2. (3 points) In lab, you will form complexes using different ligands. Use your lab manual to identify and draw the str...
For each of the following metal complexes, specify the number of ligands, the coordination number of the metal, the oxidation number of the metal, the geometry of the complex and draw the structure. Transition metal complexes with four ligands usually form tetrahedral structures unless the metal has a d8 configuration, in which case it can form either tetrahedral or square planar structures. NH4[Co(NCS)4(py)2] [RhBr(CO)5](NO3)2 K4[Fe(CN)6] [HgI4]2- [Cu(NH3)4]Cl2
Complex # of Coordination number Oxidation number Complex Structure ligands geometry NH4Co(NCS)(py): [RhBr(CO)s(NO) K[Fe(CN) [Hgl.] Cu(NH)Cl 3. What are the bond angles for the following geometries: Tetrahedral Linear Square planar_ Octahedral 4. A complex ion contains tungsten(II) bound to 4 water molecules and 2 fluoride ions. Using appropriate conventions write out its formula. 5. A complex ion contains copper(II) bonded to ethylenediamine and two water molecules. Using appropriate conventions write out its formula. Complex # of Coordination number Oxidation number...
1. Elements in Group 6A most commonly have an oxidation state of −2. a. True b. False 2. What is the noble gas core for Cu? a. He b. Kr c. Xe d. Rn e. Ar f. Ne 3. What will be the geometry of [CoCl2(NH3)4]? a. Square planar b. Linear c. Octahedral d. Tetrahedral e. Trigonal Bipyramid 4. What is the coordination number of Pt in [Pt(NH3)4]Cl2? a. 4 b. 3 c. 5 d. 1 e. 0 f. 2...
1. Elements in Group 6A most commonly have an oxidation state of −2. a. True b. False 2. What is the noble gas core for Cu? a. He b. Kr c. Xe d. Rn e. Ar f. Ne 3. What will be the geometry of [CoCl2(NH3)4]? a. Square planar b. Linear c. Octahedral d. Tetrahedral e. Trigonal Bipyramid 4. What is the coordination number of Pt in [Pt(NH3)4]Cl2? a. 4 b. 3 c. 5 d. 1 e. 0 f. 2...
5. The [NI(CN)412- ion has a square-planer geometry, whereas the INca diagrams (with d-orbital labels) for these twe complexes and determine if the compound is paramognetic or diamognet ion is tetrahedral. Drow the crystal field splitting 6. The absorption maximum for the complex ion (Co( Hale ccurs at 410 m. Predict the coler of this complex.Explain your reasoning. the Lewis structure of each and state whether the following are monodentate or bide ntate ligands a. c2042 (oxalate ion, ox) b,sar...
What is the coordination number for each of the following complexes or compounds? [Co(NH3)4Cl2]+ [Ca(EDTA)]2− [Pt(NH3)4]2+ Na[Ag(CN)2] Enter the coordination numbers, in the order that the complexes are listed, as four integers separated by commas (e.g., 1,2,3,4). What is the charge on each of the following complex ions? hexaaquairon(II), [Fe(H2O)6]? tris(carbonato)aluminate(III), [Al(CO3)3]? amminepentachloroplatinate(IV), [Pt(NH3)Cl5]? Express the charges numerically, in the order that the complexes are listed, separated by commas. For a nonzero charge, be sure to include the sign (e.g.,...
2.) Give the point group assignment of the following transition metal compounds: a.) trans- [PtCl2Br2]the ion has a square planar shape with Pt as the central atom b.) [CO(NH3)sBr]? the ion has an octahedral shape with Co as the central atom. Treat the NH3 groups as a large, spherical atom attached to the Co. c.) [Fe(CO)s) the compound is a square pyramidal shape, with Fe as the central atom. Assume that the Fe-C-O bond angle for each attached CO is...
How many d-electrons are there in the following species? Fe2+ 6 [Cr(OH)]2+ Please answer all parts of the question. What's the oxidation state of the transition metal in the following compounds? (1) [Cr(NH3)6]2+ O+3 O+2 0+1 00 0-1 (ii) Na[CO(NH3)6C12] O+3 +2 +1 00 0-1 What is the coordination number (CN) and the geometry of the following metal complex? Naz[Mn(EDTA)] (EDTA = ethylenediaminetetraacetic acid) Select one: a. CN = 6 Geometry = octahedral O b. CN = 1 Geometry =...
Draw structures for the following square planar and octahedral complexes and identify, using appropriate schematics, whether coordination or optical isomerism can exist for each complex: [PdCl2(NH3)2] [Pt(NH3)4]2+ [Ru(2,2´-bipyridine)3]2+ [CoCl3(NH3)3]
Draw structures for the following square planar and octahedral complexes and identify, using appropriate schematics, whether coordination or optical isomerism can exist for each complex: [PdCl2(NH3)2] [Pt(NH3)4]2+ [Ru(2,2´-bipyridine)3]2+ [CoCl3(NH3)3]