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Provide the major product or reagents 1. KOH (1-1) NH 2 CH CHÚCH_Br 3. NHẠNH H.,...
Provide the major product or reagents
OH (a-b) K-OH excess OH NaHCO, (c-d) 1. SOCI 2. NH OH e-t) NH 1. кон 2. CH CH CH.BI 3. NHANH H. Hy Pd 22 ?? (g-h) NH NO (g-k) OH 1. CH 2. Ag,0 3. heat 1. CH 2. Ag, 3. heat (l-m) NH OH ?? ?? (n-o) CI (p-1) 1. Mg, other 2.CO 3.H.,0,H CH,CHÁNH, H+ Δ ?? 1" O 1. LAIH4 CH,CH,OH, H осн. A 2. H,O, H.
40. (38) Predict the product or provide reagents needed to complete each transformation. OH (a-b) K+-OH excess OH OF 1. SOCI Na+ HCO3- (c-d) 2. NH3 OH 1. KOH 2. CH CH CH Br ol (e-t) NH 3. NHANH H, H2, Pd ?? ?? (g-h) 'Ng NH2 NO2 (g-k) NEN OH 1. CH3 2. Ag20 3. heat 1. CH 2. Ag2O 3. heat (I-m) NH2 OH ?? NEN ?? (n-O) CI CI CI 1. Mg, ether 2. CO2 CH3CH2NH2, H+...
40. (38) Predict the product or provide reagents needed to complete each transformation. OH A (a-b) K-OH excess OH Na+ HCO3-. (c-d) 1. SOCI 2. NH, OH 1. KOH 2. CH3CH2CH Br a H (e-f) NH 3. NHỊNH H, Hz. Pd ?? ?? (g-h) N3 NH2 NOZ (g-k) -NEN OH CI N 1. CH3 2. Ag20 3. heat 1. CHE 2. Ag20 3. heat (l-m) NH2 ?? NEN OH ?? (n-0) CI CI CI CI (put) 1. Mg, ether 2.Co,...
7. Predict the major organic product or provide reagents needed to complete each reaction. 1. CH3NH2 (a-b) excess 2. LIAIHA 3. H20 ia -NH ?? excess (c-d) HO NH2 triethylamine ? (e-f) CEN 1. CHẠMgBr 2. H20, H NH2 (g-h) H20, H* H2. Pd (1-1) CH3NH2 4 products (m) 1. LAIH 2. H2O, H & NH (n) 1. LiAIH4 2. H20, H+ 8. Predict the four possible Aldol condensation products and their dehydration products. KOH, H20.A + H 1. Predict...
Reactions and Reagents 17,37 Draw the product formed when pentanal (CH,CH,CH,CH,CHO) is treated with each reagent. With some reagents, no reaction occurs. a. NaBH. CH,OH e. Na,Cr,O, H,SO4, H,0 1. [1] (CH3)2CuLi; [2] HO b. [1] LIAIH[2] H,0 f. Ag,O, NH,OH J. [1] HCCN: (2] H,0 c. Hz. Pd-C g. (1] CHẠMgar, [2] HẠO k. [CH,CECLI: [2] H,0 d. PCC b. [1] CH, LH: (2] HẠO 1. The product in (a), then TBDMS-CI, Imidazole
39.(44) Predict the product or provide reagents needed to complete each transformation (a-b) CI benzene AICI CHẠNH (c-d) но (CH,CH) CML (e-) ОН CH₃CH₂OH (g-h) LIAHOCICH hb (-1) 1. LIAIH 2. H HO 1. LIAH 2. " H снуснон CHỊCHẠNH, (I-m) H, OH, heat (m-n) 1. LIAH 2.H (oxygen 18 labeled water) H.O.H. heat 1. LAIH 2. H (o-p) 1. HCM HO.H'.heat (9-4) -CEN 2. HOH (5-1) CEN 1. LAIH 2. H Page 3 of 9 40 (38) Predict the...
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3. Show the products formed in the tollowing reactions draw two enols 1) Mg. Et O 2) CO2 3) H:O NHz Jo .OTo. 쁘. pyridne CI NH Ci CI 0 SOCl OH heat NH 1) CH3MgBr excess CH, CH, -OCH,C 2) H2O COOMe LIAIH OH Ci 0
3. Show the products formed in the tollowing reactions draw two enols 1) Mg. Et O 2) CO2 3) H:O NHz Jo .OTo. 쁘. pyridne CI NH Ci CI
0...
Provide the major product or reagents
(a-b) lon benzene AICI CHỌN но (c-d) (CH,CH) Cuu lor. OH (1-1) ogo ogo ago age og Look CH,CH, OH (g-h) LIAIHIOCCHala 1. LAIH 2. H (6-1) HO (k-1) 1. LIATH 2.H H (l-m) CH.CH OH CH,CHẠNH, (m-n) H, 180, H heat (oxygen 18 labeled water) 1. LIAIH 2.H (0-2) H,0,H", heat 1. LAIH 2. H H,0Hheat (q-1) 1. CHỊCH,Mger 2. HẠO, H" CEN C-NH CIN 1. LIATH 2.H
2) Fill in each of the following boxes with the structure of the major reaction product(s) from each of the following reactions. (28 points total). a) Pd(PPhale NaOH b) + Pd(OA) (CH CHN CN 1. NaBH 2. H2O HH OH но -н H- OH HH OH CH,OH HNO, но NH,OH trace of acid 1. CHI (excess 2. Ag,0 H2O, heat CI 1 CRUS POY Grubbs catalyst) Page 2 of 5
Give the product(s) of reaction of hexanal with each of the following reagents. 2. (0) носн,сн,он, н (b) 1. LIAIH, 2. H,0* (e) NH,он, н" (d) NH,NH2, KOH, heat (e) (CH),СHCH,CH— P(C, Нә» , н" (g) Ag, NH, H,O (h) CrOs, H,SO H,0 () 1. KCN, 2. H,SO MCPBA
Give the product(s) of reaction of hexanal with each of the following reagents. 2. (0) носн,сн,он, н (b) 1. LIAIH, 2. H,0* (e) NH,он, н" (d) NH,NH2, KOH, heat (e) (CH),СHCH,CH—...