Question

2. An unknown containing one or more of the ions studied in this experiment has the following properties: A. No effet is o hsrved on adition of O M HNO, B. No effect is observed on addition of 0.1 M AgNO, to the solution from Part A D. A yellow precipitate is observed on addition of (NH ),MoO, to the solution from Part A On the basis of this information, which ions are present, which are absent, and which are in doubt? Absent In doubt Present
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Answer #1

A. No reaction with dilute nitric acid is not a significant indication.

B. No effect of the addition of silver nitrate means it does not have halogens.

C. A white ppt with BaCl2 means it can be sulfate ion, which forms the insoluble white ppt of BaSO4.

D. The yellow precipitate of adding ammonium molybdate indicates that phosphate was present. A yellow ammonium molybdatophosphate is formed

So,

Present = Sulfate (SO42-), Phosphate (PO43-)

Absent = Chloride, Bromide, Iodide.

In doubt = Na+ (may be present along with the sulfate, as Na2SO4)

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