDA 3 2) Ci OH, H20 -OH, H2O CHO 1 LDA 2) CH3CH2Br Он, H2O 1) NaOEt 8 2) NaOEt OEt 10 Cl NaH 2 (excess) 12 HO Bra(excess) 13 HO LDA 14L THF, -78 C NaOEt, EtOH NaOEt, EtOH 16 NaOEt, EtOH 17 Br но 18 OOEt 1)NaOEt, EtOH 2) H3O 19 OEt 20 l HO o CHO + H20
(2) NaBH4 (2) H202 OH cold, dilute KMnO4 "ОН H,C H,C HCO,H H,O с-с CH CH2CH, CH,CH2CH Predict the major products of the following reactions, including stereochemistry where appropriate. (a) (R)-2-butanol + TsCl in pyridine c) cyclooctanol + CrO3/H2SO4 (e) cyclopentylmethanol + Na2Cr 01/H2SO4 (g) n-butanol + HBr (i) potassium t-butoxide + methyl iodide (k) cyclopentanol + H2SO4/heat (m) sodium ethoxide +1-bromobutane (b) (S)-2-butyl tosylate +NaBr (d) cyclopentylmethanol + CrOs pyridine HC cyclopentanol + HCI/ZnCl2 (h) cyclooctylmethanol + CH3CH2MgBr (G)...
Provide the major product for the following reactions:
b. NaH, THF CH Br 1.1 eq LDA, THF D O NaOD 1. LDA (1.1 eq) 2. CH2CH 3. LDA (1.1 eq, -78 °C) 4. CH 1 equiv. Br2 NaOH, H2O
Provide the major product or reagents
OH (a-b) K-OH excess OH NaHCO, (c-d) 1. SOCI 2. NH OH e-t) NH 1. кон 2. CH CH CH.BI 3. NHANH H. Hy Pd 22 ?? (g-h) NH NO (g-k) OH 1. CH 2. Ag,0 3. heat 1. CH 2. Ag, 3. heat (l-m) NH OH ?? ?? (n-o) CI (p-1) 1. Mg, other 2.CO 3.H.,0,H CH,CHÁNH, H+ Δ ?? 1" O 1. LAIH4 CH,CH,OH, H осн. A 2. H,O, H.
Provide the product for the following reaction І. Br HOCH,CH,OH Mg/ether H2SO, Н,0° 2. H,0 но он ОН он IV он у Predict the product of the following synthesis. 1. Br2, H20 2. NaOH, HO 3. CH2OH, H+ OCH, н,со OCH, A B с OCH OCH OCH, D E Predict the product for the following reaction. OH Acid Catalyst + 25 °C O А D с B
Draw the arrows for the 7-step mechanism in formation of the mixed acetal shown. Map CH,OH OH mi # + HO ht Mixed ACETAL HEMIACETAL click to edit H. 0 Step он H Step w HỘ One H Two HⓇ H H 16 Step 3. Step HÖCH3 Step + H H Five Four Step 6 Draw the arrows for the 7-step mechanism for hydrolysis of an acetal to a carbonyl. Map . H2O Hö: H,O L; E i + CH,CH,OH...
5.59 Provide the products and balance the following reac tion for the complete combustion of pentane, C;H12 Identify the reactant that is oxidized and the reactant 5.65 that is reduced. CsH12) 02() 5.60 Provide the products and balance the following reac- tion for the complete combustion of the fatty acid octanoic acid, C H1602. Identify the reactant that is oxidized and the reactant that is reduced. CgH1602(s) O2 (g) 5.62 Identify the reactant that is oxidized and the reactant that...
List in Order
(a) 0 EtNH, (excess) ОН H2SO4 (cat.) OCH3 + CH,OH (excess) + H2O CI NH -02 S- HÓ: OH Hd 0–CH OCH CI LOH Hac +N-H H NH A HON A HO OH H ---CH ام وی ام H 0 CH Step #1 Step #2 Step #3 D E H2O, H2SO4 (cat.) ОН Step #1 Step #2 Step #3 Step #4 Step #5 Step #6 N ОН 0 H S- HO HO NH 0 H sos-0 B...
Enol fom Kets (om Provide the structure of the major products A, B, and C formed in each of the synthesis routes below. 2 OH EtzNH H cat Br в 1) г 2) H,о* CrO3, H2SO Hао C A (-H2O) С- 2 2EIOH 1)Hg(OAc)2, THF A Но C H' cat (-H2O) 2) NaBH OAc O2CCHy он dk pEt &0- 1) POCI DMF Ph,P CHCO Me A Pd/C c) Me в C Hа 2) NaHCO3 (aq) Me CHa CHICO me CH...
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