Question

Consider the following cell at 25°C. Pt | Hg(l) | Hg2Clz(s) | HCl(aq,0.500 mol kgr) | Cl2(g) | Pt (i) Write the appropriate reduction half-reactions for the system above.(4) (i) Write the Nemst equation for the cell reaction. (ii) Assuming that the Debye-Hückel Limiting Law holds at the given concentration, calculate the potential E for the cell. (iv) Calculate for the cell reaction.

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Reductio cathode OW rea atio 2 NOuw eq cathod half cell + anode half cell 2 Cl20 c/ 0 V0 ヒニビーo.o59 cl elATI = 1.1185V 2 1.1185-0.059 (0、S) 2 ー -208.44 EJ

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