Overall reaction is an example for Aromatic Electrophilic substitution and Cl+ is an Electrophilic intermediate.
| Chlorination of anisole gives primarily the Ortho- and para - Substituted products, provide a mechanism...
Draw the reaction mechanism of phenol nitration, show the ortho and para mechanisms separately. Include arrows, eletron flow and lone pairs.
The NMR spectrum suggests the formation of the meta-substituted product, but NH2 is an ortho/para directing group. Using the given chemicals, provide a mechanism to arrive at the meta-substituted product. 5. Adam Splidda and Flo Wrene were asked to make 4-aminobenzenesulfonic acid. They came up with the plan below. The Plan: NH2 SO3 NH2 H2SO4 HO3S 4-aminobenzenesulfonic acid The product: S, 1H t, 1H s, 2H d d, 1H 1H s, 1H 0 4 PPM Were they successful? Draw the...
please answer all questions the chlorination How many monochlorinated products would be obtained from the chlorin Methane? Give the structure of all the products (6) ve the complete first two stes of the mechanism for the radical chlorination of propane to give any one of the two organic products. Use curved arrows. 8 points 12. The structures below show the step-wise bond making and bond breaking in this reaction. Draw curved arrows to show the electron flow that has occurred...
Provide a full mechanism for the synthesis of 3-acetyl-7-(diethylamino)-2H-1-benzopyran-2-one. Include all formal charges, resonance structures, intermediates and products. Use proper arrows for electron flow, vaguely drawn arrows will not receive marks.
Provide a mechanism that explains formation of the following products. Draw step 1 of this mechanism. Include lone pairs and formal charges in the mechanism. Draw out explicitly only the hydrogen of the H_3O^+. Draw step 2 of this mechanism. Include all lone pairs and formal charges in the mechanism. Do NOT draw out any hydrogen explicitly. The product of the above mechanism step has a resonance structure that leads to the formation of the second product. Draw the resonance...
Please do 2a and 2b and write out the reaction mechanism, thank you! 2. Reaction Mechanism a. The Report Form asks you to write the mechanism for the synthesis reaction on the back of the form. Write the complete mechanism for the reaction. Be sure to use expanded structural formulas for all chemical species. Include all bonds, non-bonding electrons, formal charges, and electron-flow arrows. DO NOT use bond-line formulas, but rather explicitly show atomic symbols. For this mechanism, show the...
1. Provide a complete electron pushing mechanism for the following. Be sure to include any by-products as they are formed and show arrows for every bond change. Do not combine steps! a) (12 pts) Lactonization H3O+ +H2O b) (12 pts) Aspirin synthesis
Question 3 1s 3 ORTHO Today we learned about adding a second group to a mono-substituted benzene ring. Any group on a benzene will affect the rate of the reaction (activated or deactivated relative to benzene) and the regioselectivity Where does the electrophile add? Ortho? Meta? Para? Some combination thereof? We found that EDGs (electron-donating groups) direct the electrophile to the ortho and para positions while EWGs (electron-withdrawing groups) direct the electrophile to the meta position. Now, it is time...
1) Provide a detailed electron pushing mechanism for the below transformation. Show ALL relevant resonance structures to help explain why the para product is the major organic product. (Note: your electron pushing mechanism should include formation of the electrophile) (4 points) Cl AICl3
Provide a mechanism to explain the formation of the two products shown following reaction. Show all key intermediates and indicate electron flow using arrows. a. OH H2O, Ht, heat CH3 H3C CH3 CH3