If cyclohexanol(mw 100) (d=0.8 g/ml) were substituted for
2-methylcycholhexanol, only one product, cyclohexane (d=0.8 g/ml)
would be obtained. Distillation of the reaction mixture would occur
at 85 C. Assume that the vapor pressures of cyclohexane and water
are 152 mm and 608 mm respectively at 85 C. If 0.6 mol of water are
obtained in the distillate what is the yield of cyclohexane? Assume
that the bp of cyclohexane is 100 C and that cyclohexane is
insoluble in water?
a) 15.4 ml
b) 15.0 g
c) 61.5 ml
d) 19.2 g
e) 0.6 mol
Which statement on dehydration of 2-methylcyclohexanol is
true?
a) The reaction becomes irreversible once the intermediate
carbonium ion is generated
b) answers A and E
c) the pathway leading to the major product involves the higher of
the two possible transition states but lead to the
thermodynamically most stable product.
d) answers C and E
e) the reaction is driven to completion by removing one or more of
the products as the reaction proceeds.
Answer for second part:
Answer: C and E
c) the pathway leading to the major product involves the higher of the two possible transition states but lead to the thermodynamically most stable product.
e) the reaction is driven to completion by removing one or more of the products as the reaction proceeds.
If cyclohexanol(mw 100) (d=0.8 g/ml) were substituted for 2-methylcycholhexanol, only one product, cyclohexane (d=0.8 g/ml) would...
Introduction A common method for synthesizing alkenes is by dehydrating (removing the elements of water) an alcohol. The dehydration is accomplished by heating the alcohol with either phosphoric or sulfuric acid. In this experiment, the dehydration reaction is illustrated by the conversion of 2-methylcyclohexanol to a mixture of alkenes (remember the Saytzeff rule). Information Each step of this E1 elimination reaction is reversible and thus, the reaction may be driven to completion by removing one or more of the products,...
2 dibenzalacetone acetone benzaldehyde MW- 106.13 g/mol bp-1 78°C d 1.04 g/mL MW 234.30 g/mol mp #110-1110 MW-58.08 g/mol bp 56°C d 0.79 g/mL Its bs Reaction Setup (3 pts) S. OS Initial quantity of NaOH: S. I Initial quantity of benzaldehyde: mL Initial quantity of acetone: mL Theoretical yield of dibenzalacetone based on benzaldehyde: (show calculations) Theoretical yield of dibenzalacetone based on acetone 9 (show calculations) ce tone Limiting Reagent: Product Data (10 pts) fivAL Mass: 3.3g Percent Yield:...
Working on the questions at the end of this lab report (see above). I need help answering questions 2, 3, and 4 completely and thoroughly. Thank you! s, until the I hexano 1 clean disti CYCLOHEXENE from CYCLOHEXANOL be dehydrated with solfuric acid to yield cyclohexene and waterf Add a 0°C (record ct and cal H,SO + H20 ainer. s in purification of any crude product are (a) the preliminary separation of the product from the reaction mixture by distillation...
Organic Chemistry Lab Densities in g/ml Dichloromethane d= 1.33 g/ml Acetone d =0.79 g/ml 2, 2-dimethoxypropane d= 0.85 g/ml methanesulfonyl chloride (mesyl chloride, MsCl) MW = 114.55; d = 1.48 g/ml Triethylamine d= 0.73 g/ml Diethyl ether Water MW = 74.112 d = 0.706 d = 1.00 Pentane MW 72.5 d= 0.63 MW Phosphorous Chlorine 30.97 35.45 Boron Nitrogen Oxygen Carbon Hydrogen 10.8 14.07 16.00 12.00 1.00 In J. Med Chem 1978 21 (10) 1070, the authors report the preparation...
1) One hundred (100) ml of a 1.00 M solution of HCl is diluted with water to prepare a 0.200 M solution. What is the volume of the resulting 0.200 M solution? Or asked another way, to what volume must the original solution be diluted? (3 points) 2) Lithium hydroxide, LiOH, is used in spacecraft to absorb the carbon dioxide exhaled by astronauts. Given 1.3 kg of LiOH, how many kg of CO2 can be absorbed? (10 Pts. The reaction...
Pre-Lab Assignment 1) Draw the reaction mechanism for the reaction. 2) Determine the limiting reagent. Procedure 1 Place approximately 1 g of stilbene dibromide prepared in last week's experiment in a 50 mL round bottom flask. Record the exact mass. Add 0.8 g of KOH and 4 mL of triethylene glycol from the syringe provided in the fume hood (rinse any crystals from the sides of the flask while adding triethylene glycol). 2 Heat the stirred reaction mixture to a...
Experiment Write Up Proposal You will write up a synthesis procedure for one reaction that could be potentially run in a face- to-face Chem 2321 lab session. Your proposal will include an introduction and procedure. The procedure will include step-by-step instructions for running the reaction (including reaction monitoring), work-up. (product isolation and purification), and analysis (characterization). You will need to include sample calculations for percent yield and provide sample spectra analysis. You must upload your proposal as a single document...