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7. Predict the major organic product or provide reagents needed to complete each reaction. 1. CH3NH2...
1. Predict the four possible Aldol condensation products and their dehydration products. in KOH, H20,4 2. Provide a mechanism for the following transformation. CH,CH, OK CH.CH,OH, heat 3. Predict all possible Claisen condensation products plus their decarboxylation products. ao 1. KOE 2.H.O. 3. heat wybos 4. Predict the product of the Dieckmann cyclization. 1. KOEI 2.H.0. 3. heat
39.(44) Predict the product or provide reagents needed to complete each transformation. (a-b) got / benzene AICI CI ОН CH3NH2 via H2O (c-d) N (CH3CH2)2Culi OH (e-t) CI CH,CH, OH *K (g-h) 1. LIAIHA LIAIH[OC(CH3)al 2. H но 1. LIAIHA (k-1) 2. H H CH3CH2OH CH3CH2NH2 (l-m) H2180, H heat (m-n) 1. LIAIH 2. H (oxygen 18 labeled water) H20, H heat 1. LIAIHA (0-p) 2. H H20.H, heat (9-1) 1. CH3CH2MgBr H20, H CEN 1. LAIH -CEN (s-t) 2....
5. Predict the product of the Robinson Annulation. sigue KOH, H20, heat 6. Predict the major organic products. 1. LIAIHA 2. H+ CH3CH2CH.SK 1. CH3CH_MgBr 2. H+ CH3CH2OH (CH2CH)Culi KCN H20 7. Predict the two possible products of the intramolecular Aldol condensation. chlo KOH, H20, heat
39.(44) Predict the product or provide reagents needed to complete each transformation. (a-b) benzene AICI OH CH3NH2 H20 (c-d) (CH3CH2)2Culi OH (e-f) Rok CH3CH2OH (g-h) ogle LAIH[OC(CH3)als (1-1) 1. LAIHA 2. H HO (k-1) 1. LiAIHA 2. H+ H+ (I-m) CH3CH OH CH3CH2NH2 H2180, H+, heat 1. LAIH4 (m-n) 2. H+ (oxygen 18 labeled water) 0= (0-p) H,0,H*, heat 1. LIAIH 2. H 1. CH3CH2MgBr H20, H+, heat (q-r) CEN 2. H.0, H+ L & NHz 1. LAIH CEN (s-t)...
6. Predict the major organic products. coinotas griollot rrot minados sbiy 1. LIAIHA 2. H+ ROHO CH3CH2CH2S-K 1. CH2CH2MgBr 2. H+ CH3CH OH (CH2CH2)Culi KCN H20 obou noslzodobrioritaskibog nomabb bin oldieroa lie 7. Predict the two possible products of the intramolecular Aldol condensation. KOH, H20, heat
40. (38) Predict the product or provide reagents needed to complete each transformation. OH A (a-b) K-OH excess OH Na+ HCO3-. (c-d) 1. SOCI 2. NH, OH 1. KOH 2. CH3CH2CH Br a H (e-f) NH 3. NHỊNH H, Hz. Pd ?? ?? (g-h) N3 NH2 NOZ (g-k) -NEN OH CI N 1. CH3 2. Ag20 3. heat 1. CHE 2. Ag20 3. heat (l-m) NH2 ?? NEN OH ?? (n-0) CI CI CI CI (put) 1. Mg, ether 2.Co,...
40. (38) Predict the product or provide reagents needed to complete each transformation. OH (a-b) K+-OH excess OH OF 1. SOCI Na+ HCO3- (c-d) 2. NH3 OH 1. KOH 2. CH CH CH Br ol (e-t) NH 3. NHANH H, H2, Pd ?? ?? (g-h) 'Ng NH2 NO2 (g-k) NEN OH 1. CH3 2. Ag20 3. heat 1. CH 2. Ag2O 3. heat (I-m) NH2 OH ?? NEN ?? (n-O) CI CI CI 1. Mg, ether 2. CO2 CH3CH2NH2, H+...
39.(44) Predict the product or provide reagents needed to complete each transformation (a-b) CI benzene AICI CHẠNH (c-d) но (CH,CH) CML (e-) ОН CH₃CH₂OH (g-h) LIAHOCICH hb (-1) 1. LIAIH 2. H HO 1. LIAH 2. " H снуснон CHỊCHẠNH, (I-m) H, OH, heat (m-n) 1. LIAH 2.H (oxygen 18 labeled water) H.O.H. heat 1. LAIH 2. H (o-p) 1. HCM HO.H'.heat (9-4) -CEN 2. HOH (5-1) CEN 1. LAIH 2. H Page 3 of 9 40 (38) Predict the...
39.(44) Predict the product or provide reagents needed to complete each transformation. (a-b) benzene AICI OH CH3NH2 H2O (c-d) ogle oglase (CH3CH2)2Culi OH (e-t) CH3CH2OH (g-h) LIAIH[OC(CH3)als (1-1) 1. LIAIH4 2. H H2O (k-1) 1. LIAIH4 2. H H (I-m) CH3CH NH2 CH3CH2OH (m-n) H2190, H+, heat (oxygen 18 labeled water) 1. LIAIH 2. H (0-p) H,0,H*, heat 1. LIAIHA 2. H H,0,H-, heat (9-1) 1. CH3CH2MgBr 2. H2O, H CEN (s-t) -C-NH₂ -CEN 1. LIAH 2. H
2. Predict the product. CH,CH NH2 NH 1. LiAlH 2. H20 Br H30 KOH 1. excess CH1 2. Ag20, H20 heat