Experiment Initial [A] Initial [B] Initial [C] Initial Rate of Reaction 1 0.1 M 0.1 M...
| Experiment | Initial [A] | Initial [B] | Initial [C] | Initial Rate of Reaction |
| 1 | 0.1 M | 0.1 M | 0.2 M | 4 x 10^(-4) M/min |
| 2 | 0.3 M | 0.2 M | 0.2 M | 1.2 x 10^(-3) M/min |
| 3 | 0.1 M | 0.3 M | 0.2 M | 4 x 10^(-4) M/min |
| 4 | 0.3 M | 0.4 M | 0.6 M | 3.6 x 10^(-3) |
The method of initial rates is used to determine the rate law for reactants A, B, and C. This data was obtained at 25 degrees C. The overall stoichiometry of the reaction is A + B + 2C --> 3D.
1. What is a plausible rate determining step in this reaction?
2. In experiment 4, when the reaction has completed, which reactants, if any, will remain unconsumed? In what concentration?
3. In experiment 2, what is the maximum concentration obtainable for D? (assuming the volume remains constant.)
4. If experiment 2 is repeated at 50 degrees C and the initial rate is measured at 1.6 x 10^(-3) M/min. What is the activation energy of this new reaction?
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Experiment
Initial [A]
Initial [B]
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Initial Rate of Reaction
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0.1 M
0.1 M...
Given the data below for the reaction, 2 A + 2 B + 4 C =>...
Given the data below for the reaction, 2 A + 2 B + 4 C => D + E + 3 F Experiment Initial conc of A, mol/L Initial conc of B, mol/L Initial conc of C, mol/L Initial rate, mol/L.s 1 0.1 0.1 0.2 2 x 10-3 2 0.2 0.3 0.2 6 x 10-3 3 0.3 0.1 0.2 2 x 10-3 4 0.4 0.3 0.4 1.2 x 10-2 Calculate the value of k to 3 significant figures.
Given the data below for the reaction, 2 A + 2 B + 4 C =>...
Given the data below for the reaction, 2 A + 2 B + 4 C => D + E + 3 F, the reaction is ( ) order in A,( ) order in B, ( ) order in C and ( ) order overall. USE WORDS TO FILL IN THE BLANKS NOT NUMBERS (i.e., zero, first, second etc) !!!!! : Experiment Initial conc of A, mol/L Initial conc of B, mol/L Initial conc of C, mol/L Initial rate, mol/L.s 1...
1. The initial reaction rate of a hypothetical reaction | A +B →G was measured at 25°C for several different starting c...
1. The initial reaction rate of a hypothetical reaction | A +B →G was measured at 25°C for several different starting concentrations of A and B. The results are shown below: Experiment 0.2 Initial reaction rate M/s 2.0 X 10-6 1.2 X 10-5 8.0 X 10-6 0.4 0.3 0.6 0.2. A) Use these data to determine the values of m and n and k in the following equation: Rate = k AmBn B) What will the reaction rate be when...
QUESTION 9 Initial rate, mol/L.s Given the data below for the reaction, 2A + 2B +...
QUESTION 9 Initial rate, mol/L.s Given the data below for the reaction, 2A + 2B + 4C => D + E +3 F Experiment Initial conc of A Initial conc of B. Initial conc of C, mol/L mol/L mol/L 0.1 0.1 0.2 0.3 0.3 0.4 N 0.2 2 x 10-3 4x 10-3 6 x 103 8x10-3 w A Calculate the value of k to 3 significant figures. QUESTION 7 For the reaction, 2 A(g) + 2 B(g) => C(g) +...
4. For the reaction 2A+B → CD+E Experiment [B] 0.015 0.006 0.015 0.012 0.045 0.012 Initial...
4. For the reaction 2A+B → CD+E Experiment [B] 0.015 0.006 0.015 0.012 0.045 0.012 Initial Rate, M/min 0.0195 0.039 0.120 2C 5. For the reaction 2A +B Experiment 1 8.0x102 4 .0x102 3 8.0x102 1 [B] 2.0x102 1.0x102 4.0x102 Initial Rate, M/min 4.0x10 1.0x10 4.0x10 2 76. Use the following data for the reaction: 4CH N O the rate when [CH.N) is 0.004 M and [O] is 0.02 M → CO+H,0 + 4NO. Find Experiment 2 CHEN 3.8 x...
1. The rate expression for a particular reaction is rat·klArBP. If the initial concentration of A...
1. The rate expression for a particular reaction is rat·klArBP. If the initial concentration of A is increased from 0.1 to 0.3 and the initial concentration of B is increased from 0.1 M to 0.2 M, the initial rate will increase by how much?
The table below contains initial rate experimental data for the reaction: A +BC Experiment: [A], M....
The table below contains initial rate experimental data for the reaction: A +BC Experiment: [A], M. [B], M. Initial Rate in M/min 1 0.34 0.21 1.2 2 0.34 0.42 4.8 3 0.68 0.42 9.6 4 0.50 0.35 ???? What is the initial rate for experiment 4? 7.0 Mmin 3.7 Mmin What is the initial rate for experiment 4? 7.0 M/min 3.7 M/min 4.9 M/min 2.1 M/min 3.1 M/min
Initial rate data are listed in the table for the reaction: Initial rate data are listed...
Initial rate data are listed in the table for the reaction:
Initial rate data are listed in the table for the reaction: NH4+ (aq) + NO2 (aq) + N2 (g) + H20 (1) Experiment (NH4+]: [NO 2-1. Initial rate (M/s) 0.24 0.10 7.2 x 10-4 0.10 3.6 x 10-4 10.12 0.15 5.4 x 10-4 0.12 0.12 4.3 x 10-4 0.12 First determine the rate law and rate constant. Under the same initial conditions as in Experiment 4, calculate [NH4+] at...
1. Consider mixture B, which will cause the reaction to proceed forward: Concentration (M) [XY] <--->...
1. Consider mixture B, which will cause the reaction to proceed forward: Concentration (M) [XY] <---> [X] + [Y] Initial 0.5 0.1 0.1 Change - x +x + x Equilibrium 0.5 - x 0.1 + x 0.1 + x Based on a Kc value of 0.140 the given data table, what are the equilibrium concentrations of XY, X, and Y respectively? Express the molar concentrations numerically 2. Consider mixture C, which will cause the net reaction to proceed in reverse...
Initial rate data are listed in the table for the reaction: NH4+ (aq) + NO2 (aq) + N2(g) + H20 (1) Experiment (NH4+) (N...
Initial rate data are listed in the table for the reaction: NH4+ (aq) + NO2 (aq) + N2(g) + H20 (1) Experiment (NH4+) (NO2). Initial rate (m/s) AWN + 0.24 0.10 0.12 0.10 0.120.15 0.12 0.12 7.2 x 10-4 3.6 x 104 5.4 x 10-4 4.3 x 10-4 First determine the rate law and rate constant. Under the same initial conditions as in Experiment 4, calculate [NH4+) at 114 seconds after the start of the reaction. In this experiment, both...
1. The initial reaction rate of a hypothetical reaction | A +B →G was measured at 25°C for several different starting concentrations of A and B. The results are shown below: Experiment 0.2 Initial reaction rate M/s 2.0 X 10-6 1.2 X 10-5 8.0 X 10-6 0.4 0.3 0.6 0.2. A) Use these data to determine the values of m and n and k in the following equation: Rate = k AmBn B) What will the reaction rate be when...
QUESTION 9 Initial rate, mol/L.s Given the data below for the reaction, 2A + 2B + 4C => D + E +3 F Experiment Initial conc of A Initial conc of B. Initial conc of C, mol/L mol/L mol/L 0.1 0.1 0.2 0.3 0.3 0.4 N 0.2 2 x 10-3 4x 10-3 6 x 103 8x10-3 w A Calculate the value of k to 3 significant figures. QUESTION 7 For the reaction, 2 A(g) + 2 B(g) => C(g) +...
4. For the reaction 2A+B → CD+E Experiment [B] 0.015 0.006 0.015 0.012 0.045 0.012 Initial Rate, M/min 0.0195 0.039 0.120 2C 5. For the reaction 2A +B Experiment 1 8.0x102 4 .0x102 3 8.0x102 1 [B] 2.0x102 1.0x102 4.0x102 Initial Rate, M/min 4.0x10 1.0x10 4.0x10 2 76. Use the following data for the reaction: 4CH N O the rate when [CH.N) is 0.004 M and [O] is 0.02 M → CO+H,0 + 4NO. Find Experiment 2 CHEN 3.8 x...
1. The rate expression for a particular reaction is rat·klArBP. If the initial concentration of A is increased from 0.1 to 0.3 and the initial concentration of B is increased from 0.1 M to 0.2 M, the initial rate will increase by how much?
The table below contains initial rate experimental data for the reaction: A +BC Experiment: [A], M. [B], M. Initial Rate in M/min 1 0.34 0.21 1.2 2 0.34 0.42 4.8 3 0.68 0.42 9.6 4 0.50 0.35 ???? What is the initial rate for experiment 4? 7.0 Mmin 3.7 Mmin What is the initial rate for experiment 4? 7.0 M/min 3.7 M/min 4.9 M/min 2.1 M/min 3.1 M/min
Initial rate data are listed in the table for the reaction:
Initial rate data are listed in the table for the reaction: NH4+ (aq) + NO2 (aq) + N2 (g) + H20 (1) Experiment (NH4+]: [NO 2-1. Initial rate (M/s) 0.24 0.10 7.2 x 10-4 0.10 3.6 x 10-4 10.12 0.15 5.4 x 10-4 0.12 0.12 4.3 x 10-4 0.12 First determine the rate law and rate constant. Under the same initial conditions as in Experiment 4, calculate [NH4+] at...
Initial rate data are listed in the table for the reaction: NH4+ (aq) + NO2 (aq) + N2(g) + H20 (1) Experiment (NH4+) (NO2). Initial rate (m/s) AWN + 0.24 0.10 0.12 0.10 0.120.15 0.12 0.12 7.2 x 10-4 3.6 x 104 5.4 x 10-4 4.3 x 10-4 First determine the rate law and rate constant. Under the same initial conditions as in Experiment 4, calculate [NH4+) at 114 seconds after the start of the reaction. In this experiment, both...
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