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1) Predict relative acidity. Rank in order of increasing acidity (be able to explain): a) CH3CH2SO3H,...

1) Predict relative acidity. Rank in order of increasing acidity (be able to explain):

a) CH3CH2SO3H,

b) CH3CHClCO2H,

c) CH3CH2OH,

d) ClCH2CH2CO2H,

e) CH3CH2CO2H

2) Predict relative acidity. Rank the following in order in increasing acidity:
NH3, H2SO4, CH3OH, CH3CO2H, H3O+, H2O
Hint: think of what would produce the most stable species after deprotonation. A good acid would gladly lose a proton (to form a stable conjugate base).


3) Predict relative basicity. Rank the following in order in increasing basicity:
NH3, CH3O-, H2O, CH3CO2-, NH2-
Hint: think of what would give the most stable species after protonation. If that train of thought doesn’t help, compare stability of your original compounds from the list. The more unstable (=more reactive) a compound is without a proton, the more it “wants to react” with a proton to become a more stable species.

Please show all work and give full explanation. I will rate and comment.

Thanks

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Answer #1

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