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Provide the major product or reagents OH (a-b) K-OH excess OH NaHCO, (c-d) 1. SOCI 2....
Provide the major product or reagents 1. KOH (1-1) NH 2 CH CHÚCH_Br 3. NHẠNH H., Hy Pd ?? 22 (g-h) NH NO2 (g-k) -NEN OH CI 1. CH 2. Ag,0 3. heat 1. CH! 2. Ag,0 3. heat OH NHA 2? ?? (n-o) CI (p-1) 1. Mg, other 2. CO2 3. H.0, H. CH,CHÁNH, H. A ?? 1. LAIH4 CH,CH,OH, H Осн. 2. H,OH
40. (38) Predict the product or provide reagents needed to complete each transformation. OH (a-b) K+-OH excess OH OF 1. SOCI Na+ HCO3- (c-d) 2. NH3 OH 1. KOH 2. CH CH CH Br ol (e-t) NH 3. NHANH H, H2, Pd ?? ?? (g-h) 'Ng NH2 NO2 (g-k) NEN OH 1. CH3 2. Ag20 3. heat 1. CH 2. Ag2O 3. heat (I-m) NH2 OH ?? NEN ?? (n-O) CI CI CI 1. Mg, ether 2. CO2 CH3CH2NH2, H+...
40. (38) Predict the product or provide reagents needed to complete each transformation. OH A (a-b) K-OH excess OH Na+ HCO3-. (c-d) 1. SOCI 2. NH, OH 1. KOH 2. CH3CH2CH Br a H (e-f) NH 3. NHỊNH H, Hz. Pd ?? ?? (g-h) N3 NH2 NOZ (g-k) -NEN OH CI N 1. CH3 2. Ag20 3. heat 1. CHE 2. Ag20 3. heat (l-m) NH2 ?? NEN OH ?? (n-0) CI CI CI CI (put) 1. Mg, ether 2.Co,...
39.(44) Predict the product or provide reagents needed to complete each transformation (a-b) CI benzene AICI CHẠNH (c-d) но (CH,CH) CML (e-) ОН CH₃CH₂OH (g-h) LIAHOCICH hb (-1) 1. LIAIH 2. H HO 1. LIAH 2. " H снуснон CHỊCHẠNH, (I-m) H, OH, heat (m-n) 1. LIAH 2.H (oxygen 18 labeled water) H.O.H. heat 1. LAIH 2. H (o-p) 1. HCM HO.H'.heat (9-4) -CEN 2. HOH (5-1) CEN 1. LAIH 2. H Page 3 of 9 40 (38) Predict the...
Reactions and Reagents 17,37 Draw the product formed when pentanal (CH,CH,CH,CH,CHO) is treated with each reagent. With some reagents, no reaction occurs. a. NaBH. CH,OH e. Na,Cr,O, H,SO4, H,0 1. [1] (CH3)2CuLi; [2] HO b. [1] LIAIH[2] H,0 f. Ag,O, NH,OH J. [1] HCCN: (2] H,0 c. Hz. Pd-C g. (1] CHẠMgar, [2] HẠO k. [CH,CECLI: [2] H,0 d. PCC b. [1] CH, LH: (2] HẠO 1. The product in (a), then TBDMS-CI, Imidazole
Provide the major product or reagents (a-b) lon benzene AICI CHỌN но (c-d) (CH,CH) Cuu lor. OH (1-1) ogo ogo ago age og Look CH,CH, OH (g-h) LIAIHIOCCHala 1. LAIH 2. H (6-1) HO (k-1) 1. LIATH 2.H H (l-m) CH.CH OH CH,CHẠNH, (m-n) H, 180, H heat (oxygen 18 labeled water) 1. LIAIH 2.H (0-2) H,0,H", heat 1. LAIH 2. H H,0Hheat (q-1) 1. CHỊCH,Mger 2. HẠO, H" CEN C-NH CIN 1. LIATH 2.H
What reagents are required to carry out the following synthesis? A. SOCI B. CH CH/AICI: C. LiAIHA D. KMnO E. HNO3 H2SO4 F. NaCN G. NH; H. Fe, Hz0+ J. CH3CH2MgBr/H30+ K. Cl/FeCl3 LOH OH - CH3NH, CH2NH2 Identify the following as a primary, secondary, tertiary, or quaternary amine. CHE CH3----NH2 CH3 primary secondai O tertiary O quaternary
39.(44) Predict the product or provide reagents needed to complete each transformation. (a-b) benzene AICI OH CH3NH2 H20 (c-d) (CH3CH2)2Culi OH (e-f) Rok CH3CH2OH (g-h) ogle LAIH[OC(CH3)als (1-1) 1. LAIHA 2. H HO (k-1) 1. LiAIHA 2. H+ H+ (I-m) CH3CH OH CH3CH2NH2 H2180, H+, heat 1. LAIH4 (m-n) 2. H+ (oxygen 18 labeled water) 0= (0-p) H,0,H*, heat 1. LIAIH 2. H 1. CH3CH2MgBr H20, H+, heat (q-r) CEN 2. H.0, H+ L & NHz 1. LAIH CEN (s-t)...
Draw the major product(s) or reagents for the following reactions. Pay attention to sterochemistry where appropriate. 1. Draw the major product(s) or reagents for the following reactions. Pay attention to stereochemistry where appropriate. Put a box or circle around your final answer. xs ethyl lodide ..^ NH Note 3 oy bolo NO2 1. Sn, HCI 2. NaHCO, 3. [H"). NaBH,CN. acetone 1. КОН NH BI 3. HANNHKOH heat 1. HNO, HASO 2. Sn, HCI 3. NaOH 4. NaNO,, HCI 5....
6. Provide structures of the products in the boxes (40 points) лон CHO 1 Li 2. Hy-Pa 2. H.O 1. HOCH,CH,OH, TOH(cat) 1. LAH 2. H,0 2. LAH 3. H,0 1. CH,MgBr 2. H,0 2.HO 1. SOCI 1.0 2. H,O, 2. CH,OH L. excess SOC Ag HCI 2. CH,OH, Heat