1a-h Chapters 21 and 22: 14 1. Consider the structure shown on the right and answer...
please help with questions! Chapters 21 and 22 1. Consider the structure shown on the right and answer the following questions about it (fill in blanks or circle proper choice). f4 tl a. Its molecular formula is CH,O 似 and so it fits the general formula for a carbohiydrate, which is C(O b. Specifically, this structure is (a D) an L.) (aldojketo) (pent/hex (ase/ c. Will it be optically active? s d. If the top carbon was converted to a...
Chapters 21 and 22: 1. Consider the structure shown on the right and answer the following questions about it (ill in blanks or cirele proper choice) (4 a. Its molecular formula is G ,H( )0( , and so it fits the CHOH , general formula for a carbohydrate, which is b. Specifically, this structure is (a D/ an L) (aldo/keto) (pent/hex) (aselose) c. Will it be optically active? d. If the top carbon was converted to a CH,OH, would it...
2.27 (b) (a) -H H CH3-C-CEN (e) (f) (d) 2.27 In the compounds shown below, the six-membered rings are called benzene rings. Such rings are commonly found in natural products, and we will learn more about the remarkable stability of these ring systems in Chapter 17. Because of resonance effects with the attached groups, one of the benzene rings shown is electron-rich and the other is electron-poor. Draw the significant resonance contribu- tors for each to determine which is which....
19-26 thanks! 19-29* PART 3: 2,3-BUTANEDIOL CH-CH(OH)-CH(OH)-CH, mirror images, not superimposable Build as many models of 2,3-butanediol as you can. First, attach two carbons with a single bond. To each carbon add one carbon, one hydrogen, and one oxygen. To complete the structure, Ti the remaining hydrogen atoms. Remember, a model is not different if it is completely superimposable on one already constructed! 13. How many stereochemically different models are possible for 2,3-butanediol? 14. What characteristic does one of these...
Question 1 (1 point) Which of the following best describes glycogen? Question 3 (1 point) All the protease mechanisms we discussed in class involved formation of a covalent acyl enzyme intermediate. O Alinear polymer of glucose joined by a(1,6) linkages. True False O A polymer of glucose joined by a(1,4) linkages with a(1,6) linkages every 5-10 residues. Question 4 (1 point) O A polymer of glucose joined by B(1,4) linkages with a(1,6) linkages every 5-10 residues. In the mechanism of...
Question 1 (1 point) Which of the following best describes glycogen? Question 3 (1 point) All the protease mechanisms we discussed in class involved formation of a covalent acyl enzyme intermediate. O Alinear polymer of glucose joined by a(1,6) linkages. True False O A polymer of glucose joined by a(1,4) linkages with a(1,6) linkages every 5-10 residues. Question 4 (1 point) O A polymer of glucose joined by B(1,4) linkages with a(1,6) linkages every 5-10 residues. In the mechanism of...
1) a. Please draw the structure of the intermediate in the process shown below. CH2OH CH2OH Кон о он КОН OH OH OH OH OH The process shown above is called: c. Please mark an anomeric carbon and designate the orientation of the hydroxyl group. d. Indicate the carbon that determines the D or L configuration in the glucopyranose above by number or with an X. e. Is this a reducing sugar? f. Can it react with another carbohydrate to...
2. Referring to the structure at the right, answer/do the following: CH2OH a. Label each ring as locked (L) or unlocked. (U) OH O b. Circle the glycoside linkage. OH C. What type of glycoside linkage (e.g., a-1,2) is it? CH2OH HO OH HO 2MCL d. Explain the significance to humans of the type of glycoside linkage in this disaccharide.Why does it matter to some humans who consume sobi-C this sugar? Hbonvib no tiowall OH OH What is the name...
Chapters 1-11 1. Carbenes are diradicals and can have a transient existence during many reaction (particularly with alkenes). Isopropylene, :C(CH3)2, is a example of a carbone. The two electrons can share the same orbital or occupy two different orbitals. Provide the expecte hybridization when the two electrons are spin unpaired. For when they Draw the atomic orbitals of each and identify the valence orbitals on the carbene. H Hoe & H₂O 2. Account for the fact that the following carbocation...
PLEASE HELP WITH ALL. A. Which of the following Newman projections would represent the least stable conformer of 2,2,3.3-tetramethylbutane, looking down the 2,3 bond? H3C H3C H3C H3C CH3 b) CH3 H3C e) a) c) CH3 H3C CH3 CH CH3 CH о он B. which one of the following compounds would be chiral? Br он о он a) но HO O он HO C C. which of the following could potentially be used to distinguish between enantiomers? b) NMR c)...