How many moles of NaOCl must be added to 150 mL of 0.025 M HOCl to obtain a buffer solution with a pH = 7.50? Ka= 2.8×10-8 for HOCl.
The answer is 3.3x10-3
PKa = -logka
= -log2.8*10-8
= 7.5528
no of moles of HOCl = Molarity * voluem in L
= 0.025*0.15 = 0.00375 moles
PH = PKa + log[NaOCl]/[HOCl
7.5 = 7.5528 + log[NaOCl]/0.00375
log[NaOCl]/0.00375 = 7.5-7.5528
log[NaOCl]/0.00375 = -0.0528
[NaOCl]/0.00375 = 10-0.0528
[NaOCl]/0.00375 = 0.8855
[NaOCl ] = 0.88*0.00375
no of moles of NaOCl = 0.0033moles = 3.3*10-3
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