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![bH OHLe • The axial groups as in [L] are HO [1] . heat oth bath and OH Hkd to are • The equatorial groups in (1 A. OH and d.H](http://img.homeworklib.com/questions/67d3daa0-a00d-11ea-8b79-576250e970c5.png?x-oss-process=image/resize,w_560)
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For each compound drawn below, label each OH, Br, and CH kroup as axial or equatorial....
Provide the product for the following reaction І. Br HOCH,CH,OH Mg/ether H2SO, Н,0° 2. H,0 но...
Provide the product for the following reaction І. Br HOCH,CH,OH Mg/ether H2SO, Н,0° 2. H,0 но он ОН он IV он у Predict the product of the following synthesis. 1. Br2, H20 2. NaOH, HO 3. CH2OH, H+ OCH, н,со OCH, A B с OCH OCH OCH, D E Predict the product for the following reaction. OH Acid Catalyst + 25 °C O А D с B
Propose mechanisms consistent with the following reactions 8-48 H.SO н.о Br HBr ъ) Он (а) ROOR...
Propose mechanisms consistent with the following reactions 8-48 H.SO н.о Br HBr ъ) Он (а) ROOR Br СHBE, Вг Br Вг HЕr (d) NaOH осH CH, Cl Вr НС Br Br CH CH OH Cн CH, Он Н н'. Н,о Он Н "сн CH, CH,CH CH,CH Он н' (g) CH Oн осн, н CH—С-С (h) 2 н Н Н Н
Propose mechanisms consistent with the following reactions 8-48 H.SO н.о Br HBr ъ) Он (а) ROOR Br СHBE, Вг Br...
Carbohydrates 1. Label each of the monosaccharides shown below as a triose, tetrose, pentoso, or hexose....
Carbohydrates 1. Label each of the monosaccharides shown below as a triose, tetrose, pentoso, or hexose. но CH OH HT -он - он Н - ОН но -н но -Н но -н нон сньон он но -н НОН CH OH нон нон нон снон CH OH сон сон H- OH H- -он OH cң, он н-с-он Сн,он снон 2. Label each of the monosaccharides shown above as a ketose or aldose. 3. Identify all of the chiral carbons in the...
Q11. The correct structure of trans-1-bromo-3-methyl cyclopentane is ...Br (A) (B) -Br Br (C) (D) *Br...
Q11. The correct structure of trans-1-bromo-3-methyl cyclopentane is ...Br (A) (B) -Br Br (C) (D) *Br Q12. The correct order of increasing stability for the following conformations is CH, H Н. Н H H H CH2CH3 H Н CH,CH CH CH3CH2 CH H2C CH, H CH, I II III (A) III < III (C) II <I<III (B) I<III <II (D) I< II < III Q13. Identify the relationship between the following two Newman projections. CH, H НАС. H Н;С. Н...
4. For each sugar below, characterize the anomer if a monosaccharide or the glycosidic bond(s) if...
4. For each sugar below, characterize the anomer if a monosaccharide or the glycosidic bond(s) if a di- or polysaccharide (e.g., B,B-2,3; if there is more than one glycosidic bond, draw an arrow from each label to its corresponding bond). CH,OH CH2OH CH OН но н H Н H Он Н OH н OH Он Н ОН O H Но он b. a. OH H OH CH-OH O H Но ОН Н CH2OH CH2 CH2OH он OCH CH3 Но н...
1. (23 pts.) Label each stereocenter (chiral center) as Ror S. Label each molecule as chiral or achiral. CH ен-он H...
1. (23 pts.) Label each stereocenter (chiral center) as Ror S. Label each molecule as chiral or achiral. CH ен-он H- CH3 . Он CH2OH Сн,он h) н он В ньон нон НО-Б-н ен,он но- н H-LOH CH OH
What is the major product of the following multistep reaction? Brz Br 3 eg NaNH و0...
What is the major product of the following multistep reaction? Brz Br 3 eg NaNH و0 ? H2O OH OH HO OH H في المجال المسلم H0 CH B C D E OD CA E C B What is the Major product of the following reaction? 1. BH3, THE 2. NaOH, H2O2 ? ОН ОН Н ОН A В с D E Ос о A E О
Which of the following structures is not a phosphoester? (А) NH (В) Ос "CH₂ НО-Р-он о...
Which of the following structures is not a phosphoester? (А) NH (В) Ос "CH₂ НО-Р-он о О н ни ОН ОН ОН (c) NH (D) N О о" 9-ро Od-o CHz но-р-оснусн; H он Онон Select one (А)
Which is the major product of this reaction? CN 1. Et MgBr 2. acid workup our...
Which is the major product of this reaction? CN 1. Et MgBr 2. acid workup our order on one A B C D A B С D Which compound is a D-isomer? Н. Н. T НО- -Н НО——н НО -Н Н——он Но——Н НО- H -Н он І Н. -он H- -он НО -Н НО -Н CH2OH НО- Н -ОН НО -Н СН2ОН Н. -он НОН Сньон CH OH А B с D OA B Ос D
30. Which of the choices below is the enantiomer of D-glucose? сно сно нон HO-EH сно...
30. Which of the choices below is the enantiomer of D-glucose? сно сно нон HO-EH сно на-он D-glucose Іно-Ен н -он но-Ен EH,OH сно но н-он но -н нон Сн,он но-Ен на-он но -н но-Ен н -он нон CHO но -н н-он но-Ен нон снен CHOH Сн,он 3. Which of the following structures is an a-anomer? Сн,он —о, он o ноноон нонс осн он — о оно сн, он он онон он он он он тон КСн,он y CH, OH...
Provide the product for the following reaction І. Br HOCH,CH,OH Mg/ether H2SO, Н,0° 2. H,0 но он ОН он IV он у Predict the product of the following synthesis. 1. Br2, H20 2. NaOH, HO 3. CH2OH, H+ OCH, н,со OCH, A B с OCH OCH OCH, D E Predict the product for the following reaction. OH Acid Catalyst + 25 °C O А D с B
Propose mechanisms consistent with the following reactions 8-48 H.SO н.о Br HBr ъ) Он (а) ROOR Br СHBE, Вг Br Вг HЕr (d) NaOH осH CH, Cl Вr НС Br Br CH CH OH Cн CH, Он Н н'. Н,о Он Н "сн CH, CH,CH CH,CH Он н' (g) CH Oн осн, н CH—С-С (h) 2 н Н Н Н
Propose mechanisms consistent with the following reactions 8-48 H.SO н.о Br HBr ъ) Он (а) ROOR Br СHBE, Вг Br...
Carbohydrates 1. Label each of the monosaccharides shown below as a triose, tetrose, pentoso, or hexose. но CH OH HT -он - он Н - ОН но -н но -Н но -н нон сньон он но -н НОН CH OH нон нон нон снон CH OH сон сон H- OH H- -он OH cң, он н-с-он Сн,он снон 2. Label each of the monosaccharides shown above as a ketose or aldose. 3. Identify all of the chiral carbons in the...
Q11. The correct structure of trans-1-bromo-3-methyl cyclopentane is ...Br (A) (B) -Br Br (C) (D) *Br Q12. The correct order of increasing stability for the following conformations is CH, H Н. Н H H H CH2CH3 H Н CH,CH CH CH3CH2 CH H2C CH, H CH, I II III (A) III < III (C) II <I<III (B) I<III <II (D) I< II < III Q13. Identify the relationship between the following two Newman projections. CH, H НАС. H Н;С. Н...
4. For each sugar below, characterize the anomer if a monosaccharide or the glycosidic bond(s) if a di- or polysaccharide (e.g., B,B-2,3; if there is more than one glycosidic bond, draw an arrow from each label to its corresponding bond). CH,OH CH2OH CH OН но н H Н H Он Н OH н OH Он Н ОН O H Но он b. a. OH H OH CH-OH O H Но ОН Н CH2OH CH2 CH2OH он OCH CH3 Но н...
1. (23 pts.) Label each stereocenter (chiral center) as Ror S. Label each molecule as chiral or achiral. CH ен-он H- CH3 . Он CH2OH Сн,он h) н он В ньон нон НО-Б-н ен,он но- н H-LOH CH OH
What is the major product of the following multistep reaction? Brz Br 3 eg NaNH و0 ? H2O OH OH HO OH H في المجال المسلم H0 CH B C D E OD CA E C B What is the Major product of the following reaction? 1. BH3, THE 2. NaOH, H2O2 ? ОН ОН Н ОН A В с D E Ос о A E О
Which of the following structures is not a phosphoester? (А) NH (В) Ос "CH₂ НО-Р-он о О н ни ОН ОН ОН (c) NH (D) N О о" 9-ро Od-o CHz но-р-оснусн; H он Онон Select one (А)
Which is the major product of this reaction? CN 1. Et MgBr 2. acid workup our order on one A B C D A B С D Which compound is a D-isomer? Н. Н. T НО- -Н НО——н НО -Н Н——он Но——Н НО- H -Н он І Н. -он H- -он НО -Н НО -Н CH2OH НО- Н -ОН НО -Н СН2ОН Н. -он НОН Сньон CH OH А B с D OA B Ос D
30. Which of the choices below is the enantiomer of D-glucose? сно сно нон HO-EH сно на-он D-glucose Іно-Ен н -он но-Ен EH,OH сно но н-он но -н нон Сн,он но-Ен на-он но -н но-Ен н -он нон CHO но -н н-он но-Ен нон снен CHOH Сн,он 3. Which of the following structures is an a-anomer? Сн,он —о, он o ноноон нонс осн он — о оно сн, он он онон он он он он тон КСн,он y CH, OH...
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