Question

Consider the phase diagram for a hypothetical A-B system. Assume that A and B form ideal solutions in the liquid state and in the solid state. 1. If a solution containing 50 mol.% B is cooled from 1300 K, what is the composition of the first solid to form? What is the composition of the last liquid to solidify? For this 50 mol% B solution, estimate the fraction of solid and liquid in equilibrium at 1000 K Sketch the activity-composition relationship for component B in the solution at 1300 K, 1100 K and 800 K. In each case state the standard state you have chosen a. b. c. 1300 1200 ? 1100 1000 Liquid -1250 OD Liquid +Solid OD Solid 900 800 0 10 20 30 40 50 60 70 8090 100 xB (mol %)-

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0 19 30 1100 1000 5% 20 30 uo 5. 6. до 8040 ohm by lihe Ra and b

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