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42. Use retrosynthesis to design a way of making each of the following target molecules. The...
Design a multi-step synthesis for each of the following target molecules from the indicated starting material. Show the reagents needed for each step and the product of each step. Do not show any mechanisms. Draw the structures of the diene and the dienophile that reacted to form the Diels-Alder product shown. Provide the missing reagents in this multistep synthesis.
Use retrosynthesis to design a synthesis of each target using the starting material and any reagents containing three carbons or less. 5. Target Starting Material Target Starting Material OH COH H C Dis Explain why an electron pair in an sp hybrid orbital is lower in potential energy than an electron pair in an sp hybrid 6. H orbital. Explain why ethy ne is more acidic than 7 ethene or ethane. H-CRCE pk, s0 Construct an explanation for why the...
Design a synthesis of each of the following target molecules starting from methylcyclohexene and any noncyclic reagents.
1. Provide a complete retrosynthesis and forward synthesis of the target molecule below from the given starting materials. All carbons of the target must be from the given starting materials. You may use any reagents you find necessary. You may include more than one step over a reaction arrow, but please no more than 3 steps at a time. Please show the key intermediates in your synthesis for partial credit. (10 bonus points) For full credit, include a retrosynthetic analysis,...
Page 1 Synthesis using Carbonyl O-Substitution Chemistry Preamble This experiment involves the synthesis of target molecules using a-substitution chemistry. You are assigned two target molecules, one of which is best synthesized by an alkylation approach, while the other is best synthesized by an addition or condensation approach. You must do the following: 1. Perform a retrosynthetic analysis on the two target molecules assigned to you. In each case the organic starting material (what you have to work backwards toward) depends...
For 1 - 3, design reasonable syntheses of each of the target molecules using the provided starting material and organic and inorganic reagents of your choice. Show the reagents needed for each step and the product of each step. Do not show any mechanisms. Please put all your answers on this sheet. Write your answers like this (actual number of starting steps may vary)material reagent(s) reagent(s) ABCD target Two equally reasonable routes are possible Can you find them both? (For...
Synthesis using Carbonyla-Substitution Chemistry Preamble This experiment involves the synthesis of target molecules using a-substitution chemistry. You are assigned two target molecules, one of which is best synthesized by an alkylation approach, while the other is best synthesized by an addition or condensation approach. My two target molecules are number 2 and number 12 in the last page. You must do the following: 1. Perform a retrosynthetic analysis on the two target molecules assigned to you. In each case the...
Show the products for the following reactions. Propose starting materials that can form the following product in one step. NaOH, Br2 d. PCls. Br2 он e. 4. Propose starting materials that can form the following product in one step Compound Z Synthesize the starting materials you proposed above from Ethanal and ethyl acetate (do not use other carbonyl compounds). You can use ethanal and ethyl acetate as many times as you need to. Hint: you will use the 3 carbon-carbon...
BE Map. The Claisen condensation converts 2 molecules of an ester into a B-keto ester. The reaction starts with the ester in an alkoxide/alcohol solution and is worked up with acid to form the neutral B-keto ester product. Show the curved-arrow mechanism for the Claisen condensation of ethyl ethanoate treated with ethoxide ion. :0: :0: 1. -OCH2CH/CH3CH2OH 2 2. H30* Mechanism Tutorial Step 1a. Classify step Mechanism steps can be classified into a few key processes. Knowing these key processes...
To carryout a synthesis from my target molecules which is label as #20. I choose p-anisidine and/or p-toluidine as my "starting materials" and here is a list of reagents to get to my target molecules. Can you show me the way what is the correct way to do synthesis to get to my target molecules. CH3 ОН , Hood Numbers: 4,12, 20) Reagents: The reagents listed below will be available, stored according to hazard class. Requests for reagents not listed...