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Only solve last 3 problems
The committed step involved in fatty acid synthesis is catalyzed by...
Prostaglandins are a class of eicosanoids (fatty acid derivatives) with a variety of extremely potent actions...
Prostaglandins are a class of eicosanoids (fatty acid derivatives) with a variety of extremely potent actions on vertebrate tissues. They are responsible for producing fever and inflammation and its associated pain. Prostaglandins are derived from the 20-carbon fatty acid, arachidonic acid, in a reaction catalyzed by the enzyme, prostaglandin endoperoxide synthase. This uses oxygen to convert arachidonic acid to PGG2 (a prostaglandin). Ibuprofen inhibits this enzyme and is a fever reducer and anti-inflammatory agent. The kinetic data is given below...
1- Sucrose does not react with Fehling's reagent because A- Sucrose is not a reducing sugar....
1- Sucrose does not react with Fehling's reagent because A- Sucrose is not a reducing sugar. B) The anomeric carbon of glucose is involved in the glucose- fructose bond and hence is not free to form the aldehyde in solution. C) The monosaacharide constituents of sucrose no longer have an anomeric carbon with a free potential aldehyde or ketone group, and therefore no longer exhibits reducing properties. D) sucrose is a disaccharide of glucose and fructose in which the oxygen...
1. Which of the following is true? a. The main rate-limiting step for fatty acid breakdown...
1. Which of the following is true? a. The main rate-limiting step for fatty acid breakdown is the transfer of the fatty acyl group to carnitine, with release of CoA. b. Elongase activity is an enzyme functionality of fatty acid synthase that adds 2-carbon acetyl groups to increase the length of palmitate. c. Oligomycin directly inhibits Complex I in the electron transport chain d. Squalene synthase catalyzes the rate-limiting step of fatty acid synthesis.
How would you convert an unsaturated fatty acid into a saturated fatty acid A. KMnO4, "OH,...
How would you convert an unsaturated fatty acid into a saturated fatty acid A. KMnO4, "OH, heat B. "OH,H,O, heat; then H,0 C. Hz, Ni, pressure D. H,0,H,O, heat 26. What structure has the following proton NMR spectrum? 'H NMR: doublet, 6.6 ppm, 2H doublet, 7.8 ppm, 2H broad singlet, 4.2 ppm, 2H singlet, 2.1 ppm, 3H HUN 27. Which of the following is the correct synthesis of the compound shown? CH, Br o Na Na o CH,Br B. T...
What is the correct name for the following compound? d) 5-oxo-3-octenoic acid What is the defining...
What is the correct name for the following compound? d) 5-oxo-3-octenoic acid What is the defining functional group of a carboxylic acid? a) an-H attached to a carbonyl group b) an-H attached to a carbon-carbon triple bond c) an-OH attached to a carbonyl group d) an -OH group attached to a O-C double bond e) an-OH group attached to an aromatic ring To convert a carboxylic acid to an aldehyde a) convert the acid to an acid chloride, then use...
Page Chemistry 107 Midterm II Review Problems Draw a Lewis structure for CaHN (think over the...
Page Chemistry 107 Midterm II Review Problems Draw a Lewis structure for CaHN (think over the bonding preferences of each atom when you lay out the skeleton of this molecule!) 1. CC Determine the geometry at each "central atom" (a) Does this molecule have any polar bonds? Is the entire molecule polar? (b) What will be the dominant intermolecular force in a sample of this compound? (c) (c) If you had 100.0 g of this compound, how many moles would...
18. Which of the following compound(s) would undergo mutarotation in aqueous solution? 19. Draw the chair...
18.
Which of the following compound(s) would undergo mutarotation in
aqueous solution?
19. Draw the chair conformation of a-D-galactopyranose.
20. Which of the following compound(s) is a glycoside?
21. Provide the reagents neccesary to carry out the following
conversion.
22. Predict the product(s) for the following reaction.
23. D-glucose & D-galactose are ______epimers of each
other.
24. Predict the product(s) for the following reaction.
25. Which of the following compound(s) would produce D-glucose
and D-mannose when treated with HCN followed...
1. Devise a method of converting trans-2-methyl-3-hexene into -4-methylpentanoic acid. 2. Show that you understand the...
1. Devise a method of converting trans-2-methyl-3-hexene into -4-methylpentanoic acid. 2. Show that you understand the concept of retrosynthetic analysis by working backwards two steps in the synthesis below. Identify possible combinations of A and B that can lead to the alkyne C): A) B-1 and A-VI B) B-V and A I C) B-III and A-VII D) B-IV and A-VII E) B-T and A-III F) B-VI and A-VIII 3. Show that you understand the concept of retrosynthetic analysis by working...
Can you help me identify reagent (i), Compound 8 and Compound 12 in the reaction scheme?...
Can you help me identify reagent (i), Compound 8 and
Compound 12 in the reaction scheme?
You have laboratory data on all the compounds in the
synthesis, however the amount of data available to you varies. Some
have the entirety of the spectral data, others have as little as
the elemental analysis. Use the laboratory data to help you
discover which reaction has been performed.
The lab data for Compound 8 and 12 is as
follows:
You can use any...
Nehydration synthesis dissolve in water, c) are one di Decause they a soluble in the Fatty...
Nehydration synthesis dissolve in water, c) are one di Decause they a soluble in the Fatty Acids of the bilayer 8. A molecule composed of carbon hydrogen, and oxygen in a 12:1 ratio is a (n) a) on / in acid b) id c) protei n onosaccharide 9. Which of the following molecule es that are hypothesized to have fomed spontaneously in the Earth's period of Chemical evolution served as a universal sole CH Ob) CO O O , e...
Prostaglandins are a class of eicosanoids (fatty acid derivatives) with a variety of extremely potent actions on vertebrate tissues. They are responsible for producing fever and inflammation and its associated pain. Prostaglandins are derived from the 20-carbon fatty acid, arachidonic acid, in a reaction catalyzed by the enzyme, prostaglandin endoperoxide synthase. This uses oxygen to convert arachidonic acid to PGG2 (a prostaglandin). Ibuprofen inhibits this enzyme and is a fever reducer and anti-inflammatory agent. The kinetic data is given below...
How would you convert an unsaturated fatty acid into a saturated fatty acid A. KMnO4, "OH, heat B. "OH,H,O, heat; then H,0 C. Hz, Ni, pressure D. H,0,H,O, heat 26. What structure has the following proton NMR spectrum? 'H NMR: doublet, 6.6 ppm, 2H doublet, 7.8 ppm, 2H broad singlet, 4.2 ppm, 2H singlet, 2.1 ppm, 3H HUN 27. Which of the following is the correct synthesis of the compound shown? CH, Br o Na Na o CH,Br B. T...
What is the correct name for the following compound? d) 5-oxo-3-octenoic acid What is the defining functional group of a carboxylic acid? a) an-H attached to a carbonyl group b) an-H attached to a carbon-carbon triple bond c) an-OH attached to a carbonyl group d) an -OH group attached to a O-C double bond e) an-OH group attached to an aromatic ring To convert a carboxylic acid to an aldehyde a) convert the acid to an acid chloride, then use...
Page Chemistry 107 Midterm II Review Problems Draw a Lewis structure for CaHN (think over the bonding preferences of each atom when you lay out the skeleton of this molecule!) 1. CC Determine the geometry at each "central atom" (a) Does this molecule have any polar bonds? Is the entire molecule polar? (b) What will be the dominant intermolecular force in a sample of this compound? (c) (c) If you had 100.0 g of this compound, how many moles would...
18.
Which of the following compound(s) would undergo mutarotation in
aqueous solution?
19. Draw the chair conformation of a-D-galactopyranose.
20. Which of the following compound(s) is a glycoside?
21. Provide the reagents neccesary to carry out the following
conversion.
22. Predict the product(s) for the following reaction.
23. D-glucose & D-galactose are ______epimers of each
other.
24. Predict the product(s) for the following reaction.
25. Which of the following compound(s) would produce D-glucose
and D-mannose when treated with HCN followed...
1. Devise a method of converting trans-2-methyl-3-hexene into -4-methylpentanoic acid. 2. Show that you understand the concept of retrosynthetic analysis by working backwards two steps in the synthesis below. Identify possible combinations of A and B that can lead to the alkyne C): A) B-1 and A-VI B) B-V and A I C) B-III and A-VII D) B-IV and A-VII E) B-T and A-III F) B-VI and A-VIII 3. Show that you understand the concept of retrosynthetic analysis by working...
Can you help me identify reagent (i), Compound 8 and
Compound 12 in the reaction scheme?
You have laboratory data on all the compounds in the
synthesis, however the amount of data available to you varies. Some
have the entirety of the spectral data, others have as little as
the elemental analysis. Use the laboratory data to help you
discover which reaction has been performed.
The lab data for Compound 8 and 12 is as
follows:
You can use any...
Nehydration synthesis dissolve in water, c) are one di Decause they a soluble in the Fatty Acids of the bilayer 8. A molecule composed of carbon hydrogen, and oxygen in a 12:1 ratio is a (n) a) on / in acid b) id c) protei n onosaccharide 9. Which of the following molecule es that are hypothesized to have fomed spontaneously in the Earth's period of Chemical evolution served as a universal sole CH Ob) CO O O , e...
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