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-3.60. The 111 position in the fcc structure is a "tetrahe- dral site," an interstice with...
2. Elemental Si crystallizes with a diamond cubic structure is shown at right below. The Si...
2. Elemental Si crystallizes with a diamond cubic structure is shown at right below. The Si atoms form an foc unit cell with a certain fractions of the tetrahedral sites occupied. a) How many octahedral sites_ and how many tetrahedral sites____ are there per unit cell. How many tetrahedral sites are occupied __ per unit cell. b) How many si atoms per unit cell (or within unit cell) ___ (justify your answer below) c) What is the coordination of the...
2. FCC Structure-Assemble the structure and answer the following: a. What is the length of the...
2. FCC Structure-Assemble the structure and answer the following: a. What is the length of the face diagonal in terms of the lattice constant "a"? b. What is the length of the face diagonal in terms of the atomic radius "r"? c. What is the linear atomic density along the body diagonal? (Number of Atoms/Length) d. What is the linear atomic density along the face diagonal? e. How many atomic volumes are contained in the unit cell? **Remember atoms at...
3. A compound comprising of Pt and N is calculated to adopt the cubic structure shown...
3. A compound comprising of Pt and N is calculated to adopt the cubic structure shown below (a derivative of the zinc blende structure). The Pt atoms form an fcc unit cell and N atoms occupy all tetrahedral sites. Please answer the following questions regarding this compound and its structure. (a) Identify the N atoms as either large spheres or small spheres (b) Indicate the coordination of the Natoms (show below (c) What is the formula of the compound how...
3.- The Perovskite structure (CaTiOs) can be described as an FCC packing of Ca2* and O2 ions on which Ti4+ occupies of the octahedral sites, located in the cube center. Data, ionic radii, r(Ca2+)-0.1...
3.- The Perovskite structure (CaTiOs) can be described as an FCC packing of Ca2* and O2 ions on which Ti4+ occupies of the octahedral sites, located in the cube center. Data, ionic radii, r(Ca2+)-0.106 nm; r(0%)-0.132 nm; r(Ti4+)-0.036 nm; atomic mass, M(Ca)-40.08; M(O)-16.00; M(Ti)-47.90. Calculate: a) The volume of the unit cell b) The packing factor c) The linear density (ions/nm) in the direction [111] d) The planar density (ions/nm2) in the planes (111) and (200) e) The volumetric density...
Given Values Atomic Radius (nm) = 0.18 FCC Metal = Silver BCC Metal: = Sodium Temperature...
Given Values Atomic Radius (nm) = 0.18 FCC Metal = Silver BCC Metal: = Sodium Temperature (c) = 1127 Metal A = Zinc Equilibrium Number of Vacancies (m^-3) = 7.42E + 23 Temperature for Metal A = 247 Metal B = Calcium If the atomic radius of a metal is the value shown above and it has the face-centered cubic crystal structure, calculate the volume of its unit cell in nm^3 Your Answer = What is the atomic packing factor...
1. (7 points) Consider a face-centered cubic (fcc) lattice: (a) (2 points) Draw a 3D primitive...
1. (7 points) Consider a face-centered cubic (fcc) lattice: (a) (2 points) Draw a 3D primitive unit cell structure (b) (2 points) Sketch the placement of atoms on a (100) plane. Express distances between atoms on the plane in terms of lattice constant (a). (c) (1 point) How many atoms are there per primitive unit cell? (d) (1 point) How many nearest neighbor atoms are there for each atom? (e) (1 point) Assume a lattice constant of Inm. Determine the...
2. (3 points) In lab, you will form complexes using different ligands. Use your lab manual to identify and draw the str...
2. (3 points) In lab, you will form complexes using different ligands. Use your lab manual to identify and draw the structural formula (lewis formula) for the following: a. A charged monodentate ligand (answer cannot be a halide ion) b. A polydentate ligand c. The CO ligand, not used in the laboratory. Is it likely CO can form a coordinate covalent bond from more than one atom? Explain. NC CN Ni Geometry of Coordination Compounds A compounds geometry (i.e., how...
Simple Cubic (SC) Structure 1. Write the Miller indices for the family of close-packed directions in...
Simple Cubic (SC) Structure 1. Write the Miller indices for the family of close-packed directions in the SC crystal. <hkl>= 2. Write the expression for theoretical density of a material with SC structure in terms of atomic radius (R), atomic weight (A), and Avogadro's number (NA). (Show your work.) 3. Calculate the planar density for the most densely packed SC planes in terms of atomic radius (R). (Show your work.) PD Body-Centered Cubic (BCC) Structure 4. How many non-parallel close-packed...
--Given Values-- Atomic Radius (nm) = 0.116 FCC Metal = Gold BCC Metal: = Sodium Temperature...
--Given Values-- Atomic Radius (nm) = 0.116 FCC Metal = Gold BCC Metal: = Sodium Temperature ( C ) = 1017 Metal A = Tin Equilibrium Number of Vacancies (m-3) = 6.02E+23 Temperature for Metal A = 369 Metal B = Gallium 1) If the atomic radius of a metal is the value shown above and it has the face-centered cubic crystal structure, calculate the volume of its unit cell in nm3? Write your answers in Engineering Notation. ...
9. Rhenium oxide has a cubic structure with the Re atoms sitting at the eight corners...
9. Rhenium oxide has a cubic structure with the Re atoms sitting at the eight corners of the cube and the (O) atoms half way along the 12 edges of the cube: (a) Draw the structure and place the Re and O atoms in their positions (b) What is the molecular formula? contributions Explain your answer using fractional Re and O (c) What is the oxidation number of Re? (d) How many formula units per cell?, (e) Is the unit...
2. Elemental Si crystallizes with a diamond cubic structure is shown at right below. The Si atoms form an foc unit cell with a certain fractions of the tetrahedral sites occupied. a) How many octahedral sites_ and how many tetrahedral sites____ are there per unit cell. How many tetrahedral sites are occupied __ per unit cell. b) How many si atoms per unit cell (or within unit cell) ___ (justify your answer below) c) What is the coordination of the...
2. FCC Structure-Assemble the structure and answer the following: a. What is the length of the face diagonal in terms of the lattice constant "a"? b. What is the length of the face diagonal in terms of the atomic radius "r"? c. What is the linear atomic density along the body diagonal? (Number of Atoms/Length) d. What is the linear atomic density along the face diagonal? e. How many atomic volumes are contained in the unit cell? **Remember atoms at...
3. A compound comprising of Pt and N is calculated to adopt the cubic structure shown below (a derivative of the zinc blende structure). The Pt atoms form an fcc unit cell and N atoms occupy all tetrahedral sites. Please answer the following questions regarding this compound and its structure. (a) Identify the N atoms as either large spheres or small spheres (b) Indicate the coordination of the Natoms (show below (c) What is the formula of the compound how...
3.- The Perovskite structure (CaTiOs) can be described as an FCC packing of Ca2* and O2 ions on which Ti4+ occupies of the octahedral sites, located in the cube center. Data, ionic radii, r(Ca2+)-0.106 nm; r(0%)-0.132 nm; r(Ti4+)-0.036 nm; atomic mass, M(Ca)-40.08; M(O)-16.00; M(Ti)-47.90. Calculate: a) The volume of the unit cell b) The packing factor c) The linear density (ions/nm) in the direction [111] d) The planar density (ions/nm2) in the planes (111) and (200) e) The volumetric density...
Given Values Atomic Radius (nm) = 0.18 FCC Metal = Silver BCC Metal: = Sodium Temperature (c) = 1127 Metal A = Zinc Equilibrium Number of Vacancies (m^-3) = 7.42E + 23 Temperature for Metal A = 247 Metal B = Calcium If the atomic radius of a metal is the value shown above and it has the face-centered cubic crystal structure, calculate the volume of its unit cell in nm^3 Your Answer = What is the atomic packing factor...
1. (7 points) Consider a face-centered cubic (fcc) lattice: (a) (2 points) Draw a 3D primitive unit cell structure (b) (2 points) Sketch the placement of atoms on a (100) plane. Express distances between atoms on the plane in terms of lattice constant (a). (c) (1 point) How many atoms are there per primitive unit cell? (d) (1 point) How many nearest neighbor atoms are there for each atom? (e) (1 point) Assume a lattice constant of Inm. Determine the...
2. (3 points) In lab, you will form complexes using different ligands. Use your lab manual to identify and draw the structural formula (lewis formula) for the following: a. A charged monodentate ligand (answer cannot be a halide ion) b. A polydentate ligand c. The CO ligand, not used in the laboratory. Is it likely CO can form a coordinate covalent bond from more than one atom? Explain. NC CN Ni Geometry of Coordination Compounds A compounds geometry (i.e., how...
Simple Cubic (SC) Structure 1. Write the Miller indices for the family of close-packed directions in the SC crystal. <hkl>= 2. Write the expression for theoretical density of a material with SC structure in terms of atomic radius (R), atomic weight (A), and Avogadro's number (NA). (Show your work.) 3. Calculate the planar density for the most densely packed SC planes in terms of atomic radius (R). (Show your work.) PD Body-Centered Cubic (BCC) Structure 4. How many non-parallel close-packed...
9. Rhenium oxide has a cubic structure with the Re atoms sitting at the eight corners of the cube and the (O) atoms half way along the 12 edges of the cube: (a) Draw the structure and place the Re and O atoms in their positions (b) What is the molecular formula? contributions Explain your answer using fractional Re and O (c) What is the oxidation number of Re? (d) How many formula units per cell?, (e) Is the unit...
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