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PROBLEM 7 13 Assign E or Z configuration to the following alkenes: (a) H3C CH2OH (b)...
1. Name the following alkenes: 2. Assign the E/Z or cis/trans configuration of the following alkenes: C-C H3CH2C CH2CH3 Br CH3H H3 CH3 Cl Br
Can you explain please 3. Assign E or Z configuration to the alkenes below. (4 pts) CN CH,CH,OH b) Cl H2CH3 CH3
1 Question 7 For each of the following alkenes, assign the configuration of the double bond as either E or Z: Oz OE N Ο Ε ze
3. Assign the stereochemistry for the following alkenes as E or Z, wherever applicable (4 points) CN OCH3 Br nturon for the following.compounds (12 points):
3. Assign E or Z configuration of the following alkenes; CH CH OH non CH CH, CH COOCH3 c) CHO CH, CH,CH CH.CH NC CHINH Сс OCH CH-CO-HN CH NHCH
so answers are on back but how can you tell between S and R configuration PROBLEM 5-7 Which member in each of the following sets ranks higher (а) -Н ог-Вr (c) -CH3 or-CH2CH3 8- (b) -Cl or -Bг (d) -NH2 or-OH P BL CCHSCH3 НО- Б PRORIFM S. 0-2 moldor (a Я O1-2 maidontT 2d PROBLEM 5-9 Orient each of the following drawings so that the lowest-ranked group is toward the rear, and then assign R or S configuration: (c)...
3. Assign E or Z configuration of the following alkenes; CH,OH CH-CH, COOCH, CH b) CH_CH CH " CH, CHCHOL OH NC 2 CHÁNH, " OCH CH-CO-HN CH NHCH CH 4. Draw structures corresponding to the following systematic names; a) 1-isopropyl-4-methylcyclohexene b) 3-butyl-2-heptene c) 4-methyl-1,2- hexadiene d) trans-3,3-dimethyl-4-propyl-1,5-octadiene e) (42) -2,4-diethyl-1,4-hexadiene 1) 1.2-propadiene g) (32,5E) -2,6-dimethyl-1,3,5,7-octatetraene h) cis-2,2,5,5- tetramethyl-3-hexene i) Methylenecyclohexane j) trans- 1,2 divinylcyclohexane
Problem 7.7 Determine the configuration of each of the following as Zor E as appropriate: LOH Y OH (a) (b) (c) (d) Sample Solution (a) One of the doubly bonded carbons bears a methyl group and a hydrogen. According to the Cahn-Ingold-Prelog sequence rules, methyl outranks hydrogen. The other carbon atom of the double bond bears a methyl and a —CH OH group. The-CH2OH group is of higher priority than methyl. Higher (C) — Hzc CH2OH - Higher C(O,H,H) Lower...
question 1,2 and 3 اولا Problem 1: Are the following alkenes circle the carbon-carbon double bond and clearly indicate if the alkene is cis, trans or neither? کہا کہ گا ) H CH3 C=C CHg H Problem 2: Use the labels E and Z to best describe the stereochemistry of the alkenes below. OH NH2 H2N OH Problem 3: Using IUPAC rules name the following molecules. لہ لہ مہم
Draw the product(s) of the following reactions. H H3C-CEC-CH2CH2-C C-CH3 Lindlar catalyst • Consider E/Z stereochemistry of alkenes. • If no reaction occurs, draw the organic starting material. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. Нас ChemDoodle