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Open Response. Draw the answer for each question below. 1. (10 points) Propose a synthesis of...
(10 points) Draw the correct product for the reaction below. For step 2, draw the reaction...
(10 points) Draw the correct product for the reaction below. For step 2, draw the reaction mechanism. Be sure to include important intermediate compounds, electron flow arrows, and formal charges for full credit. ОН 1. SOCl2, pyridine 2. CH3NH2 (10 points) Fill in the boxes with the missing starting material, intermediate products, reagents, and/or products. Then for each reaction draw the reaction mechanism with Correct electron flow arrows if appropriate or intermediates and correct formal charges. -OH -NH2 NH (10...
(10 points) Fill in the boxes with the missing starting material, intermediate products, reagents, and/or products....
(10 points) Fill in the boxes with the missing starting material, intermediate products, reagents, and/or products. Then for each reaction draw the reaction mechanism with correct electron flow arrows if appropriate or intermediates and correct formal charges. -OH -NH2 NH (10 points) Use the Gabrielle synthesis to make your starting amine below. Then use this starting amine to synthesize the secondary amine using reductive amination. Draw the mechanisms for both reactions below. Be sure to draw correct intermediates, electron flow...
CICI 35. (4) Provide a mechanism for the following transformation. You must use curved arrows to...
CICI 35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent electron movement and show all formal +/- charges to get full credit. a Nichols heat CHE CH2 OH 36.6) Provide a synthesis for the following amine using a Gabriel synthesis. NH2 37.(4) Draw the 4 possible organic products for each reaction. CHÚNH 38. (4) Draw a structure for the expected product of the following reactions. NH + HEN OH OH
35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent...
35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent electron movement and show all formal +/- charges to get full credit. heat NCH) CH, OH CH 36. (6) Provide a synthesis for the following amine using a Gabriel synthesis. NH 37.(4) Draw the 4 possible organic products for each reaction. Lly CH,NH 38. (4) Draw a structure for the expected product of the following reactions. wila + HN OH Gila OH
35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent...
35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent electron movement and show all formal +/- charges to get full credit. O NICH heat NICH) CH, OH "CH₂ 36. (6) Provide a synthesis for the following amine using a Gabriel synthesis. NH 37. (4) Draw the 4 possible organic products for each reaction. ily CH,NH. 38. (4) Draw a structure for the expected product of the following reactions, + HN OH Gila OH
35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent...
35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent electron movement and show all formal +/- charges to get full credit. a -N(CH3)3 heat CH3 CH2 OH 36. (6) Provide a synthesis for the following amine using a Gabriel synthesis. NH2 37. (4) Draw the 4 possible organic products for each reaction. 3.8 CH NHA 38. (4) Draw a structure for the expected product of the following reactions. NH2 + HEN H CI...
Question 4 (10 points) Draw mechanism for the following reactions: -OH a) HO_ Ht 1. Mel b) 2. H'/...
Question 4 (10 points) Draw mechanism for the following reactions: -OH a) HO_ Ht 1. Mel b) 2. H'/H20 Qestion 5 (6 points) Propose a synthesis for the target compound with given starting materials. You may use additional reagents you need. The proposed synthesis should be no more than S steps. Hint: Enolate Reaction, Decarboxylation Reaction. Target Compound Starting Materials
Question 4 (10 points) Draw mechanism for the following reactions: -OH a) HO_ Ht 1. Mel b) 2. H'/H20
Qestion...
31. (8) Provide a mechanism for the reaction below. Illustrate the role played by pyridine in...
31. (8) Provide a mechanism for the reaction below. Illustrate the role played by pyridine in the reaction. Your mechanism must use curved arrows to represent electron movement and it must show all non-zero formal charges. NH pyridine 32. (4) The reaction of acid chlorides with thiolates gives thioesters. Provide a mechanism for the following transformation. S Na ethyl thiolate Ischichte SCH.CH, a thioester 33. (4) Describe how the following acts as a soap. Na 34. (4) The following synthesis...
Homework extra credit! #18. As promised in lecture... Propose a synthesis of this compound starting with...
Homework extra credit!
#18. As promised in lecture... Propose a synthesis of this compound starting with the ind se a synthesis of this compound starting with the indicated material. For full credit you need to write out all the steps, showing the reagents used for each reaction. each step. For reactions that produce both ortho and para isomers, assume that the par e both ortho and para isomers, assume that the para isomer is the major product. This is not...
4. Reduction Mechanism. Draw the major product for the reduction reaction below in the box. Then,...
4. Reduction Mechanism. Draw the major product for the reduction reaction below in the box. Then, draw the proper FULL electron-pushing mechanism for the reaction, including ALL intermediates (with formal charges) and electron pushing arrows. Label the Electrophile and Nucleophile in each step! 1. NaBH4 2. H30+
(10 points) Draw the correct product for the reaction below. For step 2, draw the reaction mechanism. Be sure to include important intermediate compounds, electron flow arrows, and formal charges for full credit. ОН 1. SOCl2, pyridine 2. CH3NH2 (10 points) Fill in the boxes with the missing starting material, intermediate products, reagents, and/or products. Then for each reaction draw the reaction mechanism with Correct electron flow arrows if appropriate or intermediates and correct formal charges. -OH -NH2 NH (10...
(10 points) Fill in the boxes with the missing starting material, intermediate products, reagents, and/or products. Then for each reaction draw the reaction mechanism with correct electron flow arrows if appropriate or intermediates and correct formal charges. -OH -NH2 NH (10 points) Use the Gabrielle synthesis to make your starting amine below. Then use this starting amine to synthesize the secondary amine using reductive amination. Draw the mechanisms for both reactions below. Be sure to draw correct intermediates, electron flow...
CICI 35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent electron movement and show all formal +/- charges to get full credit. a Nichols heat CHE CH2 OH 36.6) Provide a synthesis for the following amine using a Gabriel synthesis. NH2 37.(4) Draw the 4 possible organic products for each reaction. CHÚNH 38. (4) Draw a structure for the expected product of the following reactions. NH + HEN OH OH
35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent electron movement and show all formal +/- charges to get full credit. heat NCH) CH, OH CH 36. (6) Provide a synthesis for the following amine using a Gabriel synthesis. NH 37.(4) Draw the 4 possible organic products for each reaction. Lly CH,NH 38. (4) Draw a structure for the expected product of the following reactions. wila + HN OH Gila OH
35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent electron movement and show all formal +/- charges to get full credit. O NICH heat NICH) CH, OH "CH₂ 36. (6) Provide a synthesis for the following amine using a Gabriel synthesis. NH 37. (4) Draw the 4 possible organic products for each reaction. ily CH,NH. 38. (4) Draw a structure for the expected product of the following reactions, + HN OH Gila OH
35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent electron movement and show all formal +/- charges to get full credit. a -N(CH3)3 heat CH3 CH2 OH 36. (6) Provide a synthesis for the following amine using a Gabriel synthesis. NH2 37. (4) Draw the 4 possible organic products for each reaction. 3.8 CH NHA 38. (4) Draw a structure for the expected product of the following reactions. NH2 + HEN H CI...
Question 4 (10 points) Draw mechanism for the following reactions: -OH a) HO_ Ht 1. Mel b) 2. H'/H20 Qestion 5 (6 points) Propose a synthesis for the target compound with given starting materials. You may use additional reagents you need. The proposed synthesis should be no more than S steps. Hint: Enolate Reaction, Decarboxylation Reaction. Target Compound Starting Materials
Question 4 (10 points) Draw mechanism for the following reactions: -OH a) HO_ Ht 1. Mel b) 2. H'/H20
Qestion...
31. (8) Provide a mechanism for the reaction below. Illustrate the role played by pyridine in the reaction. Your mechanism must use curved arrows to represent electron movement and it must show all non-zero formal charges. NH pyridine 32. (4) The reaction of acid chlorides with thiolates gives thioesters. Provide a mechanism for the following transformation. S Na ethyl thiolate Ischichte SCH.CH, a thioester 33. (4) Describe how the following acts as a soap. Na 34. (4) The following synthesis...
Homework extra credit!
#18. As promised in lecture... Propose a synthesis of this compound starting with the ind se a synthesis of this compound starting with the indicated material. For full credit you need to write out all the steps, showing the reagents used for each reaction. each step. For reactions that produce both ortho and para isomers, assume that the par e both ortho and para isomers, assume that the para isomer is the major product. This is not...
4. Reduction Mechanism. Draw the major product for the reduction reaction below in the box. Then, draw the proper FULL electron-pushing mechanism for the reaction, including ALL intermediates (with formal charges) and electron pushing arrows. Label the Electrophile and Nucleophile in each step! 1. NaBH4 2. H30+
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