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For a particle on a ring, the wavefunctions are: (2T)1/2 where m' # 0, 1, £2,...
Show that the wavefunctions , where n ≠ m, are orthogonal for a particle confined to...
Show that the wavefunctions , where n ≠ m, are orthogonal for a
particle confined to the region -infinity ≤x ≤ infinity
Please show all work for full credit. The following wavefunctions are from the 1-D harmonic oscillator problem (imits from - infinity to + infinity, variable is x) I. (5 pts) Show V2 is orthogonal to vs. 1a
3. Consider a particle of mass m moving in a potential given by: W (2, y,...
3. Consider a particle of mass m moving in a potential given by: W (2, y, z) = 0 < x <a,0 < y <a l+o, elsewhere a) Write down the total energy and the 3D wavefunction for this particle. b) Assuming that hw > 312 h2/(2ma), find the energies and the corresponding degen- eracies for the ground state and the first excited state. c) Assume now that, in addition to the potential V(x, y, z), this particle also has...
1. Use the model of the particle in the ring (rotation in two dimensions) of quantum...
1. Use the model of the particle in the ring (rotation in two dimensions) of quantum mechanics to describe the movement of electrons in the conjugate system of the benzene molecule. Presume that the circumference of the ring is equal to 8.40A. a. ((3 pts) Make a diagram of the energy levels of the electrons Pi in the benzene molecule, clearly identifying the HOMO and the LUMO. b. (3 pts) Calculate the energy of the HOMO and LUMO C. (3...
For a particle in a ring, the energy levels can be expressed as En= [(h)2/ (2m)]...
For a particle in a ring, the energy levels can be expressed as En= [(h)2/ (2m)] [(n)/(L)]2 where n= 0, ±1, ±2, …, L = 2πr is the circumference of the ring, and r is the radius of the ring. If r=4.0 x 10-10 m, find the energy and the corresponding wavelength (λ) for the n = 0 to n=1 transition.
the acceleration of a particle as it moves along a straight line is given by a=(2t-1)m/s^2, where t is in seconds
the acceleration of a particle as it moves along a straight line is given by a=(2t-1)m/s^2, where t is in seconds.if s=1m and v= 2m/s when t=0,determine the particles velocity and position when t=6s. Also, determine the total distance the particle travels during this time period.
Dynamics 2. The velocity of a particle is v- {5i+(6-2t);} m/sec, where 't is in secs....
Dynamics
2. The velocity of a particle is v- {5i+(6-2t);} m/sec, where 't is in secs. r=0, When t=0, determine the displacement of the particle during the time intervalt-1 secs to t-3secs. [3 Marks ] I
2. A particle of mass m in the infinite square well of width a at time...
2. A particle of mass m in the infinite square well of width a at time 1 - 0 has wave function that is an equal weight mixture of the two lowest n= 1,2 energy stationary states: (x,0) - C[4,(x)+42(x)] (a) Normalize the wave function. Hints: 1. Exploit the orthonormality of W, 2. Recall that if a wave function is normalized at t = 0, it stays normalized. (b) Find '(x, t) and (x,1)1at a later time 1>0. Express Y*...
1. (50 points) Consider the particle in a one-dimensional box (0 s x S L). Assume a term is added to the Hamiltonian of the form: πχ V(x)g sin Sketch the potential and the expected eigenfunction (...
1. (50 points) Consider the particle in a one-dimensional box (0 s x S L). Assume a term is added to the Hamiltonian of the form: πχ V(x)g sin Sketch the potential and the expected eigenfunction (small g). In the limit of small g, find the second order correction to the ground state energy 2. (50 points) For a diatomic molecule rotating in free space, the Hamiltonian may be written: 12 21 Where L is the total angular momentum operator,...
Q10 The Hamiltonian of a two-state system is given by H E ( i)- I02)(2 |...
Q10 The Hamiltonian of a two-state system is given by H E ( i)- I02)(2 | -i | ¢1)(2 | +i | ¢2) (¢1 1) where , p2) form a complete and orthonormal basis; E is a real constant having the dimensions of energy (a) Is H Hermitian? Calculate the trace of H (b) Find the matrix representing H in the | øı), | 42) basis and calculate the eigenvalues and the eigenvectors of the matrix. Calculate the trace of...
3. The predecessor to Hartree-Fock was the Hartree method, where the main difference is that the ...
Questions 3-5
3. The predecessor to Hartree-Fock was the Hartree method, where the main difference is that the Hartree-Fock method includes an trial wavefunction by writing it as a Slater Determinant, while the Hartree method uses a simple product wavefunction that does not capture anti- symmetry. In particular, for a minimal-basis model of, the Hartree method's trial wavefunction is given in the while the Hartree-Fock trial wav is given by where and are molecular orbitals, and and coordinates of electron...
Show that the wavefunctions , where n ≠ m, are orthogonal for a
particle confined to the region -infinity ≤x ≤ infinity
Please show all work for full credit. The following wavefunctions are from the 1-D harmonic oscillator problem (imits from - infinity to + infinity, variable is x) I. (5 pts) Show V2 is orthogonal to vs. 1a
3. Consider a particle of mass m moving in a potential given by: W (2, y, z) = 0 < x <a,0 < y <a l+o, elsewhere a) Write down the total energy and the 3D wavefunction for this particle. b) Assuming that hw > 312 h2/(2ma), find the energies and the corresponding degen- eracies for the ground state and the first excited state. c) Assume now that, in addition to the potential V(x, y, z), this particle also has...
1. Use the model of the particle in the ring (rotation in two dimensions) of quantum mechanics to describe the movement of electrons in the conjugate system of the benzene molecule. Presume that the circumference of the ring is equal to 8.40A. a. ((3 pts) Make a diagram of the energy levels of the electrons Pi in the benzene molecule, clearly identifying the HOMO and the LUMO. b. (3 pts) Calculate the energy of the HOMO and LUMO C. (3...
Dynamics
2. The velocity of a particle is v- {5i+(6-2t);} m/sec, where 't is in secs. r=0, When t=0, determine the displacement of the particle during the time intervalt-1 secs to t-3secs. [3 Marks ] I
2. A particle of mass m in the infinite square well of width a at time 1 - 0 has wave function that is an equal weight mixture of the two lowest n= 1,2 energy stationary states: (x,0) - C[4,(x)+42(x)] (a) Normalize the wave function. Hints: 1. Exploit the orthonormality of W, 2. Recall that if a wave function is normalized at t = 0, it stays normalized. (b) Find '(x, t) and (x,1)1at a later time 1>0. Express Y*...
1. (50 points) Consider the particle in a one-dimensional box (0 s x S L). Assume a term is added to the Hamiltonian of the form: πχ V(x)g sin Sketch the potential and the expected eigenfunction (small g). In the limit of small g, find the second order correction to the ground state energy 2. (50 points) For a diatomic molecule rotating in free space, the Hamiltonian may be written: 12 21 Where L is the total angular momentum operator,...
Q10 The Hamiltonian of a two-state system is given by H E ( i)- I02)(2 | -i | ¢1)(2 | +i | ¢2) (¢1 1) where , p2) form a complete and orthonormal basis; E is a real constant having the dimensions of energy (a) Is H Hermitian? Calculate the trace of H (b) Find the matrix representing H in the | øı), | 42) basis and calculate the eigenvalues and the eigenvectors of the matrix. Calculate the trace of...
Questions 3-5
3. The predecessor to Hartree-Fock was the Hartree method, where the main difference is that the Hartree-Fock method includes an trial wavefunction by writing it as a Slater Determinant, while the Hartree method uses a simple product wavefunction that does not capture anti- symmetry. In particular, for a minimal-basis model of, the Hartree method's trial wavefunction is given in the while the Hartree-Fock trial wav is given by where and are molecular orbitals, and and coordinates of electron...
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