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(10 points) Fill in the boxes with the missing starting material, intermediate products, reagents, and/or products....
(10 points) Draw the correct product for the reaction below. For step 2, draw the reaction...
(10 points) Draw the correct product for the reaction below. For step 2, draw the reaction mechanism. Be sure to include important intermediate compounds, electron flow arrows, and formal charges for full credit. ОН 1. SOCl2, pyridine 2. CH3NH2 (10 points) Fill in the boxes with the missing starting material, intermediate products, reagents, and/or products. Then for each reaction draw the reaction mechanism with Correct electron flow arrows if appropriate or intermediates and correct formal charges. -OH -NH2 NH (10...
What is the major organic product for #2,4,5? On the synthesis what is the reagents, starting...
What is the major organic product for #2,4,5?
On the synthesis what is the reagents, starting materials, and
intermediates?
the major organic product(s) of the following reactions. Indicate stereochemistry Reactions, Predict Where neAnswer 4 reactions below, 1 points each, 4 points total). bold and dashed wedges). Partial credit will be given to correct work so show 1. Excess CHal 3. Heat necessary (with NH2 1. NaNO2. HC 2. CuCN 2. Br 2. H2N-NH2 (CH3)2CHOH 1. PhCH2NH2 2. LiAIHA 5. Synthesis....
Open Response. Draw the answer for each question below. 1. (10 points) Propose a synthesis of...
Open Response. Draw the answer for each question below. 1. (10 points) Propose a synthesis of the following compound with one of your intermediate products must be an amine for full credit. OH 2. (10 points) Draw the correct product for the reaction below. For step 2, draw the reaction mechanism. Be sure to include important intermediate compounds, electron flow arrows, and formal charges for full credit. OH 1. SOCI2. pyridine 2. CH3NH2
1. Reductive amination (Carey, Section 22.10) is an important C-N bond forming strategy widely used in...
1. Reductive amination (Carey, Section 22.10) is an important C-N bond forming strategy widely used in the synthesis of biologically active natural product. It's a powerful and reliable strategy that avoids the problem of overalkylation that often accompanies direct alkylation of amines with alkyl halides (Figure 1). secondary amine r tiary amine quemary sa Figure 1: Yields are generally poor as product amines are more nucleophilic and can also react with halide. The result is often a mixture of amines...
3. Fill in the reagents or products for the following reactions. Note some boxes will require...
3. Fill in the reagents or products for the following reactions. Note some boxes will require two or three reagents in separate steps; list them as 1, 2, and 3. (2 points) 1. MeONa/MeOH 2. HCI +/ H2N Br 4. Using another sheet of paper, provide a reasonable reaction mechanism for the following transformation, starting with enamine generation (Carbonyls 2) and subsequent alkylation and hydrolysis (Carbonyls 3). Please write neatly and show all arrows, resonance structures, tetrahedral intermediates, and charges....
35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent...
35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent electron movement and show all formal +/- charges to get full credit. heat NCH) CH, OH CH 36. (6) Provide a synthesis for the following amine using a Gabriel synthesis. NH 37.(4) Draw the 4 possible organic products for each reaction. Lly CH,NH 38. (4) Draw a structure for the expected product of the following reactions. wila + HN OH Gila OH
35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent...
35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent electron movement and show all formal +/- charges to get full credit. O NICH heat NICH) CH, OH "CH₂ 36. (6) Provide a synthesis for the following amine using a Gabriel synthesis. NH 37. (4) Draw the 4 possible organic products for each reaction. ily CH,NH. 38. (4) Draw a structure for the expected product of the following reactions, + HN OH Gila OH
22. Show how you would make the target compounds on the right form the starting compounds on the left. Show reagent...
22. Show how you would make the target compounds on the right form the starting compounds on the left. Show reagents and conditions where appropriate, and the structures of important intermediate compounds. Do not show any (arrow pushing) mechanisms!!!! (8 points) NH2 3-Steps NH2 17. Show the products and give reaction mechanisms for the following, using curved arrows to indicate the flow of electrons between intermediates.
CICI 35. (4) Provide a mechanism for the following transformation. You must use curved arrows to...
CICI 35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent electron movement and show all formal +/- charges to get full credit. a Nichols heat CHE CH2 OH 36.6) Provide a synthesis for the following amine using a Gabriel synthesis. NH2 37.(4) Draw the 4 possible organic products for each reaction. CHÚNH 38. (4) Draw a structure for the expected product of the following reactions. NH + HEN OH OH
Electrophilic Addition Mechanisms 15 of 30 Draw all missing reactants and products in the appropriate boxes...
Electrophilic Addition Mechanisms 15 of 30 Draw all missing reactants and products in the appropriate boxes by placing soms on the grand conecting the the electron flow arrows on the molecules. Arrows should start metabond and should end on an atom, bond, w bod, including charges were a wbond should be created indicate the chamby View Available in H OO
(10 points) Draw the correct product for the reaction below. For step 2, draw the reaction mechanism. Be sure to include important intermediate compounds, electron flow arrows, and formal charges for full credit. ОН 1. SOCl2, pyridine 2. CH3NH2 (10 points) Fill in the boxes with the missing starting material, intermediate products, reagents, and/or products. Then for each reaction draw the reaction mechanism with Correct electron flow arrows if appropriate or intermediates and correct formal charges. -OH -NH2 NH (10...
What is the major organic product for #2,4,5?
On the synthesis what is the reagents, starting materials, and
intermediates?
the major organic product(s) of the following reactions. Indicate stereochemistry Reactions, Predict Where neAnswer 4 reactions below, 1 points each, 4 points total). bold and dashed wedges). Partial credit will be given to correct work so show 1. Excess CHal 3. Heat necessary (with NH2 1. NaNO2. HC 2. CuCN 2. Br 2. H2N-NH2 (CH3)2CHOH 1. PhCH2NH2 2. LiAIHA 5. Synthesis....
Open Response. Draw the answer for each question below. 1. (10 points) Propose a synthesis of the following compound with one of your intermediate products must be an amine for full credit. OH 2. (10 points) Draw the correct product for the reaction below. For step 2, draw the reaction mechanism. Be sure to include important intermediate compounds, electron flow arrows, and formal charges for full credit. OH 1. SOCI2. pyridine 2. CH3NH2
1. Reductive amination (Carey, Section 22.10) is an important C-N bond forming strategy widely used in the synthesis of biologically active natural product. It's a powerful and reliable strategy that avoids the problem of overalkylation that often accompanies direct alkylation of amines with alkyl halides (Figure 1). secondary amine r tiary amine quemary sa Figure 1: Yields are generally poor as product amines are more nucleophilic and can also react with halide. The result is often a mixture of amines...
3. Fill in the reagents or products for the following reactions. Note some boxes will require two or three reagents in separate steps; list them as 1, 2, and 3. (2 points) 1. MeONa/MeOH 2. HCI +/ H2N Br 4. Using another sheet of paper, provide a reasonable reaction mechanism for the following transformation, starting with enamine generation (Carbonyls 2) and subsequent alkylation and hydrolysis (Carbonyls 3). Please write neatly and show all arrows, resonance structures, tetrahedral intermediates, and charges....
35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent electron movement and show all formal +/- charges to get full credit. heat NCH) CH, OH CH 36. (6) Provide a synthesis for the following amine using a Gabriel synthesis. NH 37.(4) Draw the 4 possible organic products for each reaction. Lly CH,NH 38. (4) Draw a structure for the expected product of the following reactions. wila + HN OH Gila OH
35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent electron movement and show all formal +/- charges to get full credit. O NICH heat NICH) CH, OH "CH₂ 36. (6) Provide a synthesis for the following amine using a Gabriel synthesis. NH 37. (4) Draw the 4 possible organic products for each reaction. ily CH,NH. 38. (4) Draw a structure for the expected product of the following reactions, + HN OH Gila OH
22. Show how you would make the target compounds on the right form the starting compounds on the left. Show reagents and conditions where appropriate, and the structures of important intermediate compounds. Do not show any (arrow pushing) mechanisms!!!! (8 points) NH2 3-Steps NH2 17. Show the products and give reaction mechanisms for the following, using curved arrows to indicate the flow of electrons between intermediates.
CICI 35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent electron movement and show all formal +/- charges to get full credit. a Nichols heat CHE CH2 OH 36.6) Provide a synthesis for the following amine using a Gabriel synthesis. NH2 37.(4) Draw the 4 possible organic products for each reaction. CHÚNH 38. (4) Draw a structure for the expected product of the following reactions. NH + HEN OH OH
Electrophilic Addition Mechanisms 15 of 30 Draw all missing reactants and products in the appropriate boxes by placing soms on the grand conecting the the electron flow arrows on the molecules. Arrows should start metabond and should end on an atom, bond, w bod, including charges were a wbond should be created indicate the chamby View Available in H OO
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