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For each of the following cyclohexane derivatives, indicate (i) whether the molecule is a cis or...
9. Draw two different chair conformations of cyclohexanol, showing all hydropen atoms. Identify each position as...
9. Draw two different chair conformations of cyclohexanol, showing all hydropen atoms. Identify each position as axial or equatorial 10. Draw the most stable chair conformation of the following molecules, and estimate the amount of strain in each: (a) trans-1-Chloro-3-methylcyclohexane (b) cis-1-Ethyl-2-methylcyclohexane (c) cis-1-Bromo-4-ethylcyclohexane (d) cis-1-tert-Butylcyclohexane 11. Which isomer is more stable, cis-decalin or trans-decalin? Explain. 12. Glucose exists in two forms having a 36:64 ratio at equilibrium. Draw a skeletal structure of each, describe the difference between them and...
please answer all parts. your the best :) 4. For each compound below, draw the most...
please answer all parts. your the best :)
4. For each compound below, draw the most stable chair conformation. Do no draw in the hydrogen atoms. For clarity, circle all non-hydrogen substituents that are in an axial position. It may help to number the carbons in each chair first before drawing in cach substituent. (3pts for each correct conformation properly drawn) 5. (a) Convert Compound A (shown below) to its chair-like structure by placing the substituents of this compound in...
6. Provide the IUPAC names for the compounds below Name: 7. Draw the following: cis-1-isobutyl-2-propyleyclopentane 8....
6. Provide the IUPAC names for the compounds below Name: 7. Draw the following: cis-1-isobutyl-2-propyleyclopentane 8. Label the indicated atoms in the structure below as 1º, 2º, 3º, or 4º. PB A A B co 9. Draw Newman projections for the day-diethylane about the C4CS bond, Circle the most stable conforme if you need additional space, please feel free to the backside of this paper 10. Draw the chair conformation and ring-flip for the given compound. Calculate the sterie strain...
I. name the following compounds II. write structures for each of the followong structires III.Arrange alkenes from most...
I.
name the following compounds
II. write structures for each of the followong
structires
III.Arrange alkenes from most to least stable
IV. if rearrangement is expected, draw rearranged structure
for wach carbocation
V.
PLEASE HELP, ive been struggling in organic and this is the
review for our 3rd exam. if i can get help (and explanations) for
1-4 it would be a big help
CHM 2210 Examination 3 11/02/18 Directions: Please supply all answers in the spaces provided on both...
H 9. For each molecule: 1) Identify all possible enantiomers and distinguish those that are enantiomers, diastereomers...
H 9. For each molecule: 1) Identify all possible enantiomers and distinguish those that are enantiomers, diastereomers and meso compounds. II) Assign the absolute configuration of chiral carbons in each molecule OCH3 HO+Br HS+CN H2N-CH3 HOSH Он HO+CH3 н OCH3 Сн, ососна Br +D HOCH HC-BrHN+Br CH 8. For the following compounds, assign the absolute configuration for those with chiral carbons and identify those that are NOT enantiomers HO C-C-OHY -CCIN 13CH3 HAN CH3 CH3 осі H-CH3 H2N+CH H O+COOH...
For letters h & i : For each of the following reactions, predict the major mechanistic pathway (SN1/SN2/E1/E2...
For
letters h & i :
For each of the following reactions, predict the major
mechanistic pathway (SN1/SN2/E1/E2) and the major organic
products
1. (cont.) (h) НСОН CHB -CHBr HCOH - (0) CH,CH,CH,CH,Br- NH 2. For each of the following indicate which reaction will occur faster. Explain your reasoning. (No credit will be given for guesses) (a) The reaction of (CH),CBr with 0.001M aqueous NaOH or 0.10M aqueous NaOH (b) The reaction of 2-bromobutane with NaOH in DMSO or NaSH...
(C) Protonation of alkene to form a carbocation followed by addition of bromide ion (D) Addition...
(C) Protonation of alkene to form a carbocation followed by addition of bromide ion (D) Addition of the proton to one face of the alkene with simultaneous delivery of a bromide ion from a different molecule of H-Br. 11. Which compound is the strongest nmucleophile for reaction of methane methanesulfonate (CHOS0.CH) in methanol at room temperature? (You may assume that everything is soluble in methanol) (A) potassium bromide (B) cesium iodide (C) sodiam chloride (D) lithium flaoride 12. Which proton...
9. Draw two different chair conformations of cyclohexanol, showing all hydropen atoms. Identify each position as axial or equatorial 10. Draw the most stable chair conformation of the following molecules, and estimate the amount of strain in each: (a) trans-1-Chloro-3-methylcyclohexane (b) cis-1-Ethyl-2-methylcyclohexane (c) cis-1-Bromo-4-ethylcyclohexane (d) cis-1-tert-Butylcyclohexane 11. Which isomer is more stable, cis-decalin or trans-decalin? Explain. 12. Glucose exists in two forms having a 36:64 ratio at equilibrium. Draw a skeletal structure of each, describe the difference between them and...
please answer all parts. your the best :)
4. For each compound below, draw the most stable chair conformation. Do no draw in the hydrogen atoms. For clarity, circle all non-hydrogen substituents that are in an axial position. It may help to number the carbons in each chair first before drawing in cach substituent. (3pts for each correct conformation properly drawn) 5. (a) Convert Compound A (shown below) to its chair-like structure by placing the substituents of this compound in...
6. Provide the IUPAC names for the compounds below Name: 7. Draw the following: cis-1-isobutyl-2-propyleyclopentane 8. Label the indicated atoms in the structure below as 1º, 2º, 3º, or 4º. PB A A B co 9. Draw Newman projections for the day-diethylane about the C4CS bond, Circle the most stable conforme if you need additional space, please feel free to the backside of this paper 10. Draw the chair conformation and ring-flip for the given compound. Calculate the sterie strain...
I.
name the following compounds
II. write structures for each of the followong
structires
III.Arrange alkenes from most to least stable
IV. if rearrangement is expected, draw rearranged structure
for wach carbocation
V.
PLEASE HELP, ive been struggling in organic and this is the
review for our 3rd exam. if i can get help (and explanations) for
1-4 it would be a big help
CHM 2210 Examination 3 11/02/18 Directions: Please supply all answers in the spaces provided on both...
H 9. For each molecule: 1) Identify all possible enantiomers and distinguish those that are enantiomers, diastereomers and meso compounds. II) Assign the absolute configuration of chiral carbons in each molecule OCH3 HO+Br HS+CN H2N-CH3 HOSH Он HO+CH3 н OCH3 Сн, ососна Br +D HOCH HC-BrHN+Br CH 8. For the following compounds, assign the absolute configuration for those with chiral carbons and identify those that are NOT enantiomers HO C-C-OHY -CCIN 13CH3 HAN CH3 CH3 осі H-CH3 H2N+CH H O+COOH...
For
letters h & i :
For each of the following reactions, predict the major
mechanistic pathway (SN1/SN2/E1/E2) and the major organic
products
1. (cont.) (h) НСОН CHB -CHBr HCOH - (0) CH,CH,CH,CH,Br- NH 2. For each of the following indicate which reaction will occur faster. Explain your reasoning. (No credit will be given for guesses) (a) The reaction of (CH),CBr with 0.001M aqueous NaOH or 0.10M aqueous NaOH (b) The reaction of 2-bromobutane with NaOH in DMSO or NaSH...
(C) Protonation of alkene to form a carbocation followed by addition of bromide ion (D) Addition of the proton to one face of the alkene with simultaneous delivery of a bromide ion from a different molecule of H-Br. 11. Which compound is the strongest nmucleophile for reaction of methane methanesulfonate (CHOS0.CH) in methanol at room temperature? (You may assume that everything is soluble in methanol) (A) potassium bromide (B) cesium iodide (C) sodiam chloride (D) lithium flaoride 12. Which proton...
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