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6) Fill in the missing reagents and intermediate products for the following two...
Fill in the boxes over each arrow with the letter that corresponds to the reagents needed to perform each step of the multistep synthesis show below. Reagents may be used more than once, or not at all...
Fill in the boxes over each arrow with the letter that
corresponds to the reagents needed to perform each step of the
multistep synthesis show below. Reagents may be used more than
once, or not at all. Pay close attention to the numbered carbons in
the starting material, and be sure that your answer accounts for
the position of these carbons in the final product.
pts) Fill in the boxes over each arrow with the letter that corresponds to the...
(10 points) Fill in the boxes with the missing starting material, intermediate products, reagents, and/or products....
(10 points) Fill in the boxes with the missing starting material, intermediate products, reagents, and/or products. Then for each reaction draw the reaction mechanism with correct electron flow arrows if appropriate or intermediates and correct formal charges. -OH -NH2 NH (10 points) Use the Gabrielle synthesis to make your starting amine below. Then use this starting amine to synthesize the secondary amine using reductive amination. Draw the mechanisms for both reactions below. Be sure to draw correct intermediates, electron flow...
6. (20) Fill in the missing reagents to accomplish these conversions (>1 step may be needed): 7, (10) Give the a...
6. (20) Fill in the missing reagents to accomplish these conversions (>1 step may be needed): 7, (10) Give the alkyl halide which would give only the alkene shown by way of an E2 elimination (one alkyl halide for each alkene): 8. (10 - extra credit) (a) (6) Propose a 2-4 step mechanism to explain this conversion. (b) (4) Draw a reasonable reaction coordinate diagram for this process.
1. (6 pts) Fill in the blanks to complete the reaction scheme. If multiple products/reagents are...
1. (6 pts) Fill in the blanks to complete the reaction scheme. If multiple products/reagents are possible, choose one that will allow the rest of the synthesis to occur. If multiple stereoisomers form, only draw one. NaOH mCPBA ''Br KOtBu 1) BH3, THE 2) H2O2, NaOH
Predict the Products/Reagents. Draw the expected products from the following reactions or fill in the missing...
Predict the Products/Reagents.
Draw the expected products from the following reactions or fill
in the missing reagent(s). Where a stereocenter is created,
indicate the configuration of the product.
Predict the Products/Reagents. Draw the expected products from the following reactions or fil in the missing reagent(s). Where a stereocenter is created, indicate the configuration of the product Br Mgo Et20 8. 1. PhCH2Br 2. BuLi PPh3 9. H2N Et, (c CO2Et Ph 10. NH2 NaBH3CN
2. REACTIONS AND REAGENTS: Fill in the following boxes with the appropriate reagents or products. Note,...
2. REACTIONS AND REAGENTS: Fill in the following boxes with the appropriate reagents or products. Note, most of the reagent problems will have more than one step. Also, for the last three please use aldehyde III (benzaldehyde) as the starting material. оснусн, II CH,CH, OH H NH2 IV H2NCH, cat H+ CH, H-N CH, , NaBH,CN Br2. FeBr 3 Cros, H2SO4 acetone
(10 pts) Fill in the missing intermediates (two), final product, and reagents (two) in the llowing...
(10 pts) Fill in the missing intermediates (two), final product, and reagents (two) in the llowing multistep synthesis. Br X OH -- NH 에 CH,Br 6) (5 pts) Write out the 3-step arrow pushing mechanism showing how cyclopentanol is dehydrated to make cyclopentene: он conc. H,SO + HO heat
3. Mechanism: Draw the curved arrow mechanism for the following hydrolysis reaction, only draw the mechanism...
3. Mechanism: Draw the curved arrow mechanism for the following hydrolysis reaction, only draw the mechanism from the starting material to the neutral functional group intermediate. Additionally, indicate what is in the final product by writing Y="appropriate atom here". Use only the reagents provided below, in your mechanism. (5 pts) excess NaOH H2O, heat HNĐ neutral functional group intermediate 9. Mechanism: Draw the curved arrow mechanism for the following reaction. Please be aware that during the mechanism you will form...
1. (12 pts) Fill in the boxes over each arrow with the letter that corresponds to the reagents needed to perform each step of the multistep sequence shown below. Reagents may be used more than once,...
1. (12 pts) Fill in the boxes over each arrow with the letter that corresponds to the reagents needed to perform each step of the multistep sequence shown below. Reagents may be used more than once, or not all. Pay close attention to the numbered carbons in the starting material, and be sure that your answer accounts for the position of these carbons in the final product. 1 3 3 3 2 2 MCPBA CF3SO3H A) HOCH3, DCC, DMAP E)...
Fill in the boxes over each arrow with the letter that
corresponds to the reagents needed to perform each step of the
multistep synthesis show below. Reagents may be used more than
once, or not at all. Pay close attention to the numbered carbons in
the starting material, and be sure that your answer accounts for
the position of these carbons in the final product.
pts) Fill in the boxes over each arrow with the letter that corresponds to the...
(10 points) Fill in the boxes with the missing starting material, intermediate products, reagents, and/or products. Then for each reaction draw the reaction mechanism with correct electron flow arrows if appropriate or intermediates and correct formal charges. -OH -NH2 NH (10 points) Use the Gabrielle synthesis to make your starting amine below. Then use this starting amine to synthesize the secondary amine using reductive amination. Draw the mechanisms for both reactions below. Be sure to draw correct intermediates, electron flow...
6. (20) Fill in the missing reagents to accomplish these conversions (>1 step may be needed): 7, (10) Give the alkyl halide which would give only the alkene shown by way of an E2 elimination (one alkyl halide for each alkene): 8. (10 - extra credit) (a) (6) Propose a 2-4 step mechanism to explain this conversion. (b) (4) Draw a reasonable reaction coordinate diagram for this process.
1. (6 pts) Fill in the blanks to complete the reaction scheme. If multiple products/reagents are possible, choose one that will allow the rest of the synthesis to occur. If multiple stereoisomers form, only draw one. NaOH mCPBA ''Br KOtBu 1) BH3, THE 2) H2O2, NaOH
Predict the Products/Reagents.
Draw the expected products from the following reactions or fill
in the missing reagent(s). Where a stereocenter is created,
indicate the configuration of the product.
Predict the Products/Reagents. Draw the expected products from the following reactions or fil in the missing reagent(s). Where a stereocenter is created, indicate the configuration of the product Br Mgo Et20 8. 1. PhCH2Br 2. BuLi PPh3 9. H2N Et, (c CO2Et Ph 10. NH2 NaBH3CN
2. REACTIONS AND REAGENTS: Fill in the following boxes with the appropriate reagents or products. Note, most of the reagent problems will have more than one step. Also, for the last three please use aldehyde III (benzaldehyde) as the starting material. оснусн, II CH,CH, OH H NH2 IV H2NCH, cat H+ CH, H-N CH, , NaBH,CN Br2. FeBr 3 Cros, H2SO4 acetone
(10 pts) Fill in the missing intermediates (two), final product, and reagents (two) in the llowing multistep synthesis. Br X OH -- NH 에 CH,Br 6) (5 pts) Write out the 3-step arrow pushing mechanism showing how cyclopentanol is dehydrated to make cyclopentene: он conc. H,SO + HO heat
3. Mechanism: Draw the curved arrow mechanism for the following hydrolysis reaction, only draw the mechanism from the starting material to the neutral functional group intermediate. Additionally, indicate what is in the final product by writing Y="appropriate atom here". Use only the reagents provided below, in your mechanism. (5 pts) excess NaOH H2O, heat HNĐ neutral functional group intermediate 9. Mechanism: Draw the curved arrow mechanism for the following reaction. Please be aware that during the mechanism you will form...
1. (12 pts) Fill in the boxes over each arrow with the letter that corresponds to the reagents needed to perform each step of the multistep sequence shown below. Reagents may be used more than once, or not all. Pay close attention to the numbered carbons in the starting material, and be sure that your answer accounts for the position of these carbons in the final product. 1 3 3 3 2 2 MCPBA CF3SO3H A) HOCH3, DCC, DMAP E)...
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