The vapour pressures of the pure components P and Q are 700 Torr and 500 Torr respectively. When the two phases are in equilibrium at 1.0 atm, the mole fraction of P in the liquid phase is 0.6 and in the
vapour phase 0.4. The activity co-efficient of compound P in the solution on the basis of Raoult’s law is
(a) 0.60 (b) 0.72
(c) 0.92 (d) 1.01
The vapour pressures of the pure components P and Q are 700 Torr and 500 Torr...
10 AL 39.9°C. the vapor pressures of pure ethanol and isooctane are 130.4 torr and 43.9 torr respectively. At this same temperature (39.9°C), a solution of ethanol-isooctane is prepared that has a mole fraction, Xethanol = 0.90, a vapor phase with yethanol = 0.67, and p = 185.9 torr. (a) Calculate the activity and activity coefficients of each component. (b) Calculate the vapor pressure of this solution using Raoult's law. (8 pts)
P3.7. A gaseous mixture is made of two gases. The saturated vapour pressures over the pure liquids are p = 30 kPa and p = 40 kPa at temperature T = 320K. The mole fraction of the first component is equal to xe = 0.6. The mixture was isothermally compressed up to the moment when the first drop of liquid appeared. Find the particular pressure when this phenomenon occurred. The mixture may be treated as an ideal one.
At 100 0C the vapor pressures of pure n-hexane (subscript 1) and pure n-octane (subscript 2) are, respectively, p10 = 1836 torr and p20 = 354 torr . A certain liquid mixture of these two compounds has a vapor pressure of 668 torr at the same temperature. A) What is the mole fraction x1 of n-hexane in the liquid mixture. B) What is the mole fraction y1 of n-hexane in the vapor phase above the mixture? C) What is the...
At 100 0C the vapor pressures of pure n-hexane (subscript 1) and pure n-octane (subscript 2) are, respectively, p10 = 1836 torr and p20 = 354 torr . A certain liquid mixture of these two compounds has a vapor pressure of 668 torr at the same temperature. A) What is the mole fraction x1 of n-hexane in the liquid mixture. B) What is the mole fraction y1 of n-hexane in the vapor phase above the mixture? C) What is the...
1) The vapor pressure of pure water at 120 °C is 1250 torr. A solution of aniline and water has a vapor pressure of 1.2 atm at 120 °C. Assuming that Raoult’s law is obeyed, what is the mole fraction of aniline in the solution? Please show work. ----------------------------------------------------------------------- 2) Consider the following solutions, all in 1.0 kg of water: 1 mol of KBr, 1.5 mol CuCl2, 2 mol CH3COOH, and 1.5 mol CoCl3. The correct order for the respective...
Binary mixture at vapor-liquid equilibrium at constant temperature has total pressure P=1.57 bar at x1=0.3. The vapor pressures of pure components are P1=2.06 bar and P2=1.13 bar, respectively. Assume that the vapor phase is ideal and the liquid phase non-ideality can be described by 1-parameter Margules equation . Calculate the total pressure and the vapor composition for this mixture at x1=0.6 at the same temperature
At 350K, pure toluene and hexane have vapor pressures of 3.57 x 10^4 Pa and 1.30 x 10^5 Pa respectively. a) Calculate the mole fraction of hexane in the liquid mixture that boils at 350 K at a pressure of 1 atm. b) Calculate the mole fraction of hexane in the vapor that is in equilibrium with the liquid part (a). I have looked up the answer and can follow, but I do not understand how to determine the value...
Nicotine |H2O T u210 P 2 61 Tm P 1 0 0.2 0.4 0.6 0.8 1 Mole fraction of nicotine, X Temperature, 0/°C The phase diagram for nicotine and water is shown here. Note the two boundaries for pure water (left) and pure nicotine (right) and mole fractions of nicotine across the horizontal axis. The letter "P" means phases, and this diagram has two regions: single-phase (one liquid, fully dissolved solid), and the other two-phase (two liquids) Here, the curve...
please answer clearly 1 (Lecture LOI) 50 m3 of a 35-C gas mixture with composition 98 miole percent air(3), 2 mole percent toluene(1) is contacted with 400 kg of 35°C pure n-decane(2). The vapor-liquid system is allowed to come to equilibrium isothermally at 35 oC at a constant pressure of 1.0 atm. What are the final compositions of the liquid and vapor phases? You should neglect dissolution of air in the liquid, but you must account for evaporation of n-decane....
at you 7.54 Consider a binary mixture of a and b at T 300K and P = 40 kPa. A graph of the fugacity of species a as a function of mole fraction is shown below. Use Henry's law as the reference state for species a and the Lewis/Randall rule for species b. Show all your work 40 38 36 T-300 K P: 40 kPa 34 32 30 28 26 24 22 20 18 16 14 12 10 4 2...